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Catalyst-free vertically aligned graphene nanoflakes possessing a large amount of high density edge planes were functionalized using nitrogen species in a low energy N+ ion bombardment process to achieve pyridinic, cyanide and nitrogen…

Materials Science · Physics 2012-05-15 Ajay Kumar , Abhijit Ganguly , Pagona Papakonstantinou

Experimental studies of the oxygen reduction reaction (ORR) at nitrogen doped graphene electrodes have reported a remarkably low overpotential, on the order of 0.5 V, similar to Pt based electrodes. Theoretical calculations using density…

Heteroatom doping is an important method for engineering graphene nanoribbons (GNRs) because of its ability to modify electronic properties by introducing extra electrons or vacancies. However, precisely integrating oxygen atoms into the…

We report the local atomic and electronic structure of a nitrogen-doped graphite surface by scanning tunnelling microscopy, scanning tunnelling spectroscopy, X-ray photoelectron spectroscopy, and first-principles calculations. The…

The n-type tensile-strained Ge can be used as high-efficient light-emitting materials. To reveal the influence of n-type doping on the electronic structure of Ge, we have computed the electronic structure of P, As and Sb doped Ge using…

Materials Science · Physics 2017-06-14 Zhong-Hua Dai , Yao-Ping Xie , Yi-Chen Qian , Li-Juan Hu , Xiao-Di Li , Hai-Tao Ma

We use confocal Raman microscopy and modified vector analysis methods to investigate the nanoscale origin of strain and carrier concentration in exfoliated graphene-hexagonal boron nitride (hBN) heterostructures on silicon dioxide (SiO2).…

The simplest tight-binding model is used to study lattice effects on two properties of doped graphene: i) magnetic orbital susceptibility and ii) regular Friedel oscillations, both suppressed in the usual Dirac cone approximation. i) An…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 G. Gómez-Santos , T. Stauber

The electronic properties of boron-nitride nanoribbons (BNNRs) doped with a line of carbon atoms are investigated by using density functional calculations. Three different configurations are possible: the carbon atoms may replace a line of…

Mesoscale and Nanoscale Physics · Physics 2015-06-04 J. Beheshtian , A. Sadeghi , M. Neek-Amal , K. H. Michel , F. M. Peeters

Nitrogen doped graphene and carbon nanotubes are popularly in focus as metal-free electro-catalysts for oxygen reduction reactions (ORR) central to fuel-cells. N doped CNTs have been also reported to chemisorb mutually, promising a route to…

Materials Science · Physics 2015-04-17 Joydeep Bhattacharjee

A theoretical model is presented to reveal the mechanism of B doping into graphene in the microwave plasma experiment choosing trimethylboron as the doping source (ACS NANO 6 (2012) 1970). The results show that the reason for B doping comes…

Mesoscale and Nanoscale Physics · Physics 2016-09-21 Xiaohui Deng , Jing Zeng , Mingsu Si , Wei Lu

We develop a simple chemical method to obtain bulk quantities of N-doped, reduced graphene oxide (GO) sheets through thermal annealing of GO in ammonia. X-ray photoelectron spectroscopy (XPS) study of GO sheets annealed at various reaction…

Materials Science · Physics 2009-10-07 Xiaolin Li , Hailiang Wang , Joshua T. Robinson , Hernan Sanchez , Georgi Diankov , Hongjie Dai

Near-interfacial oxide traps and chemical impurities on the graphene surface or at the graphene-dielectric interface can be a source of intentional or unintentional doping of graphene sheet. The efficiency of such chemical doping can vary…

Mesoscale and Nanoscale Physics · Physics 2019-07-03 G. I. Zebrev , S. A. Shostachenko

Nitrogen doped carbon nanotubes have been synthesized using pyrolysis and characterized by Scanning Tunneling Spectroscopy and transmission electron microscopy. The doped nanotubes are all metallic and exhibit strong electron donor states…

Controlling the type and density of charge carriers by doping is the key step for developing graphene electronics. However, direct doping of graphene is rather a challenge. Based on first-principles calculations, a concept of overcoming…

Mesoscale and Nanoscale Physics · Physics 2011-07-26 Bing Huang , Hongjun Xiang , Su-Huai Wei

Doped semiconductors are a central and crucial component of all integrated circuits. By using a combination of white light and a focused laser beam, and exploiting hBN defect states, heterostructures of hBN/Graphene/hBN are photodoped…

Mesoscale and Nanoscale Physics · Physics 2025-02-12 Son T. Le , Thuc T. Mai , Maria F. Munoz , Angela R. Hight Walker , Curt A. Richter , Aubrey T. Hanbicki , Adam L. Friedman

Insight into why superconductivity in pristine and doped monolayer graphene seems strongly suppressed has been central for the recent years' various creative approaches to realize superconductivity in graphene and graphene-like systems. We…

Superconductivity · Physics 2020-06-12 Even Thingstad , Akashdeep Kamra , Justin W. Wells , Asle Sudbø

Graphene antidot lattices constitute a novel class of nano-engineered graphene devices with controllable electronic and optical properties. An antidot lattice consists of a periodic array of holes which causes a band gap to open up around…

We study the energy gap opening in the electronic spectrum of graphene bilayers caused by asym- metric doping. Both substitutional impurities (boron acceptors and nitrogen donors) and adsorbed potassium donors are considered. The gap…

Mesoscale and Nanoscale Physics · Physics 2010-12-14 Marcos G. Menezes , Rodrigo B. Capaz , Jorge L. B. Faria

Sulfur and nitrogen dual doped graphene have been extensively investigated in the field of oxygen reduction reaction, supercapacitors and batteries, but their magnetic and absorption performance have not been explored. Besides, the effects…

Applied Physics · Physics 2020-03-24 L. Quan , H. T. Lu , F. X. Qin , D. Estevez , Y. F. Wang , Y. H. Li , Y. Tian , H. Wang , H. X. Peng

Density functional theory calculations suggest a pronounced hole electron doping asymmetry in a single layer graphene. It turns out that a single graphene sheet can sustain doping levels up to 0.1 holes or up to a remarkably large 1.9…

Superconductivity · Physics 2025-07-01 Dawid Ciszewski , Wojciech Grochala