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We present a combined ion imaging and density functional theory study of the dynamics of the desorption process of rubidium and cesium atoms off the surface of helium nanodroplets upon excitation of the perturbed $6s$ and $7s$ states,…

Atomic and Molecular Clusters · Physics 2015-03-03 J. von Vangerow , A. Sieg , F. Stienkemeier , M. Mudrich , A. Leal , D. Mateo , A. Hernando , M. Barranco , M. Pi

The desorption of excited rubidium (Rb) atoms off the surface of helium (He) nanodroplets is studied in detail using femtosecond time-resolved photoion and photoelectron imaging spectroscopy in combination with quantum wave packet…

Atomic and Molecular Clusters · Physics 2018-10-17 N. V. Dozmorov , J. von Vangerow , J. A. M. Fordyce , F. Stienkemeier , A. V. Baklanov , M. Mudrich

The real-time dynamics of photoexcited and photoionized rubidium (Rb) atoms attached to helium (He) nanodroplets is studied by femtosecond pump-probe mass spectrometry. While excited Rb atoms in the perturbed 6p-state (Rb*) desorb off the…

Atomic and Molecular Clusters · Physics 2020-11-09 J. von Vangerow , O. John , andF. Stienkemeier , M. Mudrich

Highly excited states of rubidium (Rb) atoms attached to helium (He) nanodroplets are studied by two-photon ionization spectroscopy in combination with electron and ion imaging. Photoion spectra and angular distributions are in good…

Atomic and Molecular Clusters · Physics 2017-08-23 L. Fechner , B. Gruener , A. Sieg , C. Callegari , F. Ancilotto , F. Stienkemeier , M. Mudrich

The dynamics following the photoexcitation of Na and Li atoms located on the surface of helium nanodroplets has been investigated in a joint experimental and theoretical study. Photoelectron spectroscopy has revealed that excitation of the…

Atomic and Molecular Clusters · Physics 2017-08-23 Alberto Hernando , Manuel Barranco , Martí Pi , Evgeniy Loginov , Marina Langlet , Marcel Drabbels

The dynamics of vibrational wave packets in triplet states of rubidium dimers (Rb2) formed on helium nanodroplets are studied using femtosecond pump-probe photoionization spectroscopy. Due to fast desorption of the excited Rb2 molecules off…

Atomic and Molecular Clusters · Physics 2011-12-19 M. Mudrich , Ph. Heister , T. Hippler , Ch. Giese , O. Dulieu , F. Stienkemeier

The vibrational wave-packet dynamics of diatomic rubidium molecules (Rb2) in triplet states formed on the surface of superfluid helium nanodroplets is investigated both experimentally and theoretically. Detailed comparison of experimental…

Atomic and Molecular Clusters · Physics 2017-09-13 Barbara Grüner , Martin Schlesinger , Philipp Heister , Walter T. Strunz , Frank Stienkemeier , Marcel Mudrich

We thoroughly investigate vibrational quantum dynamics of dimers attached to He droplets motivated by recent measurements with K-2 [1]. For those femtosecond pump-probe experiments, crucial observed features are not reproduced by gas phase…

Chemical Physics · Physics 2012-03-15 Martin Schlesinger , Walter. T. Strunz

Rubidium dimers residing on the surface of He nanodroplets are doubly ionized by an intense fs laser pulse leading to fragmentation into a pair of $\mathrm{Rb^+}$ ions. We show that the kinetic energy of the $\mathrm{Rb^+}$ fragment ions…

The dynamics of vibrational wave packets excited in K$_2$ dimers attached to superfluid helium nanodroplets is investigated by means of femtosecond pump-probe spectroscopy. The employed resonant three-photon-ionization scheme is studied in…

Atomic and Molecular Clusters · Physics 2009-11-11 P. Claas , G. Droppelmann , C. P. Schulz , M. Mudrich , F. Stienkemeier

Besides the use as cold matrix for spectroscopic studies, superfluid helium droplets have served as a cold environment for the synthesis of molecules and clusters. Since vibrational frequencies of molecules in helium droplets exhibit almost…

Atomic and Molecular Clusters · Physics 2022-10-03 Florian Lackner , Wolfgang E. Ernst

Hybrid quantum systems made of cold atoms near nanostructured surfaces are expected to open up new opportunities for the construction of quantum sensors and for quantum information. For the design of such tailored quantum systems the…

Optics · Physics 2015-05-19 C. Stehle , H. Bender , F. Jessen , C. Zimmermann , S. Slama

An experimental pump-probe study of the photoassociative creation of translationally ultracold rubidium molecules is presented together with numerical simulations of the process. The formation of loosely bound excited-state dimers is…

Rotational dynamics of D$_2$ molecules inside helium nanodroplets is induced by a moderately intense femtosecond (fs) pump pulse and measured as a function of time by recording the yield of HeD$^+$ ions, created through strong-field…

The interactions of atomic and molecular hydrogen with bare interstellar dust grain surfaces are important for understanding H2 formation at relatively high temperatures (>20 K). We investigate the diffusion of physisorbed H atoms and the…

Astrophysics of Galaxies · Physics 2019-11-14 Masashi Tsuge , Tetsuya Hama , Yuki Kimura , Akira Kouchi , Naoki Watanabe

Alkali dimers, $\mathrm{Ak}_2$, located on the surface of a helium nanodroplet, are set into rotation through the polarizability interaction with a nonresonant 1-ps-long laser pulse. The time-dependent degree of alignment is recorded using…

We present an experimental study of the dynamics following the photo-excitation and subsequent photo-ionization of single Cs atoms on the surface of helium nanodroplets. The dynamics of excited-Cs-atom desorption and re-adsorption as well…

Atomic and Molecular Clusters · Physics 2021-10-18 Nicolas Rendler , Audrey Scognamiglio , Katrin Dulitz , Frank Stienkemeier , Manuel Barranco , Marti Pí , Nadine Halberstadt

Molecules immersed in liquid helium are excellent probes of superfluidity. Their electronic, vibrational and rotational dynamics provide valuable clues about the superfluid at the nanoscale. Here we report on the experimental study of the…

Quantum Physics · Physics 2023-04-11 Alexander A. Milner , V. A. Apkarian , Valery Milner

We demonstrate that a sodium dimer, Na$_{2}$($1^3\Sigma_{u}^+$), residing on the surface of a helium nanodroplet, can be set into rotation by a nonresonant 1.0 ps infrared laser pulse. The time-dependent degree of alignment measured,…

The direct photodissociation of trapped $^{85}$Rb$_2^+$ (rubidium) molecular ions by the cooling light for the $^{85}$Rb magneto-optical trap (MOT) is studied, both experimentally and theoretically. Vibrationally excited Rb$_{2}^{+}$ ions…

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