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We develop several configuration interaction approaches for characterizing the electronic structure of an adsorbate on a metal surface (at least in model form). When one can separate adsorbate from substrate, these methods can achieve a…

Chemical Physics · Physics 2020-02-26 Zuxin Jin , Wenjie Dou , Joseph E. Subotnik

Multi-configurational wave functions are known to describe electronic structure across a Born-Oppenheimer surface qualitatively correct. However, for quantitative reaction energies, dynamical correlation originating from the many…

Chemical Physics · Physics 2020-04-16 Christopher J. Stein , Markus Reiher

In this work, we extend the x-ray constrained wavefunction fitting approach, a key method in quantum crystallography for charge density reconstruction, to incorporate experimental observables beyond x-ray diffraction. Unlike traditional…

Quantum Physics · Physics 2024-10-31 Stasis Chuchurka , Milaim Kas , Andrei Benediktovitch , Nina Rohringer

The nuclear binding energies for 28 nuclei including several isotopic chains with masses ranging from A=64 to A=226 were evaluated using the Skyrme effective nucleon-nucleon interaction and the Extended Thomas-Fermi approximation. The…

Nuclear Theory · Physics 2009-11-07 A. Dobrowolski , K. Pomorski , J. Bartel

The rotational properties of the transfermium nuclei are investigated in the full deformation space by implementing a shell-model-like approach in the cranking covariant density functional theory on a three-dimensional lattice, where the…

Nuclear Theory · Physics 2024-07-17 F. F. Xu , Y. K. Wang , Y. P. Wang , P. Ring , P. W. Zhao

We present an alternative to the Kohn-Sham formulation of density functional theory for the ground-state properties of strongly interacting electronic systems. The idea is to start from the limit of zero kinetic energy and systematically…

Strongly Correlated Electrons · Physics 2015-05-13 Paola Gori-Giorgi , Michael Seidl , G. Vignale

Excitations of chiral rotation observed in triaxial nuclei and magnetic and/or antimagnetic rotations seen in near-spherical nuclei have attracted a lot of attention. Unlike conventional rotation in well-deformed or superdeformed nuclei,…

Nuclear Theory · Physics 2016-05-04 Jie Meng , Pengwei Zhao

The evolution of shapes and low-energy shape coexistence is analyzed in neutron-deficient Nd and Sm nuclei, using a five-dimensional quadrupole collective Hamiltonian (5DCH). Deformation energy surfaces, calculated with the relativistic…

Nuclear Theory · Physics 2018-12-05 J. Xiang , Z. P. Li , W. H. Long , T. Nikši\' c , D. Vretenar

The accuracy of applying density functional theory to noncovalent interactions is hindered by errors arising from low-density regions of interaction-induced change in the density gradient, error compensation between correlation and exchange…

Chemical Physics · Physics 2014-10-22 Marcin Modrzejewski , Grzegorz Chałasiński , Małgorzata M. Szczęśniak

We have performed self-consistent calculations for first and second row atoms using a variant of density-functional theory, the optimized effective potential method, with an approximation due to Krieger, Li and Iafrate and a…

chem-ph · Physics 2009-10-28 Tobias Grabo , E. K. U. Gross

We test the applicability of density functional theory (DFT) to spectral perturbations taking an example of a Cs atom surrounded by superfluid helium. The atomic DFT of helium is used to obtain the distribution of helium atoms around the…

Atomic Physics · Physics 2008-12-18 Takashi Nakatsukasa , Kazuhiro Yabana , George F. Bertsch

A microscopic formulation of the interacting boson-fermion model for odd-$A$ nuclei is made using the nuclear energy density functional framework. Strength parameters for the bosonic Hamiltonian and boson-fermion interactions are shown to…

Nuclear Theory · Physics 2025-09-22 M. Homma , K. Nomura

Density functional theory (DFT) exploits an independent-particle-system construction to replicate the densities and current of an interacting system. This construction is used here to access the exact effective potential and bias of…

Mesoscale and Nanoscale Physics · Physics 2018-03-30 Daniel Karlsson , Miroslav Hopjan , Claudio Verdozzi

The $SU(3)$ meson exchange approach to interactions within the baryon octet and nuclear density functional theory are used to derive an \emph{ab initio} description of hypernuclear interactions. The density dependence of interactions is…

Nuclear Theory · Physics 2016-03-01 H. Lenske , M. Dhar , T. Gaitanos

The self consistent version of the density functional theory is presented, which allows to calculate the ground state and dynamic properties of finite multi-electron systems. An exact functional equation for the effective interaction, from…

Materials Science · Physics 2017-08-23 M. Ya. Amusia , A. Z. Msezane , V. R. Shaginyan

To explore the applicability of orbital-free density functional theory (OF-DFT) in nuclear physics, we perform a systematic benchmark of 36 one-point kinetic energy density functionals, which are originally developed for electron systems in…

Nuclear Theory · Physics 2026-05-20 Tian Shuai Shang , Jian Li , Haozhao Liang , Xinhui Wu , Cheng Ma , Wenhui Mi , Xuecheng Shao , Yanchao Wang

Shape and multiple shape coexistence of nuclei are investigated throughout the nuclear chart by calculating the low-lying spectra and the quadrupole shape invariants for even-even nuclei with $10\leq Z\leq 104$ from the proton drip line to…

Nuclear Theory · Physics 2023-02-16 Y. L. Yang , P. W. Zhao , Z. P. Li

Density functional theory (DFT) became a universal approach to compute ground-state and excited configurations of many-electron systems held together by an external one-body potential in condensed-matter, atomic, and molecular physics. At…

Nuclear Theory · Physics 2011-09-30 J. Dobaczewski

A new alternative approach to calculate the ratio of the surface to volume components of the nuclear symmetry energy is proposed in the framework of the coherent density fluctuation model (CDFM). A new expression (scheme II) for the ratio…

A method to solve the Schr\"{o}dinger equation based on the use of constant particle-particle interaction potential surfaces is proposed. The many-body wave function is presented in configuration interaction form with coefficients -…

Quantum Physics · Physics 2018-06-19 V. M. Tapilin