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We propose a definition of microcanonical and canonical statistical ensembles based on the concept of density of states. This definition applies both to the classical and the quantum case. For the microcanonical case this allows for a…

Statistical Mechanics · Physics 2016-11-23 Vadim Kostrykin , Robert Schrader

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

In contrast to the canonical ensemble where thermodynamic functions are smooth for all finite system sizes, the microcanonical entropy can show nonanalytic points also for finite systems, even if the Hamiltonian is smooth. The relation…

Statistical Mechanics · Physics 2007-05-23 Lapo Casetti , Michael Kastner

The work performed on a system in a microcanonical state by changes in a control parameter is characterized in terms of its statistics. The transition probabilities between eigenstates of the system Hamiltonians at the beginning and the end…

Statistical Mechanics · Physics 2014-01-21 Peter Talkner , Manuel Morillo , Juyeon Yi , Peter Hanggi

We take the perspective of open quantum systems and examine from their nonequilibrium dynamics the conditions when the physical quantities, their relations and the laws of thermodynamics become well defined and viable for quantum many body…

Quantum Physics · Physics 2018-01-30 Jen-Tsung Hsiang , C. H. Chou , Y. Subaşi , B. L. Hu

The resource-theoretic approach to quantum thermodynamics assumes complete knowledge of the thermal equilibrium against which thermodynamic resources are defined. In practice, however, this state is determined by the system Hamiltonian and…

Quantum Physics · Physics 2026-04-16 Munan Zhang , Kun Fang

Classical thermodynamics is built with the concept of equilibrium states. However, it is less clear how equilibrium thermodynamics emerges through the dynamics that follows the principle of quantum mechanics. In this paper, we develop a…

Quantum Physics · Physics 2018-12-18 Md. Manirul Ali , Wei-Ming Huang , Wei-Min Zhang

We set up a framework for quantum stochastic thermodynamics based solely on experimentally controllable, but otherwise arbitrary interventions at discrete times. Using standard assumptions about the system-bath dynamics and insights from…

Quantum Physics · Physics 2019-08-22 Philipp Strasberg

This work focuses on the response to an external field of a Brownian particle submerged in an Ohmic quantum thermal bath. The field only affects the dynamics of the central particle without affecting the thermal reservoir. The thermodynamic…

Quantum Physics · Physics 2019-11-12 Pedro J. Colmenares

Microcanonical thermodynamics (MCTh) is contrasted to canonical thermodynamics (CTh). At phase transitions of 1.order the two ensembles are NOT equivalent even in the thermodynamic limit . Energy fluctuations do not vanish and phase…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

How should one define thermodynamic quantities (internal energy, work, heat, etc.) for quantum systems coupled to their environments strongly? We examine three (classically equivalent) definitions of a quantum system's internal energy under…

In contrast to the canonical case, microcanonical thermodynamic functions can show nonanalyticities also for finite systems. In this paper we contribute to the understanding of these nonanalyticities by working out the relation between…

Statistical Mechanics · Physics 2009-07-22 Lapo Casetti , Michael Kastner , Rachele Nerattini

In the standard framework of thermodynamics the work produced or consumed in a process is a random variable whose average value is bounded by the change in the free energy of the system. This work is calculated without regard for the size…

Quantum Physics · Physics 2017-04-19 Jonathan G. Richens , Lluis Masanes

There are both practical and foundational motivations to consider the thermodynamics of quantum systems at small scales. Here we address the issue of autonomous quantum thermal machines that are tailored to achieve some specific…

Quantum Physics · Physics 2016-03-08 Max F. Frenzel , David Jennings , Terry Rudolph

We develop a geometric foundation of microcanonical thermodynamics in which entropy and its derivatives are determined from the geometry of phase space, rather than being introduced through an a priori ensemble postulate. Once the minimal…

Statistical Mechanics · Physics 2025-12-30 Loris Di Cairano

In recent years, the study of heat to work conversion has been re-invigorated by nanotechnology. Steady-state devices do this conversion without any macroscopic moving parts, through steady-state flows of microscopic particles such as…

Mesoscale and Nanoscale Physics · Physics 2017-08-14 Giuliano Benenti , Giulio Casati , Keiji Saito , Robert S. Whitney

The resource theory with covariant Gibbs-preserving operations, also called enhanced thermal operations, is investigated. We prove that with the help of a correlated catalyst, the state convertibility for any coherent state is fully…

Quantum Physics · Physics 2026-04-13 Naoto Shiraishi

Microcanonical Thermodynamics allows the application of Statistical Mechanics on one hand to closed finite and even small systems and on the other to the largest,self-gravitating ones. However, one has to reconsider the fundamental…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

We develop a physics-based model for classical computation based on autonomous quantum thermal machines. These machines consist of few interacting quantum bits (qubits) connected to several environments at different temperatures. Heat flows…

Quantum Physics · Physics 2025-03-06 Patryk Lipka-Bartosik , Martí Perarnau-Llobet , Nicolas Brunner

The study of intelligent systems explains behaviour in terms of economic rationality. This results in an optimization principle involving a function or utility, which states that the system will evolve until the configuration of maximum…

Information Theory · Computer Science 2024-06-18 Pedro Hack
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