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An improved thermodynamic cycle is proposed, where the cooling effect of an electrocaloric refrigerant is enhanced by applying a reversed electric field. In contrast to conventional adiabatic heating or cooling by on-off cycles of the…

Computational Physics · Physics 2016-10-05 Yang-Bin Ma , Nikola Novak , Jurij Koruza , Tongqing Yang , Karsten Albe , Bai-Xiang Xu

New strategy is presented to optimize the performance of Thermoelectric (TE) coolers. This approach breaks optimizing TE coolers free from traditional methods of controlling temperature or engineering materials and the structural properties…

Systems and Control · Electrical Eng. & Systems 2024-07-26 Alireza Amiri-Margavi , Reza Jamali , Seyed Aria Hosseini , Farschad Torabi

The electrocaloric effect (ECE) offers a promising alternative to the traditional gas compressing refrigeration due to its high efficiency and environmental friendliness. The unusual negative electrocaloric effect refers to the adiabatic…

Materials Science · Physics 2023-07-14 Xingyue Ma , Mingxing Chen , Jun-Ming Liu , Di Wu , Yurong Yang

Density functional theory at finite temperatures often relies on the zero-temperature approximation, which uses a ground-state exchange-correlation functional with thermalized densities. This approach, however, neglects the explicit…

Other Condensed Matter · Physics 2026-03-26 Brianna Aguilar-Solis , Brittany P. Harding , Aurora Pribram-Jones

There is a surge of interest in developing environmentally friendly cooling technology based on the solid--state electrocaloric effect (ECE). Here, we point out that negative ECE with a fast cooling rate ($\approx$10$^{11}$ K/s) can be…

Materials Science · Physics 2018-02-07 Yubo Qi , Shi Liu , Aaron M. Lindenberg , Andrew M. Rappe

The electrocaloric effect refers to the temperature change in a material when an electric field is applied or removed. Significant breakthroughs revealed its potential for solid-state cooling technologies in past decades. These devices…

Mesoscale and Nanoscale Physics · Physics 2025-04-10 Jean Spièce , Valentin Fonck , Charalambos Evangeli , Phil S. Dobson , Jonathan M. R. Weaver , Pascal Gehring

We analyze the steady-state formalism for optimizing the cooling power of a thermoelectric refrigerator (TER), unifying the endoreversible and exoreversible approximations within one framework. Although the cooling power is non-optimizable…

Statistical Mechanics · Physics 2026-04-14 Rajeshree Chakraborty , Ramandeep S. Johal

In acceptor doped ferroelectrics and in ferroelectric films and nanocomposites, defect dipoles, strain gradients, and the electric boundary conditions at interfaces and surfaces often impose internal bias fields. In this work we delicately…

Materials Science · Physics 2018-09-05 Yang-Bin Ma , Bai-Xiang Xu , Karsten Albe , Anna Grünebohm

We developed a new technique for measuring the thermodynamic entropy as a function of the magnetic field angle. This technique enables high-resolution angle-resolved measurements of the entropy in an unprecedentedly short measuring time.…

Strongly Correlated Electrons · Physics 2018-06-15 Shunichiro Kittaka , Shota Nakamura , Hiroaki Kadowaki , Hiroshi Takatsu , Toshiro Sakakibara

There is growing interest in heat pumps based on materials that show thermal changes when phase transitions are driven by changes of electric, magnetic or stress field. Importantly, regeneration permits sinks and loads to be thermally…

Materials Science · Physics 2019-10-09 S. Crossley , B. Nair , R. W. Whatmore , X. Moya , N. D. Mathur

An efficient cooling effect is put forward, by means of external electric or magnetic fields along hysteresis loops. A simplified model of hysteresis is used for numerical illustration. The model is based upon a second-order expansion of…

Materials Science · Physics 2026-05-26 M. Apostol

In this paper an analysis of the Stirling cycle in thermoeconomic terms is developed using the entropy generation. In the thermoeconomic optimization of an irreversible Stirling heat pump cycle the F function has been introduced to evaluate…

Classical Physics · Physics 2010-11-08 U. Lucia , G. Gervino

Electrically driven adiabatic changes of temperature are identified in the archetypal electrocaloric material PbSc0.5Ta0.5O3 by comparing isothermal changes of electrical polarization due to slow variation of electric field, and adiabatic…

Materials Science · Physics 2021-01-22 S. Crossley , R. W. Whatmore , N. D. Mathur , X. Moya

We present a modified simulated annealing method with a dynamical choice of the cooling temperature. The latter is determined via a closed-loop control and is proven to yield exponential decay of the entropy of the particle system. The…

Optimization and Control · Mathematics 2026-02-18 Michael Herty , Mattia Zanella

Elastocaloric cooling has been identified as a promising alternative to high global warming potential vapor compression cooling. Two key bottlenecks to adoption are the need for bulky/expensive actuators to provide sufficient uniaxial…

Materials Science · Physics 2021-05-19 Darin J. Sharar , Joshua Radice , Ronald Warzoha , Brendan Hanrahan , Andrew Smith

The electrocaloric effect (ECE), i.e., the reversible temperature change due to the adiabatic variation of the electric field, is of great interest due to its potential technological applications. Based on entropy arguments, we present a…

Materials Science · Physics 2023-04-28 Lucas Squillante , Isys F. Mello , A. C. Seridonio , Mariano de Souza

In this note, the equilibrium curve of a thermodynamic system is used to depict entropy production in the process of thermalization with a reservoir. For the given initial and final equilibrium states of the system, the entropy production…

Statistical Mechanics · Physics 2024-09-06 Ramandeep S. Johal

A contactless technique for direct time-resolved measurements of the full dynamics of the adiabatic temperature change in electrocaloric materials is introduced. The infrared radiation emitted by the electrocaloric sample is sensitively…

Modelling elastocaloric effect (eCE) is crucial for the design of environmentally friendly and energy-efficient eCE based solid-state cooling devices. Here, a thermodynamically consistent non-isothermal phase-field model (PFM) coupling…

Materials Science · Physics 2023-03-10 Wei Tang , Qihua Gong , Min Yi , Bai-Xiang Xu , Long-Qing Chen

Minor hysteresis loops within the main loop are obtained analytically and exactly in the one-dimensional ferromagnetic random field Ising-model at zero temperature. Numerical simulations of the model show excellent agreement with the…

Disordered Systems and Neural Networks · Physics 2009-10-31 Prabodh Shukla
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