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Interfacial charge transfer plays an essential role in establishing the relative alignment of the metal Fermi level and the energy bands of organic semiconductors. While the details remain elusive in many systems, this charge transfer has…

Materials Science · Physics 2009-05-21 J. H. Worne , R. Giridharagopal , K. F. Kelly , D. Natelson

We show that infrared imaging of the charge density profile in organic field-effect transistors (FETs) can probe transport characteristics which are difficult to access by conventional contact-based measurements. Specifically, we carry out…

We measure hole transport in poly(3-hexylthiophene) field effect transistors with channel lengths from 3 $\mu$m down to 200 nm, from room temperature down to 10 K. Near room temperature effective mobilities inferred from linear regime…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 B. H. Hamadani , D. Natelson

It is still a matter of controversy whether the relative difference in hole and electron transport in solution-processed organic semiconductors is either due to intrinsic properties linked to chemical and solid-state structure or to…

Chemical Physics · Physics 2019-12-02 Giuseppina Pace , Ilaria Bargigia , Yong-Young Noh , Carlos Silva , Mario Caironi

$\alpha$-(BEDT-TTF)$_2$I$_3$ is a prominent example of charge ordering among organic conductors. In this work we explore the details of transport within the charge-ordered as well as semimetallic phase at ambient pressure. In the…

Investigation of the inherent field-driven charge transport behaviour of 3D lead halide perovskites has largely remained a challenging task, owing primarily to undesirable ionic migration effects near room temperature. In addition, the…

The interplay between inter- and intra-chain charge transport in bulk polythiophene in the hopping regime has been clarified by studying the conductivity as a function of frequency (up to 3 THz), temperature and doping level. We present a…

Soft Condensed Matter · Physics 2009-10-31 J. A. Reedijk , H. C. F. Martens , H. B. Brom , M. A. J. Michels

The transport properties of high-performance thin-film transistors (TFT) made with a regio-regular poly(thiophene) semiconductor (PQT-12) are reported. The room-temperature field-effect mobility of the devices varied between 0.004 cm2/V s…

Materials Science · Physics 2009-11-10 A. Salleo , T. W. Chen , A. R. Voelkel , Y. Wu , P. Liu , B. S. Ong , R. A. Street

We study the interplay of intrinsic-electronic and environmental factors on long-range charge transport across molecular chains with up to $N\sim 80$ monomers. We describe the molecular electronic structure of the chain with a tight-binding…

Mesoscale and Nanoscale Physics · Physics 2022-09-21 Francisco Lai Liang , Dvira Segal

Ultrathin polymer-graphene heterostructures are promising materials for next generation optoelectronic and photovoltaic technologies, while the influence of the polymer's structural variation on interfacial charge transfer remains unclear.…

Materials Science · Physics 2025-12-25 Yosra Mater , Salih Demirci , V. Ongun Özçelik

The charge carrier localization length {\alpha} is a crucial, yet often ignored parameter of conjugated polymers that exponentially influences electronic conductivity. Here, we argue it is a unique proxy of the energy landscape as…

Disordered Systems and Neural Networks · Physics 2025-11-18 Morteza Shokrani , Felix Maximilian Graf , Anton Kompatscher , Dennis Derewjanko , Martijn Kemerink

The transport properties of organic light-emitting diodes in which the emissive layer is composed of conjugated polymers in the liquid-crystalline phase have been investigated. We have performed simulations of the current transient response…

Condensed Matter · Physics 2009-11-07 S. J. Martin , A. Kambili , A. B. Walker

The origin of p-type conductivity and the mechanism responsible for low carrier mobility was investigated in pyrite (FeS2) thin films. Temperature dependent resistivity measurements were performed on polycrystalline and nanostructured thin…

We have investigated the charge carrier transport in organic molecular semiconductors. It has been found that mobility is a function of electric field and temperature due to hopping conduction. Several theoretical models for charge…

Materials Science · Physics 2007-05-23 Ajit Kumar Mahapatro , Subhasis Ghosh

The advent of new-class of high-mobility semiconducting polymers opens up a window to address fundamental issues in electrical transport mechanism such as hopping between localized states versus extended state conduction. Here, we…

Materials Science · Physics 2015-06-23 Satyaprasad P. Senanayak , A. Z. Ashar , Catherine Kanimozhi , Satish Patil , K. S. Narayan

We present a unified calculation method for variable range hopping transport with a varying charge concentration and a varying applied electrical field. We demonstrate that the major differences between the transport properties measured at…

Statistical Mechanics · Physics 2007-05-23 Yohai Roichman , Nir Tessler

We investigated the charge carrier mobility in pristine poly(3-hexyl thiophene-2,5-diyl) (P3HT):[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) blend devices by applying the time resolved photoconductivity experiment in dependence on the…

Materials Science · Physics 2008-12-23 A. Baumann , J. Lorrmann , C. Deibel , V. Dyakonov

Semiconducting polycrystalline thin films are cheap to produce and can be deposited on flexible substrates, yet high-performance electronic devices usually utilize single-crystal semiconductors, owing to their superior electrical mobilities…

The charge carrier transport in metal phthallocyanine based disordered thin films has been investigated. Charge carrier mobility in these disordered thin films strongly depends on the electric field and temperature due to hopping…

Disordered Systems and Neural Networks · Physics 2015-06-25 Ajit Kumar Mahapatro , Subhasis Ghosh

Hybrid (organic-inorganic) materials have emerged as a promising class of thermoelectric materials, achieving power factors exceeding those of either constituent. The mechanism of this enhancement is still under debate, and pinpointing the…

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