Related papers: Systematic Theoretical Study on the Interstellar C…
Molecular oxygen has been the subject of many observational searches as chemical models predicted it to be a reservoir of oxygen. Although it has been detected in two regions of the interstellar medium, its rarity is a challenge for…
We present a longslit optical spectrophotometric survey in the irregular "post-starburst" galaxy NGC 1569 to search for chemical gradients and inhomogeneities in the interstellar medium. Despite the presence of two massive evolved…
Carbon monoxide (CO) is the most abundant molecule after molecular hydrogen and is important for the chemistry in circumstellar envelopes around evolved stars. When modelling the strength and shape of molecular lines, the size of the CO…
Observations were made for a number of carbon-rich circumstellar envelopes using the Phoenix spectrograph on the Gemini South telescope to determine the abundance of small carbon chain molecules. Vibration-rotation lines of the $\nu_{3}$…
We study the chemical complexity towards the central parts of the starburst galaxy M82, and investigate the role of certain molecules as tracers of the physical processes in the galaxy circumnuclear region. We carried out a spectral line…
Isomerism in complex organic molecules provides key insights into the formation mechanisms and physical conditions of the interstellar medium (ISM). Among the C$_2$H$_5$NO isomers, only acetamide and trans-N-methylformamide (trans-NMF) have…
Observations of CO+ suggest column densities on the order 10^12 cm^-2 that can not be reproduced by many chemical models. CO+ is more likely to be destroyed than excited in collisions with hydrogen. An anomalous excitation mechanism may…
We report on the detection of vinyl cyanide (CH2CHCN), cyanomethyl radical (CH2CN), methylacetylene (CH3CCH) and thioformaldehyde (H2CS) in the C-rich star IRC +10216. These species, which are all known to exist in dark clouds, are detected…
A mechanism based on the penetration of interstellar ultraviolet photons into the inner layers of clumpy circumstellar envelopes around AGB stars is proposed to explain the non-equilibrium chemistry observed in such objects. We show through…
The addition of individual quanta of rotational excitation to a molecule has been shown to markedly change its reactivity by significantly modifying the intermolecular interactions. So far, it has only been possible to observe these…
We aimed to study the chemistry of the circumnuclear molecular gas of NGC1068, and to compare it with those of the starburst galaxies M82 and NGC253. Using the IRAM-30m telescope, we observed the inner 2 kpc of NGC1068 between 86.2 GHz and…
Spectroscopic observations of 32 HII regions in the spiral galaxy NGC 3963 and the barred irregular galaxy NGC 7292 were carried out with the 2.5-m telescope of the Caucasus Mountain Observatory of the Sternberg Astronomical Institute using…
Isolated dense molecular cores are investigated to study the onset of complex organic molecule formation in interstellar ice. Sampling three cores with ongoing formation of low-mass stars (B59, B335, and L483) and one starless core (L694-2)…
We report the first identification in space of H2NC, a high-energy isomer of H2CN that has been largely ignored in chemical and astrochemical studies. The observation of various unidentified lines around 72.2 GHz in the cold dark cloud L483…
We investigate chemistry in the compression layer behind the interstellar shock waves, where molecular cloud formation starts. We perform three-dimensional magnetohydrodynamics simulations of converging flows of atomic gas with shock…
Hot core molecules should be detectable in external active galaxies out to high redshift. We present here a detailed study of the chemistry of star-forming regions under physical conditions that differ significantly from those likely to be…
(Abridged) We present evidence that low-mass starless cores, the simplest units of star formation, are systematically differentiated in their chemical composition. Molecules including CO and CS almost vanish near the core centers, where the…
[ABRIDGED]We study the carbon abundances with a twofold objective. On the one hand, we want to evaluate the behaviour of carbon in the context of Galactic chemical evolution. On the other hand, we focus on the possible dependence of carbon…
Because of their importance in biological systems, in our understanding of the solar system and in other applications, seven heterocycles; furan, imidazole, pyridine, pyrimidine, pyrrole, quinoline and isoquinoline have been astronomically…
Bell et al. (1997) reported the first detection of the cyanopolyyne HC$_{11}$N toward the cold dark cloud TMC-1; no subsequent detections have been reported toward any source. Additional observations of cyanopolyynes and other carbon-chain…