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We investigate the electro-optic properties of black phosphorus (BP) thin films for optical modulation in the mid-infrared frequencies. Our calculation indicates that an applied out-of-plane electric field may lead to red-, blue-, or…

Mesoscale and Nanoscale Physics · Physics 2016-04-20 Charles Lin , Roberto Grassi , Tony Low , Amr S. Helmy

LSCF is a promising candidate for the cathode in SOFCs. Understanding the microstructural characteristics is crucial to its application because they predominately determine the performance and durability of the porous cathodes and hence of…

Materials Science · Physics 2015-02-10 Zhangwei Chen

We study the mechanical and electronic properties of heterobilayers composed of black phosphorus (BP) on hexagonal boron nitride (hBN) and of blue phosphorus (\Pblue) on hBN by means of ab-intio density functional theory. Emphasis is put on…

Materials Science · Physics 2020-07-15 Baptiste Bienvenu , Hakim Amara , François Ducastelle , Lorenzo Sponza

Black phosphorene is not stable at ambient conditions, so atomic defects and oxidation effects are unavoidable in black phosphorus samples in the experiment. The effects of these defects on the performance of the black phosphorus…

Materials Science · Physics 2017-04-05 Cui-Xia Wang , Chao Zhang , Jin-Wu Jiang , Timon Rabczuk

Black phosphorous (BP) is is recently unveiled as a promising two-dimensional direct bandgap semiconducting material. Here, we report the ambipolar field effect transistor behavior of multilayers of BP with ferromagnetic tunnel contacts. We…

Mesoscale and Nanoscale Physics · Physics 2014-07-07 M. Venkata Kamalakar , B. N Madhushankar , André Dankert , Saroj P. Dash

Black phosphorus (BP) offers considerable promise for infrared and visible photonics. Efficient tuning of the bandgap and higher subbands in BP by modulation of the Fermi level or application of vertical electric fields has been previously…

The mechanical properties of single-layer black phosphrous under uniaxial deformation are investigated using first-principles calculations. Both Young's modulus and the ultimate strain are found to be highly anisotropic and nonlinear as a…

Materials Science · Physics 2015-03-06 Jin-Wu Jiang , Harold S. Park

We have calculated numerically electron exchange, correlation energies and dynamical polarization function for newly discovered silicene, germanene and black phosphorus (BP), consisting of puckered layers of elemental phosphorus atoms,…

Mesoscale and Nanoscale Physics · Physics 2016-05-30 Andrii Iurov , Godfrey Gumbs , Danhong Huang

Although monolayer black phosphorus (BP) or phosphorene has been successfully exfoliated and its optical properties have been explored, most of electrical performance of the devices is demonstrated on few-layer phosphorene and ultra-thin BP…

Materials Science · Physics 2014-11-05 Yuchen Du , Han Liu , Yexin Deng , Peide D. Ye

Black phosphorous is a layered material having a high capacity of 2596 mAh/g as a battery electrode, however it suffers from cracking due to high volume expansion during lithiation. These cracks causes loss of electrical contact in the…

Materials Science · Physics 2020-07-21 Burak Ozdemir

The liquid-phase exfoliation (LPE) of black phosphorus (BP) is a strategic route for the large-scale production of phosphorene and few-layer BP (FL-BP) flakes. The exploitation of this exfoliated material in cutting-edge technologies, e.g.,…

Carbon nanostructures are promising ballistic protection materials, due to their low density and excellent mechanical properties. Recent experimental and computational investigations on the behavior of graphene under impact conditions…

As mechanical structures enter the nanoscale regime, the influence of van der Waals forces increases. Graphene is attractive for nanomechanical systems because its Young's modulus and strength are both intrinsically high, but the mechanical…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 Steven P. Koenig , Narasimha G. Boddeti , Martin L. Dunn , J. Scott Bunch

The recent isolation of atomically thin black phosphorus by mechanical exfoliation of bulk layered crystals has triggered an unprecedented interest, even higher than that raised by the first works on graphene and other two-dimensional, in…

Mesoscale and Nanoscale Physics · Physics 2015-10-21 Andres Castellanos-Gomez

Phosphorene, a two-dimensional (2D) monolayer of black phosphorus, has attracted considerable theoretical interest, although the experimental realization of monolayer, bilayer, and few-layer flakes has been a significant challenge. Here we…

Two-dimensional crystals are emerging materials for nanoelectronics. Development of the field requires candidate systems with both a high carrier mobility and, in contrast to graphene, a sufficiently large electronic bandgap. Here we…

Materials Science · Physics 2014-07-08 Jingsi Qiao , Xianghua Kong , Zhi-Xin Hu , Feng Yang , Wei Ji

Based on extensive first principle calculations, we explore the thickness dependent effective di- electric constant and slab polarizability of few layer black phosphorene. We find that the dielectric constant in ultra-thin phosphorene is…

Mesoscale and Nanoscale Physics · Physics 2016-06-08 Piyush Kumar , B. S. Bhadoria , Sanjay Kumar , Somnath Bhowmick , Yogesh Singh Chauhan , Amit Agarwal

Thin layers of black phosphorus have recently raised interest for their two-dimensional (2D) semiconducting properties, such as tunable direct bandgap and high carrier mobilities. This lamellar crystal of P atoms stacked together by weak…

Mesoscale and Nanoscale Physics · Physics 2014-08-22 A. Favron , E. Gaufrès , F. Fossard , P. L. Lévesque , A-L. Phaneuf-L'Heureux , N. Y-W. Tang , A. Loiseau , R. Leonelli , S. Francoeur , R. Martel

With a semiconducting band gap and high charge carrier mobility, two-dimensional (2D) black phosphorus (BP), often referred to as phosphorene, holds significant promise for next generation electronics and optoelectronics. However, as a 2D…

Materials Science · Physics 2015-02-10 Xiaolong Liu , Joshua D. Wood , Kan-Sheng Chen , EunKyung Cho , Mark C. Hersam

Low-dimensional systems based on black phosphorus (BP) have recently attracted much interest. Since the crystal structure of BP consists of 2D layers with a strong in-plane anisotropy, its electronic properties at a high magnetic field…

Mesoscale and Nanoscale Physics · Physics 2025-03-26 H. Okamura , S. Iguchi , T. Sasaki , Y. Ikemoto , T. Moriwaki , Y. Akahama