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We describe a rapid screening technique for determining the optimal characteristics of nano- photocatalysts for the production of H2 on a single surface. Arrays of TiO2 nanotubes (NTs) with a gradient in length and diameter were fabricated…

Materials Science · Physics 2016-10-18 G. Loget , P. Schmuki

In the present work we use TiO2 nanotube arrays, carrying a Pt coating that is optimally dewetted, as a photocatalyst to generate H2. In order to achieve a maximum H2-generation efficiency, on the one hand an ideal thermal dewetting of the…

In the present work we explore the front- and back-side performance of a photocatalytic platform consisting of self-organized TiO2 nanotube layers formed by complete anodization of Ti metal films evaporated on quartz slides. The adhesion…

In the present work we introduce a technique to form a photocatalyst, based on Pt nanoparticles suspended over the mouth of TiO2 nanotubes. These structures are obtained by the decoration of the top end of highly ordered TiO2 nanotubes with…

Chemical Physics · Physics 2016-10-18 Nhat Truong Nguyen , JeongEun Yoo , Marco Altomare , Patrik Schmuki

In the present work we grow self-organized Ta2O5 nanotube layers in a H2SO4/NH4F electrolyte at various elevated temperatures. Under optimized conditions we obtain 4 {\mu}m long nanotubes that are well adherent to the substrate and can be…

Materials Science · Physics 2016-10-18 Sabina Grigorescu , Seulgi So , Jeong Eun Yoo , Anca Mazare , Robert Hahn , Patrik Schmuki

Self-standing TiO$_2$ nanotube layers in the form of membranes are fabricated by self-organizing anodization of Ti metal and a potential shock technique. The membranes were then decorated by sputtering different Pt amounts i) only at the…

Applied Physics · Physics 2020-06-02 Gihoon Cha , Marco Altomare , Nhat Truong Nguyen , Nicola Taccardi , Kiyoung Lee , Patrik Schmuki

In the present work we grow self-organized TiO2 nanotube arrays with a defined and controlled regular spacing between individual nanotubes. These defined intertube gaps allow to build up hierarchical 1D-branched structures, conformally…

Materials Science · Physics 2016-10-27 Nhat Truong Nguyen , Selda Ozkan , Imgon Hwang , Anca Mazare , Patrik Schmuki

The least is the best. We introduce a technique to strongly reduce Pt use for photocatalytic hydrogen generation from TiO2 nanotubes. By site-selectively depositing thin layers of Pt only at the mouth of the nanotubes and by a subsequent…

Chemical Physics · Physics 2016-10-18 Nhat Truong Nguyen , Marco Altomare , JeongEun Yoo , Nicola Taccardi , Patrik Schmuki

The interaction of water with TiO2 is crucial to many of its practical applications, including photocatalytic water splitting. Following the first demonstration of this phenomenon 40 years ago there have been numerous studies of the rutile…

The present work reports on the enhancement of TiO2 nanotubes photoelectrochemical water splitting rate by decorating the nanostructure with an amine layer in a hydrothermal process using diethylenetriamine (DETA). The aminate coated TiO2…

Materials Science · Physics 2016-10-14 Seyedsina Hejazi , Nhat Truong Nguyen , Anca Mazare , Patrik Schmuki

A simple refluxing wet-chemical approach is employed for fabricating In2S3/Pt-TiO2 heterogeneous catalysts for hydrogen generation under visible light irradiation. When the mass ratio between Pt-TiO2 and cubic-phased In2S3 (denoted as…

We investigate the photocatalytic performance of nanocomposites prepared in a one-step process by liquid-phase exfoliation of graphite in the presence of TiO$_2$ nanoparticles (NPs) at atmospheric pressure and in water, without heating or…

Photocatalytic water splitting reaction on TiO2 surface is one of the fundamental issues that bears significant implication in hydrogen energy technology and has been extensively studied. However, the existence of the very first reaction…

Chemical Physics · Physics 2011-11-15 Shijing Tan , Yongfei Ji , Yang Wang , Jin Zhao , Aidi Zhao , Bing Wang , Yi Luo , Jinlong Yang , J. G. Hou

We propose a systematic approach to obtain various forms of insulating titanium oxynitrides Ti$_{n}$N$_{2}$O$_{2n-3}$ and we conduct a detailed study on its $n=2$ case, Ti$_{2}$N$_{2}$O. We study the energetics and the electronic structures…

Materials Science · Physics 2019-03-06 Yuta Aoki , Sinisa Coh , Steven G. Louie , Marvin L. Cohen , Susumu Saito

Low-dose nitrogen implantation induces in TiO2 nanotubes a co-catalytic activity for photocatalytic H2-evolution. The use of an ion implantation process leads to a N-implanted zone only at the top part of the tubes. The coupling of this top…

We fabricate photo-anodes by transferring anodic TiO2 nanotube membranes in tube-top-down configuration on FTO glass, and use them for constructing frontside illuminated dye-sensitized solar cells. Prior to solar cell construction, the…

In the present work we compare TiO2 nanotube lift-off strategies for the construction of front-side illuminated dye-sensitized solar cells (DSSCs). Anodic nanotube layers were detached from the metallic back contact by using different…

Due to their characteristic geometry, TiO$_2$ nanotubes (TNTs), suitably doped by metal-substitution to enhance their photocatalytic properties, have a high potential for applications such as clean fuel production. In this context, we…

Materials Science · Physics 2020-09-17 Mohamed M. Fadlallah , Ulrich Eckern

We address one of the main challenges to TiO2-photocatalysis, namely band gap narrowing, by combining nanostructural changes with doping. With this aim we compare TiO2's electronic properties for small 0D clusters, 1D nanorods and…

Materials Science · Physics 2010-01-18 D. J. Mowbray , J. I. Martinez , J. M. García-Lastra , K. S. Thygesen , K. W. Jacobsen

A template-free process for the synthesis of nanocrystalline TiO2 hierarchical microstructures by reactive Pulsed Laser Deposition (PLD) is here presented. By a proper choice of deposition parameters a fine control over the morphology of…

Materials Science · Physics 2013-11-28 F. Di Fonzo , C. S. Casari , V. Russo , M. F. Brunella , A. Li Bassi , C. E. Bottani
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