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Metallic alloys often form phases - known as solid solutions - in which chemical elements are spread out on the same crystal lattice in an almost random manner. The tendency of certain chemical motifs to be more common than others is known…

Materials Science · Physics 2024-06-21 Killian Sheriff , Yifan Cao , Tess Smidt , Rodrigo Freitas

In high-entropy alloys (HEAs), the local chemical fluctuations from disordered solute solution state into segregation, precipitation and ordering configurations are complex due to the large number of elements. In this work, the cluster…

Materials Science · Physics 2017-05-05 A. Fernandez-Caballero , J. S. Wrobel , P. M. Mummery , D. Nguyen-Manh

Tailoring the performance of next-generation high entropy materials requires a deep understanding of the competition between entropy-driven random solid solution and enthalpy-driven chemical ordering. Investigating such order and disorder…

Materials Science · Physics 2026-03-24 Fanli Zhou , Hao Chen , Pengxiang Xu , Kai Yang , Zongrui Pei , Xianglin Liu

A central problem in multicomponent lattice systems is to systematically quantify multi-point ordering. Ordering in such systems is often described in terms of pairs, even though this is not sufficient when three-point and higher-order…

Materials Science · Physics 2021-08-18 James M. Goff , Bryant Y. Li , Susan B. Sinnott , Ismaila Dabo

The chemical short-range order (CSRO) in the crystalline materials influences the properties and its effect is particularly important in the context of the multicomponent materials. We propose a scheme for CSRO parameter or…

Materials Science · Physics 2022-10-20 G. Anand , Swarnava Ghosh , Markus Eisenbach

We present theoretical study of ordering phenomena in binary $C_{1-x}B_{x}$, $C_{1-x}N_{x}$ and ternary $B_{x}C_{1-x-y}N_{y}$ alloys forming two-dimensional, graphene-like systems. For calculating energy of big systems (20 000 atoms in the…

Mesoscale and Nanoscale Physics · Physics 2017-01-11 Agnieszka Jamróz , Jacek A. Majewski

Short-range order (SRO) in Fe-rich Fe-Cr alloys is investigated by means of atomistic off-lattice Monte Carlo simulations in the semi-grand canonical ensemble using classical interatomic potentials. The SRO parameter defined by Cowley…

Materials Science · Physics 2010-09-03 Paul Erhart , Alfredo Caro , Magdalena Serrano de Caro , Babak Sadigh

On the basis of the assumption that atoms play a role of effective Fermions at lattice distribution, the study of the long-range ordering is shown to be reduced to self-consistent consideration of single and collective excitations being…

Statistical Mechanics · Physics 2007-05-23 A. I. Olemskoi

Local, or short-range, order in disordered alloys is an important and exciting phenomenon which is quantified in electron, X-ray and neutron scattering experiments. It is discussed in many excellent reviews and books, as well as in the…

Statistical Mechanics · Physics 2007-05-23 Igor Tsatskis

Based on an analysis of the short range chemical environment of each atom in a system, standard machine learning based approaches to the construction of interatomic potentials aim at determining directly the central quantity which is the…

Materials Science · Physics 2015-08-05 S. Alireza Ghasemi , Albert Hofstetter , Santanu Saha , Stefan Goedecker

Recent experiments show that charge-density-wave correlations are prevalent in underdoped cuprate superconductors. The correlations are short ranged at weak magnetic fields but their intensity and spatial extent increase rapidly at low…

Superconductivity · Physics 2016-01-20 Yosef Caplan , Gideon Wachtel , Dror Orgad

To obtain comprehensive performance, heavy elements were added into superalloys for solid solution hardening. In this article, it is found by scanning transmission electron microscope observation that rather than distribute randomly…

Materials Science · Physics 2017-02-08 Yushi Luo , Lihui Zhang , Yumei Wang , Binghui Ge , Wei Guo , Jie Zhan , Jianxin zhang , Jing Zhu

As pointed out by Linus Pauling in his classic work on the relationship between crystal packing and ionic radius ratio, a difference in atomic size can be accommodated more readily by an ordered structure than by a disordered one. Because…

Materials Science · Physics 2007-05-23 Dean J. Lee , Jong K. Lee

Chemical short-range order (SRO) affects the distribution of elements throughout the solid-solution phase of metallic alloys, thereby modifying the background against which microstructural evolution occurs. Investigating such…

Materials Science · Physics 2024-07-10 Yifan Cao , Killian Sheriff , Rodrigo Freitas

Crystalline materials have atomic-scale fluctuations in their chemical composition that modulate various mesoscale properties. Establishing chemistry-microstructure relationships in such materials requires proper characterization of these…

Materials Science · Physics 2024-10-01 Killian Sheriff , Yifan Cao , Rodrigo Freitas

The exceptional mechanical strengths of medium and high-entropy alloys have been attributed to hardening in random solid solutions. Here, we evidence non-random chemical mixings in CrCoNi alloys, resulting from short range ordering. A novel…

Materials Science · Physics 2022-06-07 H. W. Hsiao , R. Feng , H. Ni , K. An , J. D. Poplawsky , P. K. Liaw , J. M. Zuo

Effects of size and charge asymmetry between oppositely charged ions or particles on spatial inhomogeneities are studied for a large range of charge and size ratios. We perform a stability analysis of the primitive model (PM) of ionic…

Soft Condensed Matter · Physics 2013-05-30 O. Patsahan , A. Ciach

Amorphous interfacial complexions have been shown to restrict grain growth and improve damage tolerance in nanocrystalline alloys, with increased chemical complexity stabilizing the complexions themselves. Here, we investigate local…

Materials Science · Physics 2026-03-05 Esther C. Hessong , Zhengyu Zhang , Tianjiao Lei , Mingjie Xu , Toshihiro Aoki , Timothy J. Rupert

We present a thorough theoretical study of ordering phenomena in nitride ternary alloys GaInN, AlInN, and AlGaN. Using the Monte Carlo approach and energetics based on the Keating model we analyze the influence of various factors on…

Materials Science · Physics 2015-03-19 Michal Lopuszynski , Jacek A. Majewski

Traditional metallic alloys are mixtures of elements where the atoms of minority species tend to distribute randomly if they are below their solubility limit, or lead to the formation of secondary phases if they are above it. Recently, the…

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