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We present a scheme to construct model potentials, with parameters computed from first principles, for large-scale lattice-dynamical simulations of materials. Our method mimics the traditional solid-state approach to the investigation of…

Materials Science · Physics 2013-12-04 Jacek C. Wojdeł , Patrick Hermet , Mathias P. Ljungberg , Philippe Ghosez , Jorge Íñiguez

We present a first-principles-based (second-principles) scheme that permits large-scale materials simulations including both atomic and electronic degrees of freedom on the same footing. The method is based on a predictive…

Materials Science · Physics 2016-06-08 Pablo García-Fernández , Jacek C. Wojdeł , Jorge Íñiguez , Javier Junquera

We show how to construct Landau-like free energy potentials using a machine-learning approach. For concreteness, we focus on perovskite oxide PbTiO$_{3}$. We work with a training set obtained from Monte Carlo simulations based on an…

Materials Science · Physics 2025-08-01 Mauro Pulzone , Natalya S. Fedorova , Hugo Aramberri , Jorge Íñiguez-González

First principles predictions of lattice dynamics are of vital importance for a broad range of topics in materials science and condensed matter physics. The large-scale nature of lattice dynamics calculations and the desire to design novel…

Materials Science · Physics 2023-01-23 Jinliang Ning , James W. Furness , Jianwei Sun

The first-principles-based effective Hamiltonian scheme provides one of the most accurate modeling technique for large-scale structures, especially for ferroelectrics. However, the parameterization of the effective Hamiltonian is…

In the first-principles bulk-layer model the superlattice structure and polarization are determined by first-principles computation of the bulk responses of the constituents to the electrical and mechanical boundary conditions in an…

Materials Science · Physics 2019-03-27 J. Bonini , J. W. Bennett , P. Chandra , K. M. Rabe

An accurate and easily extendable method to deal with lattice dynamics of solids is offered. It is based on first-principles molecular dynamics simulations and provides a consistent way to extract the best possible harmonic - or higher…

Materials Science · Physics 2013-10-14 Olle Hellman , I. A. Abrikosov , S. I. Simak

We propose a systematic procedure for constructing effective lattice fermion models for narrow-band compounds on the basis of first-principles electronic structure calculations. The method is illustrated for the series of transition-metal…

Strongly Correlated Electrons · Physics 2009-11-11 I. V. Solovyev

We present a systematic, quasi-automated methodology for generating electronic models in the framework of second-principles density functional theory (SPDFT). This approach enables the construction of accurate and computationally efficient…

The application of first-principles calculations for predicting lattice thermal conductivity (LTC) in crystalline materials, in conjunction with the linearized phonon Boltzmann equation, has gained increasing popularity. In this…

Materials Science · Physics 2024-05-14 Atsushi Togo , Atsuto Seko

Halide perovskites have been extensively studied as materials of interest for optoelectronic applications. There is a major emphasis on ways to tailor the stability, defect behavior, electronic band structure, and optical absorption in…

Materials Science · Physics 2023-09-29 Jiaqi Yang , Arun Mannodi-Kanakkithodi

Ferroelectric perovskites have been ubiquitously applied in piezoelectric devices for decades, among which, eco-friendly lead-free (K,Na)NbO3-based materials have been recently demonstrated to be an excellent candidate for sustainable…

Materials Science · Physics 2023-01-18 Hao-Cheng Thong , XiaoYang Wang , Han Wang , Linfeng Zhang , Ke Wang , Ben Xu

In this work we introduce a new semi-implicit second order correction scheme to the kinetic Kohn-Sham lattice model. The new approach is validated by performing realistic exchange-correlation energy calculations of atoms and dimers of the…

Materials Science · Physics 2016-06-15 Sergio Solorzano , Miller Mendoza , Hans Herrmann

In the development of first-principles high-throughput searches for materials with desirable functional properties, there is a clear need for an efficient method to determine the ground state and low-energy alternative structures of…

Materials Science · Physics 2014-06-25 Yuanjun Zhou , Karin M. Rabe

Parameter-free calculations of lattice dynamics from first principles have achieved significant progress in the past decades, with a wealth of applications in thermodynamics, phase transitions, and transport properties of materials. Current…

Materials Science · Physics 2025-08-05 Changpeng Lin , Jian Han , Ben Xu , Nicola Marzari

The large-scale search for high-performing candidate 2D materials is limited to calculating a few simple descriptors, usually with first-principles density functional theory calculations. In this work, we alleviate this issue by extending…

Materials Science · Physics 2020-07-07 Victor Venturi , Holden Parks , Zeeshan Ahmad , Venkatasubramanian Viswanathan

We present a computationally efficient general first-principles based method for spin-lattice simulations for solids. Our method is based on a combination of atomistic spin dynamics and molecular dynamics, expressed through a spin-lattice…

First-principles based crystal structure prediction (CSP) methods have revealed an essential tool for the discovery of new materials. However, in solids close to displacive phase transitions, which are common in ferroelectrics,…

Materials Science · Physics 2026-04-17 Hao Gao , Yue-Wen Fang , Ion Errea

Design of novel artificial materials based on ferroelectric perovskites relies on the basic principles of electrostatic coupling and in-plane lattice matching. These rules state that the out-of-plane component of the electric displacement…

Materials Science · Physics 2016-01-20 Claudio Cazorla , Massimiliano Stengel

Molecules can form myriad crystalline polymorphs, each with distinct properties affecting their performance across diverse applications, from pharmaceuticals to functional materials and more. Predicting the thermodynamically most stable…

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