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Conventional nuclear magnetic resonance (NMR) spectroscopy relies on acquiring signal from a macroscopic ensemble of molecules to gain information about molecular structure and dynamics. Transferring this technique to nanoscale sample sizes…

Mesoscale and Nanoscale Physics · Physics 2019-02-06 Jeffrey Holzgrafe , Qiushi Gu , Jan Beitner , Dhiren Kara , Helena S. Knowles , Mete Atatüre

Nuclear magnetic resonance (NMR) schemes can be applied to micron-, and nanometer-sized samples by the aid of quantum sensors such as nitrogen-vacancy (NV) color centers in diamond. These minute devices allow for magnetometry of nuclear…

Quantum Physics · Physics 2021-07-19 C. Munuera-Javaloy , R. Puebla , J. Casanova

Nitrogen vacancy (NV) centers in diamond have been used as ultrasensitive magnetometers to perform nuclear magnetic resonance (NMR) spectroscopy of statistically polarized samples at 1 - 100 nm length scales. However, the spectral linewidth…

We demonstrate a wide-band all-optical method of nanoscale magnetic resonance (MR) spectroscopy under ambient conditions. Our method relies on cross-relaxation between a probe spin, the electronic spin of a nitrogen-vacancy centre in…

After initial proof-of-principle demonstrations, optically pumped nitrogen-vacancy (NV) centres in diamond have been proposed as a non-invasive platform to achieve hyperpolarisation of nuclear spins in molecular samples over macroscopic…

Mesoscale and Nanoscale Physics · Physics 2021-01-27 J. -P. Tetienne , L. T. Hall , A. J. Healey , G. A. L. White , M. -A. Sani , F. Separovic , L. C. L. Hollenberg

Two-dimensional Nuclear Magnetic Resonance (NMR) is essential in molecular structure determination. The Nitrogen-Vacancy (NV) center in diamond has been proposed and developed as an outstanding quantum sensor to realize NMR in nanoscale. In…

We present a new method for high-resolution nanoscale magnetic resonance imaging (nano-MRI) that combines the high spin sensitivity of nanowire-based magnetic resonance detection with high spectral resolution nuclear magnetic resonance…

Mesoscale and Nanoscale Physics · Physics 2018-03-07 William Rose , Holger Haas , Angela Q. Chen , Nari Jeon , Lincoln J. Lauhon , David G. Cory , Raffi Budakian

Nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) are well-established techniques that provide valuable information in a diverse set of disciplines but are currently limited to macroscopic sample volumes. Here we…

Nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) spectroscopy of bulk quantum materials have provided insight into phenomena such as quantum phase criticality, magnetism, and superconductivity. With the emergence of…

We present nanoscale NMR measurements performed with nitrogen-vacancy (NV) centers located down to about 2 nm from the diamond surface. NV centers were created by shallow ion implantation followed by a slow, nanometer-by-nanometer removal…

Mesoscale and Nanoscale Physics · Physics 2014-01-24 M. Loretz , S. Pezzagna , J. Meijer , C. L. Degen

Ensembles of nitrogen-vacancy (NV) centers are used as sensors to detect NMR signals from micron-sized samples at room temperature. In this scenario, the regime of large magnetic fields is especially interesting as it leads to a large…

Quantum Physics · Physics 2023-04-04 C. Munuera-Javaloy , A. Tobalina , J. Casanova

Magnetic spin resonance is a key non-invasive sensing and imaging technique across the life-, material- and fundamental sciences with further medical and commercial applications. Recent advances using paramagnetic color centers enable…

Mesoscale and Nanoscale Physics · Physics 2018-07-24 Florestan Ziem , Marwa Garsi , Helmut Fedder , Jörg Wrachtrup

Single nitrogen-vacancy (NV) centers are widely used as nanoscale sensors for magnetic and electric fields, strain and temperature. Nanoscale magnetometry using NV centers allows for example to quantitatively measure local magnetic fields…

Nuclear magnetic resonance (NMR) spectroscopy provides unparalleled access to molecular structure and dynamics but is traditionally limited by weak signal strength, requiring large sample volumes and high magnetic fields. Here, we…

Applied Physics · Physics 2026-04-29 Dileep Singh , Riley W. Hooper , Christoph Findler , Utsab Banerjee , Dominik B. Bucher

In nanoscale metrology applications, measurements are commonly limited by the performance of the sensor. Here we show that in nuclear magnetic resonance (NMR) spectroscopy measurements using single nitrogen-vacancy (NV) centers in diamond,…

Nanomagnetometry using the nitrogen-vacancy (NV) centre in diamond has attracted a great deal of interest because of the combined features of room temperature operation, nanoscale resolution and high sensitivity. One of the important goals…

Detecting nuclear spins using single Nitrogen-Vacancy (NV) centers is of particular importance in nano-scale science and engineering, but often suffers from the heating effect of microwave fields for spin manipulation, especially under high…

Quantum Physics · Physics 2024-09-06 Zhiyi Hu , Fengjian Jiang , Jingyan He , Yulin Dai , Ya Wang , Nanyang Xu , Jiangfeng Du

Optically active quantum defects in solids, such as the nitrogen vacancy (NV) center in diamond, are a leading modality for micron-scale and nanoscale (ultralow-mass) nuclear magnetic resonance (NMR) spectroscopy and imaging under ambient…

Spin defects in solids, such as the nitrogen-vacancy (NV) center in diamond, have emerged as a key tool for detecting nuclear spins at the nanoscale. While active nuclear spin control via radio-frequency (RF) irradiation is often…

Achieving atomic resolution is the ultimate limit of magnetic resonance imaging (MRI), and attaining this capability offers enormous technological and scientific opportunities, from drug development to understanding the dynamics in…

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