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Despite the widespread use of silicon in modern technology, its peculiar thermal expansion is not well-understood. Adapting harmonic phonons to the specific volume at temperature, the quasiharmonic approximation, has become accepted for…

The anharmonicity of atomic motion limits the thermal conductivity in crystalline solids. However, a microscopic understanding of the mechanisms active in strong thermal insulators is lacking. In this letter, we classify 465 experimentally…

Materials Science · Physics 2023-06-14 Florian Knoop , Thomas A. R. Purcell , Matthias Scheffler , Christian Carbogno

Phonon-phonon anharmonic effects have a strong influence on the phonon spectrum; most prominent manifestation of these effects are the softening (shift in frequency) and broadening (change in FWHM) of the phonon modes at finite temperature.…

Understanding interfacial thermal transport is essential for improving thermal management in high-speed power electronic devices, where the efficient removal of excess heat is a critical challenge. In this study, a machine learning…

Materials Science · Physics 2025-10-01 Lei Zhang , Fei Tian , Ke Chen , Zhongbo Yan , Kun Cao

We theoretically explore the influence of end-group chemistry (bond stiffness and mass) on the interfacial thermal conductance at a gold-alkane interface. We accomplish this using the Non-Equilibrium Green's Function (NEGF) coupled with…

Mesoscale and Nanoscale Physics · Physics 2018-09-14 Jingjie Zhang , Carlos A. Polanco , Avik W. Ghosh

Indium iodides, which adopt layered or molecular-crystal-like arrangements depending on composition, are expected to exhibit low lattice thermal conductivity because of their heavy constituent atoms and weak In-I bonding. In this work, we…

Materials Science · Physics 2026-01-06 Takuma Shiga , Yoshikazu Mizuguchi , Hiroshi Fujihisa

The methods of non-equilibrium thermodynamics of systems with an interface have been applied to the study of thermionic emission processes in abrupt semiconductor junctions, including the effects of surface states . Our analysis covers…

Condensed Matter · Physics 2015-06-25 G. Gomila , A. Perez-Madrid , J. M. Rubi

We present an \emph{ab initio} study of the role of interference effects in the thermal conductance of single-molecule junctions. To be precise, using a first-principles transport method based on density functional theory, we analyze the…

Mesoscale and Nanoscale Physics · Physics 2017-12-27 J. C. Klöckner , J. C. Cuevas , F. Pauly

The quasiharmonic approximation is the most common method for modeling the specific heat of solids; however, it fails to capture the effects of intrinsic anharmonicity. In this study, we introduce the "elastic softening approximation," an…

We study the nonlinear interfacial thermal transport across atomic junctions by the quantum self-consistent mean field (QSCMF) theory based on nonequilibrium Green's function approach; the QSCMF theory we propose is very precise and matches…

Statistical Mechanics · Physics 2013-10-15 Lifa Zhang , Juzar Thingna , Dahai He , Jian-Sheng Wang , Baowen Li

Amorphous alumina is employed ubiquitously as a high-dielectric-constant material in electronics, and its thermal-transport properties are of key relevance for heat management in electronic chips and devices. Experiments show that the…

Materials Science · Physics 2023-12-27 Angela F. Harper , Kamil Iwanowski , William C. Witt , Mike C. Payne , Michele Simoncelli

The amorphous solids can be theoretically modeled by anharmonic disordered lattices. However, most of theoretical studies on thermal conductivity in anharmonic disordered lattices only focus on the potentials of hard-type (HT)…

Statistical Mechanics · Physics 2023-03-16 Jianjin Wang , Chi Xiong , Daxing Xiong

Superlattices (SLs) can induce phonon coherence through the periodic layering of two or more materials, enabling tailored thermal transport properties. While most theoretical studies assume atomically sharp, perfect interfaces, real SLs…

Materials Science · Physics 2025-01-30 Theodore Maranets , Evan Doe , Yan Wang

The anharmonicity resulted from the intrinsic phonon interaction is neglected by quasiharmonic approximation. Although the intensive researches about anharmonicity have been done, up to now the free energy contributed by the anharmonicity…

Statistical Mechanics · Physics 2007-05-23 Zhongqing Wu , Renata M. Wentzcovitch

Explicit expressions for anharmonic contributions to the thermodynamic properties with allowance for higher-order phonon-phonon interactions for closed-packed crystals are given, and the calculations for some fcc metals near the melting…

Materials Science · Physics 2009-11-07 M. I. Katsnelson , A. F. Maksyutov , A. V. Trefilov

We reveal the intricate impact of nonlinearity and disorder on the thermal conductivity of acoustic chains. Disorder induces mobility edges and allows to control the amount of extended modes which are the ballistic channels for energy…

Disordered Systems and Neural Networks · Physics 2010-09-20 M. V. Ivanchenko , S. Flach

The hot and dense hadronic medium formed during the heavy-ion collisions at the Relativistic Heavy Ion Collider and Large Hadron Collider energies can show thermoelectric effects in the presence of temperature gradients and nonzero baryon…

High Energy Physics - Phenomenology · Physics 2025-04-30 Kamaljeet Singh , Kshitish Kumar Pradhan , Dushmanta Sahu , Raghunath Sahoo

We adopted and extended an efficient Gr\"uneisen formalism to study the phonon anharmonicity and linear thermal expansion coefficients (TECs) of trigonal bismuth selenide (Bi$_2$Se$_3$) and antimony telluride (Sb$_2$Te$_3$). Anharmonicity…

Materials Science · Physics 2018-05-11 Chee Kwan Gan , Ching Hua Lee

The existed theories and methods for calculating interfacial thermal conductance of solid-solid interface lead to diverse values that deviate from experimental measurements. In this letter, We propose a model to estimate the ITC at high…

Materials Science · Physics 2020-11-20 Jinxin Zhong , Zhiguo Wang , Xiaobo Li , Jun Liu , Jun Zhou

The acoustic mismatch model and the diffuse mismatch model have been widely used to predict the thermal interface conductance. However, the acoustic mismatch model (diffuse mismatch model) is based on the hypothesis of a perfectly smooth…

Mesoscale and Nanoscale Physics · Physics 2018-12-10 Yingying Zhang , Dengke Ma , Yi Zang , Nuo Yang
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