Related papers: Critical Drying of Liquids
We report a theoretical and simulation study of the drying and wetting phase transitions of a truncated Lennard-Jones fluid at a flat structureless wall. Binding potential calculations predict that the nature of these transitions depends on…
Employing smart Monte Carlo sampling techniques within the grand canonical ensemble, we investigate the properties of water at a model hydrophobic substrate. By reducing the strength of substrate-water attraction we find that fluctuations…
We investigate density fluctuations in a liquid close to a solvophobic substrate at which a surface critical drying transition occurs. Using classical density functional theory, we determine three measures of the spatial extent and strength…
Depletion of the liquid density near a solid surface with a weak long-range fluid-surface interaction was studied by computer simulations of the liquid-vapor coexistence of a LJ fluid confined in slitlike pores. In a wide temperature range…
Clarifying the factors that control the contact angle of a liquid on a solid substrate is a long-standing scientific problem pertinent across physics, chemistry and materials science. Progress has been hampered by the lack of a…
A solid substrate, when exposed to a vapour, can interact with it in such a way that sufficiently close to liquid-vapour coexistence a macroscopically thick liquid wetting layer is formed on the substrate surface. If such a wetting…
We study numerically the influence of contact angle on slow evaporation in two-dimensional model porous media. For sufficiently low contact angles, the drying pattern is fractal and can be predicted by a simple model combining the invasion…
We present an experimental study of density and order fluctuations in the vicinity of the solid-liquid-like transition that occurs in a vibrated quasi-two-dimensional granular system. The two-dimensional projected static and dynamic…
A theory is derived for the nonequilibrium probability currents of the capillary interaction which determines the pair correlation function near contact. This yields an analytic expression for the equation of state, P = P(N/V,T), of wet…
Critical wetting is an elusive phenomenon for solid-fluid interfaces. Using interfacial models we show that the diverging length scales, which characterize complete wetting at an apex, precisely mimic critical wetting with the apex angle…
Recent work on the complete wetting transition has emphasized the role played by the coupling of fluctuations of the order parameter at the wall and at the depinning fluid interface. Extending this approach to the wetting transition itself…
We report on a high statistics numerical study of the crystalline random surface model with extrinsic curvature on lattices of up to $64^2$ points. The critical exponents at the crumpling transition are determined by a number of methods all…
With the use of thermodynamics and general equilibrium conditions only, we study the entropy of a fluid in the vicinity of the critical point of the liquid-vapor phase transition. By assuming a general form for the coexistence curve in the…
We perform the analysis of predictions of a classical density functional theory for associating fluids with different association strength concerned with wetting of solid surfaces. The four associating sites water-like models with…
We study the motion of a rigid sphere falling in a two-layer stratified fluid under the action of gravity in the potential flow regime. Experiments at a moderate Reynolds number of approximately 20 to 450 indicate that a sphere with the…
We study the critical droplet for a close-to-equilibrium Widom-Rowlinson model of interacting particles, represented by disks of radius $1$, in the two-dimensional plane at low temperature. The critical droplet is the set of macroscopic…
We investigate the origin of the density depletion and enhanced density fluctuations that occur in water in the vicinity of an extended hydrophobic solute. We argue that both phenomena are remnants of the critical drying surface phase…
Simulations of water near extended hydrophobic spherical solutes have revealed the presence of a region of depleted density and accompanying enhanced density fluctuations.The physical origin of both phenomena has remained somewhat obscure.…
We consider the thermal undulation, or shape fluctuation, of an almost planar fluid membrane surrounded by the same near-critical binary fluid mixtures on both sides. A weak preferential attraction is assumed between the membrane and one…
It is well known that, at a macroscopic level, the boundary condition for a viscous fluid at a solid wall is one of "no-slip". The liquid velocity field vanishes at a fixed solid boundary. In this paper, we consider the special case of a…