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We give a detailed account of the theoretical analysis and the experimental results of an x-ray-diffraction experiment on quantum-state selected and strongly laser-aligned gas-phase ensembles of the prototypical large asymmetric rotor…

The development of attosecond technology has enabled the real-time observation of coherent electron motion in atoms, molecules and condensed phases. Experimentally, it is now possible to generate laser pulses of durations of only a few tens…

Chemical Physics · Physics 2017-05-18 David Ayuso

Tunnel ionization of room-temperature D$_2$ in an ultrashort (12 femtosecond) near infra-red (800 nm) pump laser pulse excites a vibrational wavepacket in the D2+ ions; a rotational wavepacket is also excited in residual D2 molecules. Both…

We study the quantum dynamics of a material wavepacket bouncing off a modulated atomic mirror in the presence of a gravitational field. We find the occurrence of coherent accelerated dynamics for atoms. The acceleration takes place for…

Quantum Physics · Physics 2009-11-13 Farhan Saif , Pierre Meystre

Matter-wave interferometry with molecules is intriguing both because it demonstrates a fundamental quantum phenomenon and because it opens avenues to quantum-enhanced measurements in physical chemistry. One great challenge in such…

The toolbox for imaging molecules is well-equipped today. Some techniques visualize the geometrical structure, others the electron density or electron orbitals. Molecules are many-body systems for which the correlation between the…

The present paper describes the experimental implementation of a measuring technique employing a slowly moving, near resonant, optical standing wave in the context of trapped ions. It is used to measure several figures of merit that are…

Quantum Physics · Physics 2015-05-28 A. Walther , U. Poschinger , K. Singer , F. Schmidt-Kaler

Atoms with a highly excited electron, called Rydberg atoms, can form unusual types of molecular bonds. The bond differs from the well known ionic and covalent bonds not only by its binding mechanism, but also by its bond length ranging up…

Atomic Physics · Physics 2022-05-20 N. Zuber , V. S. V. Anasuri , M. Berngruber , Y. -Q. Zou , F. Meinert , R. Löw , T. Pfau

Knowledge of molecular structure is paramount in understanding, and ultimately influencing, chemical reactivity. For nearly a century, diffractive imaging has been used to identify the structures of many biologically-relevant gas-phase…

Chemical Physics · Physics 2020-03-09 Kasra Amini , Jens Biegert

The ability to directly follow and time resolve the rearrangement of the nuclei within molecules is a frontier of science that requires atomic spatial and few-femtosecond temporal resolutions. While laser induced electron diffraction can…

The coherence of light from independent ensembles of elementary atomic emitters plays a paramount role in diverse areas of modern optics. We demonstrate the interference of photons scattered from independent ensembles of warm atoms in…

Quantum Physics · Physics 2026-02-19 Jaromír Mika , Stuti Joshi , Lukáš Lachman , Robin Kaiser , Lukáš Slodička

Since the discovery of electron-wave duality, electron scattering instrumentation has developed into a powerful array of techniques for revealing the atomic structure of matter. Beyond detecting local lattice variations in equilibrium…

Streaking of photoelectrons has long been used for the temporal characterization of attosecond extreme ultraviolet pulses. When the time-resolved photoelectrons originate from a coherent superposition of electronic states, they carry an…

Chemical Physics · Physics 2016-07-27 Markus Kowalewski , Kochise Bennett , Jérémy R. Rouxel , Shaul Mukamel

We explore the laser-induced ionization dynamics of N2 and CO2 molecules subjected to a few-cycle, linearly polarized, 800\,nm laser pulse using effective two-dimensional single active electron time-dependent quantum simulations. We show…

Atomic Physics · Physics 2012-10-02 Michel Peters , Tung Nguyen-Dang , Eric Charron , Arne Keller , Osman Atabek

The capability of generating two intense, femtosecond x-ray pulses with controlled time delay opens the possibility of performing time-resolved experiments for x-ray induced phenomena. We have applied this capability to study the…

Exposing a molecule to intense light pulses may bring this molecule to a nonstationary quantum state, thus launching correlated dynamics of electronic and nuclear subsystems. Although much had been achieved in the understanding of…

Chemical Physics · Physics 2024-04-11 Nikolay V. Golubev , Jiří Vaníček

X-ray photoelectron diffraction is a powerful tool for determining the structure of clean and adsorbate-covered surfaces. Extending the technique into the ultrafast time domain will open the door to studies as diverse as the direct…

Molecular rotational spectroscopy based on strong-field-ionization-induced nitrogen laser is employed to investigate the time evolution of the rotational wave packet composed by a coherent superposition of quantum rotational states created…

The coupling of electronic and nuclear motion in polyatomic molecules is at the heart of attochemistry. The molecular properties, transient structures and reaction mechanism of these many-body quantum objects are defined on the level of…

Chemical Physics · Physics 2024-03-12 David Schwickert , Andreas Przystawik , Dian Diaman , Detlef Kip , Jon P. Marangos , Tim Laarmann