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We derive the photovoltaic conversion efficiency limit for two-terminal tandem solar cells with a perovskite top cell and silicon bottom cell with an embedded spectrum splitter. For large-bandgap top-cells a spectrum splitter strongly…

Optics · Physics 2020-12-24 Verena Neder , Stefan W. Tabernig , Albert Polman

Sulfide Kesterite Cu2ZnSnS4 (CZTS), a nontoxic and low-cost photovoltaic material, has always being facing severe charge recombination and poor carrier transport, resulting in the cell efficiency record stagnating around 11% for years.…

Perovskite/Si tandem solar cells have the potential to considerably out-perform conventional solar cells. Under standard test conditions, perovskite/Si tandem solar cells already outperform the Si single junction. Under realistic…

Materials Science · Physics 2017-08-23 Moritz H. Futscher , Bruno Ehrler

Solar cells based on a light absorbing layer of the organometal halide perovskite CH$_3$NH$_3$PbI$_3$ have recently reached 15% conversion efficiency, though how these materials work remains largely unknown. We analyse the electronic…

Materials Science · Physics 2014-04-24 Federico Brivio , Keith T. Butler , Aron Walsh , Mark van Schilfgaarde

The Shockley and Queisser limit, a well-known efficiency limit for a solar cell, is based on unrealistic physical assumptions and its maximum limit is seriously overestimated. To understand the power loss mechanisms of record-efficiency…

Applied Physics · Physics 2019-08-28 Yoshitsune Kato , Shohei Fujimoto , Masayuki Kozawa , Hiroyuki Fujiwara

Increasing photovoltaic conversion efficiency, or PCE, has proven to be a critical factor in the transition to renewable energy. There exist strong interdependencies between the perovskite crystals and multijunction architectures within…

Materials Science · Physics 2025-01-15 Sutharsika Kumar Kalaiselvi

Though the common metal electrode-based perovskite solar cells have achieved a power conversion efficiency of >25%, they also play a crucial role in accelerating the degradation of the cells. In this study, we investigated phase transition…

Materials Science · Physics 2025-10-20 Keshav Kumar Sharma , Ashutosh Ujjwal , Rohit Saini , Ramesh Karuppannan

Hybrid organic-inorganic halide perovskites with the prototype material of CH$_{3}$NH$_{3}$PbI$_{3}$ have recently attracted intense interest as low-cost and high-performance photovoltaic absorbers. Despite the high power conversion…

Materials Science · Physics 2017-05-30 Xin-Gang Zhao , Ji-Hui Yang , Yuhao Fu , Dongwen Yang , Qiaoling Xu , Liping Yu , Su-Huai Wei , Lijun Zhang

In recent years, halide perovskite-based solar cells have received intensive attention, and demonstrated power conversion efficiency as high as 25.8%. With regard to the toxicity of Pb and the instability of organic elements, all inorganic…

Materials Science · Physics 2022-05-04 Dibyajyoti Saikia , Mahfooz Alam , Jayanta Bera , Atanu Betal , Appala Naidu Gandhi , Satyajit Sahu

The spin-split indirect bandgap in hybrid-halide perovskites provides a momentum-space realisation of a photon-ratchet intermediate band. Excited electrons thermalise to recombination-protected Rashba pockets offset in momentum space,…

Materials Science · Physics 2016-11-30 Jarvist M. Frost , Pooya Azarhoosh , Scott McKechnie , Mark van Schilfgaarde , Aron Walsh

We calculated the maximum power conversion efficiency as a function of the optical band gap for organic photovoltaic (PV) cells by assuming that charge separation is accompanied by the energy loss required to dissociate strongly bound…

Materials Science · Physics 2015-07-09 Kazuhiko Seki , Akihiro Furube , Yuji Yoshida

The scalability of highly efficient organic-inorganic perovskite solar cells (PSCs) is one of the remaining challenges of solar module manufacturing. Various scalable methods have been explored to strive for uniform perovskite films of high…

Applied Physics · Physics 2022-07-19 Severin Siegrist , Shih-Chi Yang , Evgeniia Gilshtein , Xiaoxiao Sun , Ayodhya N. Tiwari , Fan Fu

A theoretical approach to photoconversion efficiency modeling in perovskite p-i-n structures is developed. The results of this modeling compare favorably with the experiment and indicate that the surfaces of the perovskite solar cells (SCs)…

Mesoscale and Nanoscale Physics · Physics 2017-04-06 A. V. Sachenko , V. P. Kostylyov , A. V. Bobyl , V. M. Vlasyuk , I. O. Sokolovskyi , E. I. Terukov , M. Evstigneev

Photon recycling is required for a solar cell to achieve an open-circuit voltage ($V_{OC}$) and power conversion efficiency (PCE) approaching the Shockley-Queisser theoretical limit. In metal halide perovskite solar cells, the achievable…

Applied Physics · Physics 2019-07-17 Roberto Brenes , Madeleine Laitz , Joel Jean , Dane W. deQuilettes , Vladimir Bulovic

Despite the promising optoelectronic properties of methylammonium lead iodide (MAPbI3)-based perovskite solar cells (PSCs), their commercial viability is hindered by interfacial energy misalignment, suboptimal light absorption, and thermal…

Optics · Physics 2025-09-04 Md. Faiaad Rahman , Arpan Sur , Ahmed Zubair

In the previous decade, there has been a significant advancement in the performance of perovskite solar cells (PSCs), characterized by a notable increase in efficiency from 3.8% to 25%. Nonetheless, PSCs face many problems when we…

Perovskite solar cells (PSCs) are attracting great attention as the most promising candidate for the next generation solar cells. This is due to their low cost and high power conversion efficiency in spite of their relatively short period…

Applied Physics · Physics 2018-11-05 Chol-Jun Yu

A comprehensive study of the structural, electronic, and optical properties of lead-free perovskites has been carried out by means of first principles method based on DFT. The calculations are performed for the compound of the type A2BX6…

Materials Science · Physics 2020-04-24 M. Faizan , K. C. Bhamu , S. H. Khan , G. Murtaza , Xin He

The ability to reduce energy loss at semiconductor surfaces through passivation or surface field engineering has become an essential step in the manufacturing of efficient photovoltaic (PV) and optoelectronic devices. Similarly, surface…

We propose an unexplored class of absorbing materials for high-efficiency solar cells: heterostructures of transition-metal oxides. In particular, LaVO_3 grown on SrTiO_3 has a direct band gap ~1.1 eV in the optimal range as well as an…