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This paper describes a method to do ab initio molecular dynamics in electronically excited systems within the random phase approximation (RPA). Using a dynamical variational treatment of the RPA frequency, which corresponds to the…

Condensed Matter · Physics 2009-10-31 Eric R. Bittner , D. S. Kosov

An algorithm is presented which computes a translationally invariant matrix product state approximation of the ground state of an infinite 1D system; it does this by embedding sites into an approximation of the infinite ``environment'' of…

Other Condensed Matter · Physics 2008-08-18 Gregory M. Crosswhite , Andrew C. Doherty , Guifre Vidal

The random-phase approximation has been used to compute the properties of parabolic two-dimensional quantum dots beyond the mean-field approximation. Special emphasis is put on the ground state correlation energy, the symmetry restoration…

Mesoscale and Nanoscale Physics · Physics 2009-02-06 Llorens Serra , Rashid G. Nazmitdinov , A. Puente

We study the electromagnetic responses of $^4$He within the framework of the self-consistent continuum random phase approximation theory. In this approach the ground state properties are described by a Hartree-Fock calculation. The single…

Nuclear Theory · Physics 2015-05-30 V. De Donno , M. Anguiano , G. Co' , A. M. Lallena

In this paper, we study 1-d random Schr\"odinger operators on a finite interval with Dirichlet boundary conditions. We are interested in the approximation of the ground state energy using the minimum of the effective potential. For the 1-d…

Spectral Theory · Mathematics 2022-07-05 Ilias Chenn , Wei Wang , Shiwen Zhang

The calculation time for the energy of atoms and molecules scales exponentially with system size on a classical computer but polynomially using quantum algorithms. We demonstrate that such algorithms can be applied to problems of chemical…

Quantum Physics · Physics 2007-05-23 Alán Aspuru-Guzik , Anthony D. Dutoi , Peter J. Love , Martin Head-Gordon

The Faddeev Random Phase Approximation is a Green's function technique that makes use of Faddeev-equations to couple the motion of a single electron to the two-particle--one-hole and two-hole--one-particle excitations. This method goes…

Computational Physics · Physics 2015-05-20 Matthias Degroote , Dimitri Van Neck , Carlo Barbieri

We apply the analytically solvable model of two electrons in two orbitals to diradical molecules, characterized by two unpaired electrons. The effect of the doubly occupied and empty orbitals is taken into account by means of random phase…

Chemical Physics · Physics 2025-11-20 Reza G. Shirazi , Vladimir V. Rybkin , Michael Marthaler , Dmitry S. Golubev

It is exponentially hard to simulate quantum systems by classical algorithms, while quantum computer could in principle solve this problem polynomially. We demonstrate such an quantum-simulation algorithm on our NMR system to simulate an…

Quantum Physics · Physics 2009-07-22 Jiangfeng Du , Nanyang Xu , Xinhua Peng , Pengfei Wang , Sanfeng Wu , Dawei Lu

Given a set of matrices, modeled as samples of a matrix-valued function, we suggest a method to approximate the underline function using a product approximation operator. This operator extends known approximation methods by exploiting the…

Numerical Analysis · Mathematics 2016-11-15 Nira Dyn , Uri Itai , Nir Sharon

A general but simple method is proposed to eliminate the quantum fluctuations generated by selected one-body operators in the excitation spectrum of a discrete RPA Hamiltonian. This method provides an outstanding tool for the removal of the…

Nuclear Theory · Physics 2009-11-10 F. Dönau

The population distribution within the ground-state of an atomic ensemble is of large significance in a variety of quantum optics processes. We present a method to reconstruct the detailed population distribution from a set of absorption…

Quantum Physics · Physics 2010-06-04 P. London , O. Firstenberg , M. Shuker , A. Ron

We present an approximation scheme for the calculation of the principal excitation energies and transition moments of finite many-body systems. The scheme is derived from a first order approximation to the self energy of a recently proposed…

Chemical Physics · Physics 2009-10-30 Joachim Brand , Lorenz S. Cederbaum

The interpretation of quantum mechanics due to Lande' is applied to the connection between wave mechanics and matrix mechanics. The connection between the differential eigenvalue equation and the matrix eigenvalue equation for an operator…

Quantum Physics · Physics 2007-05-23 Habatwa Vincent Mweene

A path integral ground state approach has been used to estimate the ground-state energy and structural properties of hydrogen fluoride molecules pinned to a one-dimensional lattice. In the simulations, the molecules are assumed to be rigid,…

Chemical Physics · Physics 2023-08-10 Tapas Sahoo , Gautam Gangopadhyay

System state estimation constitutes a key problem in several applications involving multi-agent system architectures. This rests upon the estimation of the state of each agent in the group, which is supposed to access only relative…

Systems and Control · Electrical Eng. & Systems 2021-07-16 Marco Fabris , Giulia Michieletto , Angelo Cenedese

The use of combinatorial optimization algorithms has contributed substantially to the major progress that has occurred in recent years in the understanding of the physics of disordered systems, such as the random-field Ising model. While…

Disordered Systems and Neural Networks · Physics 2023-02-22 Manoj Kumar , Martin Weigel

With rapid progress being made in the development of platforms for quantum computation, there has been considerable interest in whether present-day and near-term devices can be used to solve problems of relevance. A commonly cited…

The particle-particle random phase approximation (ppRPA) within the hole-hole channel was recently proposed as an efficient tool for computing excitation energies of point defects in solids [J. Phys. Chem. Lett. 2024, 15, 2757-2764]. In…

Chemical Physics · Physics 2024-06-27 Jiachen Li , Yu Jin , Jincheng Yu , Weitao Yang , Tianyu Zhu

The article considers parameter estimation constructing such as quasi-maximum likelyhood estimation and one step estimation in statistical models generated by solution of stochastic differential equation. It has been developed a software…

Statistics Theory · Mathematics 2021-03-12 Dmytro Ivanenko , Rostyslav Pogorielov