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Effective potentials of the relativistic m\alpha^6 order correction for the ground state of the Coulomb two-center problem are calculated. They can be used to evaluate the relativistic contribution of that order to the energies of hydrogen…

Atomic Physics · Physics 2007-11-26 V. I. Korobov , Ts. Tsogbayar

The relativistic second-order corrections at orders $m\alpha^6$ and $m\alpha^6(m/M)$ in hydrogen molecular ions are calculated. Convergence of numerical results is studied, which allows estimating the relative numerical uncertainty to be…

Atomic Physics · Physics 2025-06-30 Vladimir I. Korobov , Jean-Philippe Karr , Zhen-Xiang Zhong

Accurate predictions for hydrogen molecular levels require the treatment of electrons and nuclei on an equal footing. While nonrelativistic theory has been effectively formulated this way, calculation of relativistic and quantum…

Chemical Physics · Physics 2024-01-24 Krzysztof Pachucki , Jacek Komasa

The major goal of the high-precision studies of ro-vibrational states in the hydrogen molecular ions is to provide an alternative way for improving the electron-to-proton mass ratio, or the atomic mass of electron. By now the complete set…

Atomic Physics · Physics 2008-04-16 V. I. Korobov

The effective Hamiltonian of $m\alpha^6$ and $m\alpha^6(m/M)$ order corrections for hydrogen molecular ions has been derived in [ Z.-X. Zhong, \emph{et al.}, Phys. Rev. A {\bf98}, 032502(2018).], in this work we express the energy…

Atomic Physics · Physics 2026-03-17 Zhen-Xiang Zhong , Ping Yang , Vladimir I. Korobov , Chun Li , Ting-Yun Shi

The recoil correction of order $(Z\alpha)^6(m/M)m$ to the hydrogen energy levels is recalculated and a discrepancy existing in the literature on this correction for the 1S energy level, is resolved. An analytic expression for the correction…

High Energy Physics - Phenomenology · Physics 2014-11-17 Michael I. Eides , Howard Grotch

We recalculate the leading relativistic corrections for the ground electronic state of the hydrogen molecule using variational method with explicitly correlated functions which satisfy the interelectronic cusp condition. The new…

Chemical Physics · Physics 2017-05-31 Mariusz Puchalski , Jacek Komasa , Krzysztof Pachucki

The $m \alpha^6$ correction to energy is expressed in terms of an effective Hamiltonian $H^{(6)}$ for an arbitrary state of helium. Numerical calculations are performed for $n=2$ levels, and the previous result for the $2^3P$ centroid is…

Atomic Physics · Physics 2009-11-13 Krzysztof Pachucki

The finite operators are derived for the recoil $m\alpha^6(m/M)$ order relativistic corrections (to spin-averaged energy levels) in hydrogen-like atoms and ions in the two- and three-body formalism beyond the adiabatic approximation.…

Atomic Physics · Physics 2025-08-12 Vladimir I Korobov

Several new corrections of order $m\alpha^6$ to the energy levels of $S$ states in helium are obtained from radiative corrections to the Breit potential and from the polarization insertions in the two photon exchange graphs. While…

High Energy Physics - Phenomenology · Physics 2007-05-23 Michael I. Eides , Howard Grotch

We calculate ionization energies and fundamental vibrational transitions for H$_2^+$, D$_2^+$, and HD$^+$ molecular ions. The NRQED expansion for the energy in terms of the fine structure constant $\alpha$ is used. Previous calculations of…

Atomic Physics · Physics 2017-06-14 Vladimir I. Korobov , Laurent Hilico , Jean-Philippe Karr

The analytical calculation of the complete $\alpha\,(Z\,\alpha)^6$ one-loop radiative correction to energies of two-body systems with the angular momenta $l>0$, consisting of a pointlike particle and an extended-size nucleus with arbitrary…

Atomic Physics · Physics 2024-08-13 Vojtěch Patkóš , Krzysztof Pachucki

We derive quantum electrodynamics corrections to the fine structure in three-electron atomic systems at $m \alpha^6$ and $m \alpha^7 \ln \alpha$ orders and present their numerical evaluations for the Li atom and Be$^+$ ion.

Atomic Physics · Physics 2015-06-09 Mariusz Puchalski , Krzysztof Pachucki

Radiative corrections to the decay rate of n=2 states of hydrogenic ions are calculated. The transitions considered are the M1 decay of the 2s state to the ground state and the E1(M2) decays of the $2p_{1/2}$ and $2p_{3/2}$ states to the…

High Energy Physics - Phenomenology · Physics 2009-11-10 J. Sapirstein , K. Pachucki , K. T. Cheng

We perform quantum electrodynamic calculations of the ionization energy of the $1s3d$ states of the $^4$He atom, including a complete evaluation of the $m\alpha^6$ correction. We find a large contribution from the nonradiative part of this…

We consider quantum electrodynamics (QED) corrections to the fine splitting $E(2P_{3/2}) - E(2P_{1/2})$ in the Li atom. We derive complete formulas for the $m\,\alpha^6$ and $m\,\alpha^7\,\ln\alpha$ contributions and calculate them…

Atomic Physics · Physics 2015-06-19 Mariusz Puchalski , Krzysztof Pachucki

NRQED approach to the fine and hyperfine structure corrections of order m$\alpha$ 6 and m$\alpha$ 6 (m/M)-Application to the hydrogen atom The NRQED approach is applied to the calculation of relativistic corrections to the fine and…

Atomic Physics · Physics 2020-02-12 Mohammad Haidar , Zhen-Xiang Zhong , Vladimir I. Korobov , Jean-Philippe Karr

State-dependent quantum electrodynamic corrections are evaluated for the hyperfine splitting of nS states for arbitrary principal quantum number n. The calculations comprise both the self-energy and the vacuum-polarization correction of…

Atomic Physics · Physics 2007-05-23 Ulrich D. Jentschura , Vladimir A. Yerokhin

The m\alpha^6(m/M) order corrections to the hyperfine splitting in the H_2^+ ion are calculated. That allows to reduce uncertainty in the frequency intervals between hyperfine sublevels of a given rovibrational state to about 10 ppm.…

Atomic Physics · Physics 2009-05-12 V. I. Korobov , L. Hilico , J. -Ph. Karr

Quantum electrodynamical (QED) calculations of ionization energies of the $1snd\,D$ states are performed for the helium atom. We reproduce the previously known relativistic and QED effects up to order $m\alpha^5$ and extend the theory by…

Atomic Physics · Physics 2020-07-14 Vladimir A. Yerokhin , Vojtěch Patkóš , Mariusz Puchalski , Krzysztof Pachucki
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