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The emergence of complex electronic behaviour from simple ingredients has resulted in the discovery of numerous states of matter. Many examples are found in systems exhibiting geometric magnetic frustration, which prevents simultaneous…

Materials Science · Physics 2013-03-29 John P. Sheckelton , James R. Neilson , Daniel G. Soltan , Tyrel M. McQueen

LiZn$_2$Mo$_3$O$_8$ has been proposed to contain $S~=~1/2$ Mo$_3$O$_{13}$ magnetic clusters arranged on a triangular lattice with antiferromagnetic nearest-neighbor interactions. Here, microwave and terahertz electron spin resonance (ESR),…

Molecular based spin-1/2 triangular lattice systems such as LiZn$_2$Mo$_3$O$_8$ have attracted research interest. Distortions, defects, and intersite disorder are suppressed in such molecular-based magnets, and intrinsic geometrical…

Strongly Correlated Electrons · Physics 2019-02-19 K. Iida , H. Yoshida , H. Okabe , N. Katayama , Y. Ishii , A. Koda , Y. Inamura , N. Murai , M. Ishikado , R. Kadono , R. Kajimoto

Inelastic neutron scattering for temperatures below 30 K from a powder of LiZn2Mo3O8 demonstrates this triangular-lattice antiferromagnet hosts collective magnetic excitations from spin 1/2 Mo3O13 molecules. Apparently gapless (\Delta < 0.2…

We synthesized a quasi-two-dimensional distorted triangular lattice antiferromagnet Ca$_3$CoNb$_2$O$_9$, in which the effective spin of Co$^{2+}$ is 1/2 at low temperatures, whose magnetic properties were studied by dc susceptibility and…

Strongly Correlated Electrons · Physics 2015-12-25 J. Dai , P. Zhou , P. S. Wang , F. Pang , T J. Munsie , G. M. Luke , J. S. Zhang , Weiqiang Yu

The control of the stoichiometry of Li$_{1+x}$Zn$_{2-y}$Mo$_3$O$_8$ was achieved by the solid-state-reaction. We found that the best sample that has the chemical composition Li$_{0.95(4)}$Zn$_{1.92(8)}$Mo$_3$O$_8$ was obtained from the…

Strongly Correlated Electrons · Physics 2019-01-09 K. E. Sandvik , D. Okuyama , K. Nawa , M. Avdeev , T. J. Sato

Metastable Co$_2$Ti$_3$O$_8$ was synthesized through a topochemical reaction using Li$_2$CoTi$_3$O$_8$ as the precursor, resulting in a vacancy-ordered spinel structure. Crystal structure analysis confirmed that Co ions selectively occupy…

Strongly Correlated Electrons · Physics 2025-07-03 Rio Kumeda , Yuya Haraguchi , Daisuke Nishio-Hamane , Akira Matsuo , Koichi Kindo , Hiroko Aruga Katori

We uncover four new spin-charge ordered ground states in the strong coupling limit of the Kondo lattice model on triangular geometry. Two of the states at one-third electronic filling ($n=1/3$) consist of decorated ferromagnetic chains…

Strongly Correlated Electrons · Physics 2015-06-23 Sahinur Reja , Rajyavardhan Ray , Jeroen van den Brink , Sanjeev Kumar

A spin-1/2 triangular-lattice antiferromagnet is a prototypical frustrated quantum magnet, which exhibits remarkable quantum many-body effects that arise from the synergy between geometric spin frustration and quantum fluctuations. It can…

We explore the magnetic phases in a Kondo lattice model on the geometrically frustrated Shastry-Sutherland lattice at metallic electron densities, searching for noncollinear and noncoplanar spin textures. Motivated by experimental…

Strongly Correlated Electrons · Physics 2017-12-05 Munir Shahzad , Pinaki Sengupta

We have successfully synthesized four Mo$_3$O$_8$-type cluster Mott insulators (CMI) by intercalating lithium into nonmagnetic precursors to regulate the Mo$_3$ cluster valence. The resulting materials are Li$_{1+x}$$R$Mo$_3$O$_8$ ($R$ =…

Strongly Correlated Electrons · Physics 2024-06-06 Daigo Ishikita , Yuya Haraguchi , Hiroko Aruga Katori

Magnetic frustration in three dimensions (3D) manifests itself in the spin-$\frac12$ insulator Li$_2$CuW$_2$O$_8$. Density-functional band-structure calculations reveal a peculiar spin lattice built of triangular planes with frustrated…

Materials Science · Physics 2016-02-05 K. M. Ranjith , R. Nath , M. Skoulatos , L. Keller , D. Kasinathan , Y. Skourski , A. A. Tsirlin

Frustration of long-range order via lattice geometries serves to amplify fluctuations of the order parameter and generate unconventional ground states that are highly sensitive to perturbations. Traditionally, this concept of geometric…

TmZn2GaO5 is a newly synthesized triangular lattice magnet that exhibits a unique quantum phase characterized by strong Ising anisotropy, a pseudo-doublet crystal electric field ground state, and a low-energy gapped excitation at the K…

We present a novel hydrated layered manganate MgMn$_3$O$_7$$\cdot$3H$_2$O as a maple-leaf-lattice (MLL) antiferromagnet candidate. The MLL is obtained by regularly depleting 1/7 of the lattice points from a triangular lattice so that the…

Materials Science · Physics 2018-08-14 Yuya Haraguchi , Akira Matsuo , Koichi Kindo , Zenji Hiroi

We report a $^7$Li nuclear magnetic resonance (NMR) study of a frustrated three-dimensional \mbox{spin-$\frac12$} antiferromagnet Li$_{2}$CuW$_{2}$O$_{8}$ and also explore the effect of non-magnetic dilution. The magnetic long-range…

Materials Science · Physics 2015-07-08 K. M. Ranjith , M. Majumder , M. Baenitz , A. A. Tsirlin , R. Nath

The geometrically frustrated two dimensional triangular lattice magnets A${_4}$B'B${_2}$O$_{12}$ (A = Ba, Sr, La; B' = Co, Ni, Mn; B = W, Re) have been studied by x-ray diffraction, AC and DC susceptibilities, powder neutron diffraction,…

We investigate the magnetic ground state of CuNdO$_2$, which is a delafossite with a triangular lattice of magnetic Nd$^{3+}$ ions that are well separated by non-magnetic Cu spacer layers. From inelastic neutron scattering measurements of…

We report magnetization and heat-capacity measurements on the ordered-spinel oxide Li$_2$NiGe$_3$O$_8$, where Ni$^{2+}$ ions with $S = 1$ form a single three-dimensional trillium lattice. Powder x-ray diffraction confirms a cubic…

Strongly Correlated Electrons · Physics 2026-05-14 Yuya Haraguchi

We clarify that the antiferromagnetic order in the distorted tetrahedral quasi-one dimensional spin system induces electric polarizations. In this system, the effects of the low dimensionality and the magnetic frustration are expected to…

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