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Pulsed laser excitation of a dense ultracold Cs vapor has been used to study the pairwise interactions between Cs atoms excited to $n$p$_{3/2}$ Rydberg states of principal quantum numbers in the range $n=22-36$. Molecular resonances were…

Atomic Physics · Physics 2015-09-14 Heiner Saßmannshausen , Frédéric Merkt , Johannes Deiglmayr

The lifetimes of the lower-lying vibrational states of ultralong-range strontium Rydberg molecules comprising one ground-state 5s2 1S0 atom and one Rydberg atom in the 5s38s 3S1 state are reported. The molecules are created in an ultracold…

We report on the formation of ultralong-range Rydberg D-state molecules via photoassociation in an ultracold cloud of rubidium atoms. By applying a magnetic offset field on the order of 10 G and high resolution spectroscopy, we are able to…

Rydberg atoms are remarkable tools for the quantum simulation of spin arrays. Circular Rydberg atoms open the way to simulations over very long time scales, using a combination of laser trapping of the atoms and spontaneous-emission…

We have studied the associative ionization of a Rydberg atom and a ground state atom in an ultracold Rydberg gas. The measured scattering cross section is three orders of magnitude larger than the geometrical size of the produced molecule.…

Atomic Physics · Physics 2017-08-24 Thomas Niederprüm , Oliver Thomas , Torsten Manthey , Tobias M. Weber , Herwig Ott

A combined experimental and theoretical spectroscopic study of high-$n$, ${30 \lesssim n \lesssim 100}$, triplet $\text{S}$ and $\text{D}$ Rydberg states in $^{87}\text{Sr}$ is presented. $^{87}\text{Sr}$ has a large nuclear spin,…

Atomic Physics · Physics 2018-10-17 R. Ding , J. D. Whalen , S. K. Kanungo , T. C. Killian , F. B. Dunning , S. Yoshida , J. Burgdörfer

We observe that when an ultracold ground state cesium (Cs) atom becomes bound within the electronic cloud of an extended Cs electronic orbit, ultralong-range molecules with giant (kilo-Debye) permanent electric dipole moments form. Large…

Atomic Physics · Physics 2015-06-23 Donald Booth , Seth Rittenhouse , Jin Yang , Hossein Sadeghpour , James Shaffer

Rydberg spin waves are optically excited in a quasi-one-dimensional atomic sample of Rb atoms. Pair-wise spin-wave correlations are observed by a spatially selective transfer of the quantum state onto a light field and photoelectric…

Atomic Physics · Physics 2015-06-05 Y. O. Dudin , F. Bariani , A. Kuzmich

We study a gas of ultracold atoms resonantly driven into a strongly interacting Rydberg state. The long distance behavior of the spatially frozen effective pseudospin system is determined by a set of dimensionless parameters, and we find…

We propose a novel scheme to efficiently tune the scattering length of two colliding ground-state atoms by off-resonantly coupling the scattering-state to an excited Rydberg-molecular state using laser light. For the s-wave scattering of…

Quantum Gases · Physics 2017-10-04 Nóra Sándor , Rosario González-Férez , Paul S. Julienne , Guido Pupillo

We explore the electronic structure of ultralong-range pentaatomic Rydberg molecules from a merger of a Rydberg atom and two ground state heteronuclear diatomic molecules. Our focus is on the interaction of Rb($23s$) and Rb($n=20$, $l\ge…

We report the creation of heteronuclear ultralong-range Rydberg-molecule dimers by excitation of minority $^{88}\text{Sr}$ atoms to $5sns\,^3S_1$ Rydberg states ($n=31-39$) in a dense background of $^{84}\text{Sr}$. We observe an isotope…

Atomic Physics · Physics 2020-07-01 J. D. Whalen , S. K. Kanungo , Y. Lu , S. Yoshida , J. Burgörfer , F. B. Dunning , T. C. Killian

We propose a scheme for constructing versatile quantum simulators using ultracold Rydberg atoms in long-lived circular and elliptical states. By exciting different subspaces of internal atomic states, the atoms can be used to simulate two…

Quantum Physics · Physics 2025-03-31 Jacek Dobrzyniecki , Paula Heim , Michał Tomza

We explore the external electric field control of a species of ultralong-range molecules that emerge from the interaction of a ground state polar molecule with a Rydberg atom. The external field mixes the Rydberg electronic states and…

Atomic Physics · Physics 2012-06-01 M. Mayle , S. T. Rittenhouse , P. Schmelcher , H. R. Sadeghpour

The properties and behaviour of a Ring Rydberg Composite are explicated. This system consists of a ring of ground state atoms centered on a Rydberg atom, whose electron elastically scatters off the ground state atoms. We transform the…

Atomic Physics · Physics 2020-02-19 Matthew T. Eiles , Andrew L. Hunter , Jan M. Rost

We observe the direct excitation of pairs of Cs atoms from the ground state to molecular states correlating asymptotically to $ns\,n'f$ asymptotes. The molecular resonances are interpreted as originating from the dipole-quadrupole…

Atomic Physics · Physics 2014-12-02 Johannes Deiglmayr , Heiner Saßmannshausen , Pierre Pillet , Frédéric Merkt

We investigate the electronic structure of a triatomic Rydberg molecule formed by a Rydberg atom and two neutral ground-state atoms. Taking into account the $s$-wave and $p$-wave interactions we perform electronic structure calculations and…

Atomic Physics · Physics 2016-06-22 Javier Aguilera Fernández , Peter Schmelcher , Rosario González-Férez

We probe resonant dipolar interactions between ultracold $^{40}$K$^{87}$Rb molecules and Rydberg $^{87}$Rb atoms in an optically trapped ensemble. Through state-selective ionization detection of the KRb molecules, we observe resonant energy…

Atomic Physics · Physics 2025-04-10 Lingbang Zhu , Jeshurun Luke , Roy Shaham , Yi-Xiang Liu , Kang-Kuen Ni

When ultracold plasma is generated using photonization of laser cooled atoms, some atoms reach only upto Rydberg states. These in turn interact with the free electrons of the plasma and get ionized further. We study the interaction of…

Atomic Physics · Physics 2026-03-18 Satyam Prakash , Ashok S Vudayagiri

We consider dynamics of a Rydberg impurity in a cloud of ultracold bosonic atoms in which the Rydberg electron can undergo spin-changing collisions with surrounding atoms. This system realizes a new type of the quantum impurity problem that…

Quantum Gases · Physics 2019-11-04 Yuto Ashida , Tao Shi , Richard Schmidt , H. R. Sadeghpour , J. Ignacio Cirac , Eugene Demler