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The most advanced techniques using fault-tolerant quantum computers to estimate the ground-state energy of a chemical Hamiltonian involve compression of the Coulomb operator through tensor factorizations, enabling efficient block-encodings…

Understanding the quantum dynamics of spin defects and their coherence properties requires accurate modeling of spin-spin interaction in solids and molecules, for example by using spin Hamiltonians with parameters obtained from…

Materials Science · Physics 2021-02-02 Krishnendu Ghosh , He Ma , Mykyta Onizhuk , Vikram Gavini , Giulia Galli

Electron-electron correlation forms the basis of difficulties encountered in many-body physics. Accurate treatment of the correlation problem is likely to unravel some nice physical properties of matter embedded in the correlation. In an…

Atomic Physics · Physics 2021-03-17 E. Jobunga

The use of the hyperspherical harmonic (HH) basis in the description of bound states in an $A$-body system composed by identical particles is normally preceded by a symmetrization procedure in which the statistic of the system is taken into…

Nuclear Theory · Physics 2011-02-22 M. Gattobigio , A. Kievsky , M. Viviani

Momentum-space approach to calculation of one-electron energies and wave functions proposed initially by Fock for a hydrogen atom and considered later by Shibuya, Wulfman, and Koga for diatomic molecules is applied to clusters composed of…

Quantum Physics · Physics 2007-05-23 V. F. Elesin , A. I. Podlivaev , L. A. Openov

With the aim of describing bound and continuum states for diatomic molecules, we develop and implement a spectral method that makes use of Generalized Sturmian Functions (GSF) in prolate spheroidal coordinates. In order to master all…

Atomic and Molecular Clusters · Physics 2021-06-02 D. M. Mitnik , F. A. Lopez , L. U. Ancarani

It is known that homogeneous distribution of particles in Coulomb-like systems can be unstable, and spatially inhomogeneous structures can be formed. A simple method for describing such inhomogeneous systems and obtaining spacial…

Statistical Mechanics · Physics 2015-06-16 B. I. Lev , V. P. Ostroukh , V. B. Tymchyshyn , A. G. Zagorodny

A method for beyond-mean-field calculations based on an energy density functional is described. The main idea is to map the energy surface for the nuclear quadrupole deformation, obtained from an energy density functional at the mean-field…

Nuclear Theory · Physics 2022-12-16 J. Ljungberg , J. Boström , B. G. Carlsson , A. Idini , J. Rotureau

We extend our analysis of two electrons on a sphere [Phys. Rev. A {\bf 79}, 062517 (2009); Phys. Rev. Lett. {\bf 103}, 123008 (2009)] to electrons on concentric spheres with different radii. The strengths and weaknesses of several…

Other Condensed Matter · Physics 2010-08-17 Pierre-François Loos , Peter M. W. Gill

Continuum states of the Dirac equation are calculated numerically for the electrostatic field generated by the charge distribution of an atomic nucleus. The behavior of the wave functions of an incoming electron with a given asymptotic…

Nuclear Theory · Physics 2007-05-23 Andreas Aste , Cyrill von Arx , Dirk Trautmann

Based on the metastable electron-pair energy band in a two-dimensional (2D) periodic potential obtained previously by Hai and Castelano [J. Phys.: Condens. Matter 26, 115502 (2014)], we present in this work a Hamiltonian of many electrons…

Superconductivity · Physics 2015-01-21 G. -Q. Hai , F. M. Peeters

Describing the Coulomb interactions between electrons in atomic or molecular systems is an important step to help us obtain accurate results for the different observables in the system. One convenient approach is to separate the dynamic…

Chemical Physics · Physics 2025-01-22 Claude Le Sech , Antonio Sarsa

The method of many-body Green's functions is developed for arbitrary systems of electrons and nuclei starting from the full (beyond Born-Oppenheimer) Hamiltonian of Coulomb interactions and kinetic energies. The theory presented here…

Other Condensed Matter · Physics 2020-06-23 Ville J. Härkönen , Robert van Leeuwen , E. K. U. Gross

New sets of functions with arbitrary large finite cardinality are constructed for two-electron atoms. Functions from these sets exactly satisfy the Kato's cusp conditions. The new functions are special linear combinations of Hylleraas-…

Atomic Physics · Physics 2020-01-08 A. T. Kruppa , J. Kovács , I. Hornyak

An approximation-free, numerically efficient algorithm is presented for the Hamiltonian eigen-states of the Stark-Hydrogen problem describing a quantum particle exposed to the central Coulomb force and a homogeneous external field. As an…

Atomic Physics · Physics 2022-03-17 Seyedmohammad Yusofsani , Mroslav Kolesik

The energy levels of the first few low-lying states of helium and lithium atoms in intense magnetic fields up to $\approx 10^8-10^9$~T are calculated in this study. A pseudospectral method is employed for the computational procedure. The…

Quantum Physics · Physics 2014-06-11 Anand Thirumalai , Jeremy S. Heyl

Rotationally invariant combinations of the Brillouin zone-center Bloch functions are used as basis function to express in cylindrical coordinates the valence-band and Kane envelope-function Hamiltonians for wurtzite and zinc-blende…

Materials Science · Physics 2012-10-30 Eduard Takhtamirov

The generation and evolution of entanglement in quantum many-body systems is an active area of research that spans multiple fields, from quantum information science to the simulation of quantum many-body systems encountered in condensed…

In this work we include electron-electron interaction beyond Hartree-Fock level in our non-equilibrium Green's function approach by a crude form of GW through the Single Plasmon Pole Approximation. This is achieved by treating all…

Mesoscale and Nanoscale Physics · Physics 2016-05-02 David O. Winge , Martin Franckié , Claudio Verdozzi , Andreas Wacker , Mauro F. Pereira

By extending the concept of Euler-angle rotations to more than three dimensions, we develop the systematics under rotations in higher-dimensional space for a novel set of hyperspherical harmonics. Applying this formalism, we determine all…

Atomic and Molecular Clusters · Physics 2015-06-26 T. A. Heim , D. Green