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Related papers: The Theory of SERS on Dielectrics and Semiconducto…

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We discuss the effect of the local field polarization in metallic nanostructures where large field enhancements can be induced by excitation of localized surface plasmons. To demonstrate the importance of these effects, we study a few model…

Chemical Physics · Physics 2007-05-23 E. C. Le Ru , P. G. Etchegoin

Surface enhanced Raman scattering (SERS) process results in a tremendous increase of Raman scattering cross section of molecules adsorbed to plasmonic metals and influenced by numerous physico-chemical factors such as geometry and optical…

Chemical Physics · Physics 2021-02-23 Shimon Rubin , Phuong H. L. Nguyen , Yeshaiahu Fainman

In Surface Enhanced Raman Scattering (SERS) the problem of drawing molecules to the places where surface plasmon resonance enhancements will produce signals is one of the most basic ones, and the initial obstacle to every application of the…

Chemical Physics · Physics 2008-11-03 Paul D. Lacharmoise , Eric C. Le Ru , Pablo G. Etchegoin

The development of electron spin resonance (ESR) combined with scanning tunneling spectroscopy (STM) is undoubtedly one of the main experimental breakthroughs in surface science of the last decade thanks to joining the extraordinarily high…

Strongly Correlated Electrons · Physics 2022-08-31 Fernando Delgado , Nicolás Lorente

Surface Enhanced Raman Scattering (SERS) and Surface-Enhanced Fluorescence (SEF) are studied within the framework of modified Spontaneous Emission (SE), and similarities and differences are highlighted. This description sheds new light into…

Chemical Physics · Physics 2007-05-23 E. C. Le Ru , P. G. Etchegoin

Dielectric mesoscale spheres have aroused strong interest because of their potential to localize light at deep subwavelength volume and to yield extremal internal magnetic and/or electric field enhancements. Recently, we showed that such…

Optics · Physics 2023-05-16 Igor V. Minin , Song Zhou , Oleg V. Minin

Contrary to a paradigm of metal-enhanced fluorescence, unusually thick dielectric coatings can be very favorable to achieve extreme values of averaged fluorescence enhancement factor $\bar F\gtrsim 3000$ for emitters located on the surface,…

Optics · Physics 2021-09-24 Ilia L. Rasskazov , Alexander Moroz , P. Scott Carney

Tip-enhanced Raman spectroscopy (TERS) with sub-nanometer spatial resolution has been recently demonstrated experimentally. However, the physical mechanism underlying is still under discussion. Here, we theoretically investigate the…

Mesoscale and Nanoscale Physics · Physics 2015-03-10 Lingyan Meng , Zhilin Yang , Jianing Chen , Mengtao Sun

Nanofibers functionalized by metal nanostructures and particles are exploited as effective flexible substrates for SERS analysis. Their complex three-dimensional structure may provide Raman signals enhanced by orders of magnitude compared…

Materials Science · Physics 2016-03-16 A. Camposeo , D. Spadaro , D. Magrì , M. Moffa , P. G. Gucciardi , L. Persano , O. M. Maragò , D. Pisignano

Plasmon-free surface-enhanced Raman scattering (SERS) substrates have attracted tremendous attention for their abundant sources, excellent chemical stability, superior biocompatibility, good signal uniformity, and unique selectivity to…

Optics · Physics 2021-06-10 Leilei Lan , Yimeng Gao , Xingce Fan , Mingze Li , Qi Hao , Teng Qiu

We present experimental demonstration of a recently predicted path interference phenomenon [Nanophotonics 7, 1687 (2018)]. A SERS process becomes resonant when both incident and the converted frequencies match with two plasmon resonances --…

It is found that for objects possessing small surface structures with differing radii of curvature the secondary electron emission (SEE) yield may be significantly higher than for objects with smooth surfaces of the same material. The…

Mesoscale and Nanoscale Physics · Physics 2016-05-03 A. R. Dzhanoev , F. Spahn , V. Yaroshenko , H. Lühr , J. Schmidt

We demonstrate an enhanced emission of high quantum yield molecules coupled to dielectric metasurfaces formed by periodic arrays of polycrystalline silicon nanoparticles. Radiative coupling of the nanoparticles, mediated by in-plane…

The SEHRS and SERS spactra of 4,4 - Bipyridine are analyzed on the base of the Dipole-Quadrupole theory for two possible geometries of the molecule. It is demonstrated that there appear strong lines caused by vibrations transforming after a…

Chemical Physics · Physics 2016-04-11 Vladimir P. Chelibanov , Alexander V. Golovin , Aleksey M. Polubotko

Surface enhanced Raman scattering (SERS) in nanoscale hotspots has been placed great hopes upon for identification of minimum chemical traces and in-situ investigation of single molecule structures and dynamics. However, previous work…

Optics · Physics 2016-09-19 Jing Long , Hui Yi , Hongquan Li , Tian Yang

The paper demonstrates possibility of giant enhancement of Surface Enhanced Hyper Raman Scattering on the base of qualitative consideration of electromagnetic field near some models of rough metal surfaces and of some features of the dipole…

Optics · Physics 2011-07-19 A. M. Polubotko

Nanoscale gaps between adjacent metallic nanostructures give rise to extraordinarily large field enhancements, known as "hot spots", upon illumination. Incident light with the electric field polarized across the gap (along the interparticle…

Mesoscale and Nanoscale Physics · Physics 2013-03-27 Joseph B. Herzog , Mark W. Knight , Yajing Li , Kenneth M. Evans , Naomi J. Halas , Douglas Natelson

A method is proposed to pin down an unambiguous proof for single molecule surface enhanced Raman spectroscopy (SERS). The simultaneous use of two analyte molecules enables a clear confirmation of the single (or few) molecule nature of the…

Chemical Physics · Physics 2007-05-23 E. C. Le Ru , M. Meyer , P. G. Etchegoin

Different periodical Frequency Selective Surfaces(FSS) whose unit cell are the Split Ring Resonators (SRR) or related geometries and their corresponding complementary screens were studied. This kind of FSS, sometimes called metasurfaces,…

Classical Physics · Physics 2013-10-14 L. M. Pulido-Mancera , J. D. Baena , J. L. Araque

It is an established understanding that the electromagnetic contribution (the plasmon-mediated enhancement of the laser and scattered local electromagnetic fields) is the main actor in Surface Enhanced Raman Scattering (SERS), with the…