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Density functional theory within the local or semilocal density approximations (DFT-LDA/GGA) has become a workhorse in electronic structure theory of solids, being extremely fast and reliable for energetics and structural properties, yet…

We present the results of calculations on bulk transition metals Rh, Pd, and Pt using the screened hybrid functional YS-PBE0 [F. Tran and P. Blaha, Phys. Rev. B \textbf{83}, 235118 (2011)]. The results for the equilibrium geometry are…

Materials Science · Physics 2012-10-11 Fabien Tran , David Koller , Peter Blaha

The consistency between the exchange-correlation functional used in pseudopotential construction and in the actual density functional theory calculation is essential for the accurate prediction of fundamental properties of materials.…

Chemical Physics · Physics 2018-02-21 Jing Yang , Liang Z. Tan , Andrew M. Rappe

In this work, we developed and showcased the occ-RI-K algorithm to compute the exact exchange contribution in density functional calculations of solids near the basis set limit. Within the gaussian planewave (GPW) density fitting, our…

Chemical Physics · Physics 2022-11-09 Joonho Lee , Adam Rettig , Xintian Feng , Evgeny Epifanovsky , Martin Head-Gordon

Organic-inorganic metal halide perovskites (HaPs) are intensively studied for their light-harvesting properties. Owing to the interplay between strong electron-electron interaction and spin-orbit coupling (SOC), their quantitative…

Materials Science · Physics 2021-11-02 Cecilia Vona , Dmitrii Nabok , Claudia Draxl

Band offsets at semiconductor-oxide interfaces are determined through a scheme based on hybrid density functionals, which incorporate a fraction $\alpha$ of Hartree-Fock exchange. For each bulk component, the fraction $\alpha$ is tuned to…

Materials Science · Physics 2008-09-19 Audrius Alkauskas , Peter Broqvist , Fabien Devynck , Alfredo Pasquarello

The development of novel materials for vacuum electron sources in particle accelerators is an active field of research that can greatly benefit from the results of \textit{ab initio} calculations for the characterization of the electronic…

Materials Science · Physics 2021-06-01 Holger-Dietrich Saßnick , Caterina Cocchi

We have performed density functional calculations using a range of local and semi-local as well as hybrid density functional approximations of the structure and elastic constants of 18 semiconductors and insulators. We find that most of the…

Materials Science · Physics 2015-10-12 M. Råsander , M. A. Moram

(Screened) hybrid functionals are being used more and more for solid-state calculations. Usually the fraction alpha of Hartree-Fock exchange is kept fixed during the calculation, however there is no single (universal) value for alpha which…

Materials Science · Physics 2013-10-17 David Koller , Peter Blaha , Fabien Tran

We present a systematic assessment of the structural properties, the electronic density of states, the charge densities, and the phase stabilities of AgInSe$_2$ and AuInSe$_2$ using screened exchange hybrid density functional theory, and…

Materials Science · Physics 2016-04-20 Namhoon Kim , Pamela Pena Martin , Angus Rockett , Elif Ertekin

We present example applications of an approach to high-throughput first-principles calculations of the electronic properties of materials implemented within the Exabyte.io platform. We deploy computational techniques based on the Density…

Materials Science · Physics 2020-01-08 Protik Das , Timur Bazhirov

For the large and chemically diverse GMTKN55 benchmark suite, we have studied the performance of density-corrected density functional theory (HF-DFT), compared to self-consistent DFT, for several pure and hybrid GGA and meta-GGA…

Chemical Physics · Physics 2021-03-29 Golokesh Santra , Jan M. L. Martin

The sum-over-states (SOS) polarizabilities are calculated within the approximate independent electron theories such as the Hartree-Fock approximation and density functional models using the eigenvalues and orbitals obtained from the…

Other Condensed Matter · Physics 2015-06-25 Rajendra R. Zope , Tunna Baruah , Mark R. Pederson , Brett I. Dunlap

We consider methods for optimizing the bandgap calculation of 3D materials, considering 340 sample materials. Examined are the effects of the choice of the pseudopotential to describe core electrons, the plane-wave basis set cutoff energy,…

Materials Science · Physics 2025-11-14 Chenxi Lu , Musen Li , Michael J. Ford , Rika Kobayashi , Roger Amos , Jeffrey R. Reimers

We present a detailed study of the structural, electronic, magnetic and ferroelectric properties of prototypical \textit{proper} and \textit{improper} multiferroic (MF) systems such as BiFeO$_{3}$ and orthorhombic HoMnO$_{3}$, respectively,…

Materials Science · Physics 2017-03-15 A. Stroppa , S. Picozzi

The accuracy of effective masses predicted by density functional theory depends on the exchange-correlation functional employed, with nonlocal hybrid functionals giving more accurate results than semilocal functionals. In this article, we…

Materials Science · Physics 2022-08-03 Magdalena Laurien , Oleg Rubel

Using a linear combination of atomic orbitals approach, we report a systematic comparison of various Density Functional Theory (DFT) and hybrid exchange-correlation functionals for the prediction of the electronic and structural properties…

Materials Science · Physics 2008-05-07 D. I. Bilc , R. Orlando , R. Shaltaf , G. -M. Rignanese , Jorge Íñiguez , Ph. Ghosez

We present an implementation of the Heyd-Scuseria-Ernzerhof (HSE) hybrid functional within the full-potential linearized augmented-plane-wave (FLAPW) method. Pivotal to the HSE functional is the screened electron-electron interaction, which…

Materials Science · Physics 2011-11-11 Martin Schlipf , Markus Betzinger , Christoph Friedrich , Marjana Ležaić , Stefan Blügel

In the present work we investigate the adequacy of broken-symmetry unrestricted density functional theory (DFT) for constructing the potential energy curve of nickel dimer and nickel hydride, as a model for larger bare and hydrogenated…

Chemical Physics · Physics 2007-05-23 Cristian V. Diaconu , Art E. Cho , J. D. Doll , David L. Freeman

We propose global hybrid approximations of the exchange-correlation (XC) energy functional which reproduce well the modified fourth-order gradient expansion of the exchange energy in the semiclassical limit of many-electron neutral atoms…

Chemical Physics · Physics 2015-01-22 E. Fabiano , L. A. Constantin , P. Cortona , F. Della Sala