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We show that incoherent quasi-elastic neutron scattering (QENS) from molecular liquids reveals a two-state dynamic heterogeneity on a 1 ps timescale, where molecules are either highly confined or are free to undergo relatively large…

Soft Condensed Matter · Physics 2015-06-17 Marcus T. Cicerone , Qin Zhong , Madhusudan Tyagi

The heterogeneous character of the Johari-Goldstein (JG) relaxation is evidenced by molecular-dynamics simulation of a model polymer system. A double-peaked evolution of dynamic heterogeneity (DH), with maxima located at JG and structural…

Soft Condensed Matter · Physics 2021-02-26 Francesco Puosi , Antonio Tripodo , Marco Malvaldi , Dino Leporini

Molecular dynamics simulations were carried out on a Lennard-Jones binary mixture of rigid (fixed bond length) diatomic molecules. The translational and rotational correlation functions, and the corresponding susceptibilities, exhibit two…

Soft Condensed Matter · Physics 2015-06-16 D. Fragiadakis , C. M. Roland

Supercooled liquids undergo complicated structural relaxation processes, which have been a long-standing problem in both experimental and theoretical aspects of condensed matter physics. In particular, past experiments universally observed…

Soft Condensed Matter · Physics 2023-03-31 Kumpei Shiraishi , Hideyuki Mizuno , Atsushi Ikeda

We investigate the Johari-Goldstein (JG) $\beta$-relaxation process in a model metallic glass-forming (GF) material (Al90Sm10), previously studied extensively by both frequency-dependent mechanical measurements and simulation studies…

Materials Science · Physics 2021-03-09 Hao Zhang , Xinyi Wang , Hai-Bin Yu , Jack F. Douglas

Experimental evidence for the Gardner transition, theoretically predicted to arise deep in the glassy state of matter, is scarce. At this transition, the energy landscape sensed by the particles forming the glass is expected to become more…

Soft Condensed Matter · Physics 2018-02-28 K. Geirhos , P. Lunkenheimer , A. Loidl

We employ an atomic-scale theory within the framework of nonaffine lattice dynamics to uncover the origin of the Johari-Goldstein (JG) $\beta$-relaxation in metallic glasses (MGs). Combining simulation and experimental data with our…

Disordered Systems and Neural Networks · Physics 2018-10-09 Bingyu Cui , Zach Evenson , Beibei Fan , Mao-Zhi Li , Wei-Hua Wang , Alessio Zaccone

Molecular dynamics simulations (mds) were carried out to investigate the reorientational motion of a rigid (fixed bond length), asymmetric diatomic molecule in the liquid and glassy states. In the latter the molecule reorients via…

Soft Condensed Matter · Physics 2015-06-04 D. Fragiadakis , C. M. Roland

We show using molecular dynamics simulations that simple diatomic molecules in the glassy state exhibit only limited participation in the Johari-Goldstein (JG) relaxation process. That is, with sufficient cooling local reorientations are…

Soft Condensed Matter · Physics 2017-07-05 D. Fragiadakis , C. M. Roland

It is well known that the \alpha-relaxation of each component in a miscible mixtures of two glass-formers has its own dynamics, which change with the composition of the blend. Lesser known are the corresponding change of the…

Soft Condensed Matter · Physics 2007-05-23 Kia l. Ngai , Simone Capaccioli

A universal secondary relaxation process, known as the Johari-Goldstein (JG) $\beta$-relaxation process, appears in glass formers. It involves all parts of the molecule and is particularly important in glassy systems because of its very…

Soft Condensed Matter · Physics 2016-01-20 Debasish Saha , Yogesh M Joshi , Ranjini Bandyopadhyay

The elusive connection between dynamics and local structure in supercooled liquids is an important piece of the puzzle in the unsolved problem of the glass transition. The Johari-Goldstein beta relaxation, ubiquitous in glass-forming…

Soft Condensed Matter · Physics 2017-03-08 D. Fragiadakis , C. M. Roland

We investigate the fast $\beta$- and Johari-Goldstein (JG) $\beta$-relaxation processes, along with the elastic scattering response of glass-forming (GF) liquids and the Boson peak, in a simulated Al-Sm GF material exhibiting a…

Materials Science · Physics 2021-03-17 Hao Zhang , Xinyi Wang , Hai-Bin Yu , Jack F. Douglas

We investigated the dynamics of a series of room temperature ionic liquids based on the same 1-butyl-3-methyl imidazolium cation and different anions by means of broadband dielectric spectroscopy covering 15 decades in frequency…

Disordered Systems and Neural Networks · Physics 2009-11-11 Alberto Rivera , Ernst A. Roessler

We investigate the dielectric response in the glass-electret state of two dipolar glass-forming materials. This unusual polar glassy state of matter is produced when a dipolar liquid is supercooled under the influence of a high electric dc…

Disordered Systems and Neural Networks · Physics 2019-12-04 P. Lunkenheimer , F. Humann , D. Reuter , K. Geirhos , A. Loidl , G. P. Johari

We show that the neutron diffuse scattering in relaxor ferroelectric (1-x)PbZn$_{1/3}$Nb$_{2/3}$O$_{3}$ - x PbTiO$_{3}$ (x=0.07) consists of two components. The first component is strictly elastic but extended in q-space and grows below 600…

Materials Science · Physics 2019-08-12 G. -M. Rotaru , S. N. Gvasaliya , B. Roessli , S. Kojima , S. G. Lushnikov , P. Günter

Strong changes in bulk properties, such as modulus and viscosity, are observed near the glass transition temperature, T_{g}, of amorphous materials. For more than a century, intense efforts have been made to define a microscopic origin for…

Disordered Systems and Neural Networks · Physics 2024-04-24 Joseph B. Schlenoff , Khalil Akkaoui

We report a thorough characterization of the dielectric relaxation behavior and the ionic conductivity in the plastic-crystalline mixture of 60% succinonitrile and 40% glutaronitrile. The plastic phase can be easily supercooled and the…

Disordered Systems and Neural Networks · Physics 2011-02-16 Th. Bauer , M. Köhler , P. Lunkenheimer , A. Loidl , C. A. Angell

Nearly all glass-forming liquids feature, along with the structural alpha-relaxation process, a faster secondary process (beta-relaxation), whose nature belongs to the great mysteries of glass physics. However, for some of these liquids, no…

Disordered Systems and Neural Networks · Physics 2010-04-15 A. A. Pronin , M. V. Kondrin , A. G. Lyapin , V. V. Brazhkin , A. A. Volkov , P. Lunkenheimer , A. Loidl

Bragg diffraction divides a Bose-Einstein condensate into two overlapping components, moving with respect to each other with high momentum. Elastic collisions between atoms from distinct wave packets can significantly deplete the…

Other Condensed Matter · Physics 2007-05-23 Pawel Zin , Jan Chwedenczuk , Marek Trippenbach
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