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The temperature dependence of the local structure of PbSe has been investigated using pair distribution function (PDF) analysis of x-ray and neutron powder diffraction data and density functional theory (DFT) calculations. Observation of…

The simplest anharmonic characteristics of Ir and Rh are discussed in the framework of a previously developed simple pseudopotential model which describes the elastic moduli, phonon spectra and the lattice heat capacity in the harmonic…

Materials Science · Physics 2007-05-23 M. I. Katsnelson , M. Sigalas , A. V. Trefilov , K. Yu. Khromov

A quantum Langevin model, similar to models used recently for optomechanics, was used to predict intermodulation phonon sidebands (IPS). Ab initio calculations of anharmonic phonons in rocksalt NaBr showed these spectral features as…

Materials Science · Physics 2021-04-21 Y. Shen , C. N. Saunders , C. M. Bernal , D. L. Abernathy , T. J. Williams , M. E. Manley , B. Fultz

Low-collisionality plasma in a magnetic field generically develops anisotropy in its distribution function with respect to the magnetic field direction. Motivated by the application to radiation from accretion flows and jets, we explore the…

High Energy Astrophysical Phenomena · Physics 2023-09-20 Alisa Galishnikova , Alexander Philippov , Eliot Quataert

Alloying is widely used as a means to fine-tune the properties of thermoelectric materials by reducing the lattice thermal conductivity. However, the effects of compositional variation on the lattice dynamics of alloy systems are not well…

Materials Science · Physics 2020-01-31 Jonathan M. Skelton

Ab initio investigations of structural, electronic, and dynamical properties of the high-temperature $\beta$ phase of copper pyrophosphate were performed using density functional theory. The electronic band structure shows the Mott…

The origin of the phonon thermal Hall effect in insulators is a matter of ongoing debate. The large amplitude of the signal in an elemental non-magnetic solid, such as black phosphorus (BP), calls for a minimal mechanism not invoking the…

Strongly Correlated Electrons · Physics 2025-05-09 Xiaokang Li , Xiaodong Guo , Zengwei Zhu , Kamran Behnia

We report neutron inelastic scattering experiments on single crystal PbMg$_{1/3}$Nb$_{2/3}$O$_{3}$ doped with 32\% PbTiO$_{3}$, a relaxor ferroelectric that lies close to the morphotropic phase boundary. When cooled under an electric field…

Materials Science · Physics 2016-01-06 John A. Schneeloch , Zhijun Xu , B. Winn , C. Stock , P. M. Gehring , R. J. Birgeneau , Guangyong Xu

We present a general harmonic theory for the temperature dependence of phonon-renormalized properties of solids. Firstly, we formulate a perturbation theory in phonon-phonon interactions to calculate the phonon renormalization of physical…

Materials Science · Physics 2015-10-28 Bartomeu Monserrat , G. J. Conduit , R. J. Needs

We demonstrate the determination of anharmonic acoustic phonon properties via second-order Raman scattering exemplarily on copper iodide single crystals. The origin of multi-phonon features from the second-order Raman spectra was assigned…

Anharmonic decay of coherent optical phonons in semimetal Sb has been investigated by using a femtosecond pump-probe technique. The coherent $A_{1g}$ mode is observed in time domain in a wide temperature range of 7 - 290 K. The decay rate…

Materials Science · Physics 2015-01-12 Muneaki Hase , Kiminori Ushida , Masahiro Kitajima

Metal-organic frameworks often display large positive or negative thermal expansion coefficients. MOF-74, a material envisioned for many applications does not display such a behavior. For this system, temperature-dependent x-ray diffraction…

Materials Science · Physics 2022-01-19 Tomas Kamencek , Benedikt Schrode , Roland Resel , Raffaele Ricco , Egbert Zojer

The partition function of an oscillator disturbed by a set of electron particle paths has been computed by a path integral method which permits to evaluate at any temperature the relevant cumulant terms in the series expansion. The time…

Soft Condensed Matter · Physics 2009-11-10 Marco Zoli

Graphene and its derivatives distinguish themselves for their large negative thermal expansion even at temperatures as high as 1000K. The linear thermal expansion coefficients (LTEC) of two-dimensional honeycomb structured pure graphene and…

Mesoscale and Nanoscale Physics · Physics 2017-05-01 Sarita Mann , Ranjan Kumar , V. K. Jindal

The phonon dispersion was measured at room temperature along (0,0,L) in the tetragonal phase of LaFeAsO using inelastic x-ray scattering. Spin-polarized first-principles calculations imposing various types of antiferromagnetic order are in…

Thermal boundary resistance is a critical quantity that controls heat transfer at the nanoscale, which is primarily related to interfacial phonon scattering. Here, we combine lattice dynamics calculations and inputs from first principles ab…

Mesoscale and Nanoscale Physics · Physics 2017-10-30 Ali Alkurdi , Stéphane Pailhès , Samy Merabia

We investigate the thermal behavior of the (111) surface of silver, using phonon frequencies obtained from ab initio total energy calculations, and anharmonic effects treated within a quasiharmonic approximation. Our results reproduce the…

mtrl-th · Physics 2008-02-03 Shobhana Narasimhan , Matthias Scheffler

Lead chalcogenides such as PbS, PbSe, and PbTe are of interest for their exceptional thermoelectric properties and strongly anharmonic lattice dynamics. Although PbTe has received the most attention, PbSe has a lower thermal conductivity…

Materials Science · Physics 2017-01-11 Nina Shulumba , Olle Hellman , Austin J. Minnich

Extensive inelastic neutron scattering measurements of phonons on a single crystal of CaFe2As2 allowed us to establish a fairly complete picture of phonon dispersions in the main symmetry directions. The phonon spectra were also calculated…

Interatomic forces that bind materials are largely determined by an often complex interplay between the electronic band-structure and the atomic arrangements to form its equilibrium structure and dynamics. As these forces also determine the…