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Rhombohedral B$_{12}$ unit is viewed as a host matrix embedding linear tri-atomic arrangements of elements (E) resulting in a relatively large family of boron-rich compounds with B$_{12}${E-E-E} generic formulation. The present work focuses…

Materials Science · Physics 2021-01-13 Samir F. Matar , Vladimir L. Solozhenko

The traditional display of elements in the periodic table is convenient for the study of chemistry and physics. However, the atomic number alone is insufficient for training statistical machine learning models to describe and extract…

Materials Science · Physics 2023-08-25 Anthony Onwuli , Ashish V. Hegde , Kevin Nguyen , Keith T. Butler , Aron Walsh

The group IV-VI compound SnSe, with an orthorhombic lattice structure, has recently attracted particular interest due to its unexpectedly low thermal conductivity and high power factor, showing great promise for thermoelectric applications.…

Materials Science · Physics 2017-01-03 Xiaolong Xu , Qingjun Song , Haifeng Wang , Pan Li , Kun Zhang , Yilun Wang , Kai Yuan , Zichen Yang , Yu Ye , Lun Dai

Based on the relativistic spin-polarized density functional theory calculations we investigate the crystal structure, electronic and magnetic properties of a family MnPn2Ch4 compounds, where pnictogen metal atoms (Pn) are Sb and Bi;…

Materials Science · Physics 2018-09-28 S. V. Eremeev , M. M. Otrokov , E. V. Chulkov

A systematic theoretical study of two PbTe-based ternary alloys, Pb1-xCdxTe and Pb1-xMnxTe, is reported. First, using ab initio methods we study the stability of the crystal structure of CdTe - PbTe solid solutions, to predict the…

Materials Science · Physics 2013-05-30 Malgorzata Bukala , Piotr Sankowski , Ryszard Buczko , Perla Kacman

The electronic structure of four polytypes (beta, gamma, delta and epsilon) of hexagonal GaSe and InSe is calculated from first principles, using the WIEN2k and VASP codes and PBEsol prescription for the exchange-correlation potential,…

Materials Science · Physics 2018-02-02 J. Srour , A. Postnikov , M. Badawi , F. El Haj Hassan

Structural disorder is common in metal-halide perovskites and important for understanding the functional properties of these materials. First-principles methods can address structure variation on the atomistic scale, but they are often…

Emergent phenomena at heterointerfaces are directly associated with the bonding geometry of adjacent layers. Effective control of accessible parameters, such as the bond length and bonding angles, offers an elegant method to tailor…

Fabrication of semiconductor heterostructures is now so precise that metrology has become a key challenge for progress in science and applications. It is now relatively straightforward to characterize classic III-V and group IV…

We report $\textit{ab-initio}$ density functional theory calculation and Raman scattering results to explore the electronic structure of Ba$_5$CuIr$_3$O$_{12}$ single crystals. This insulating iridate, consisting of face-sharing IrO$_6$…

Strongly Correlated Electrons · Physics 2018-11-14 Mai Ye , Heung-Sik Kim , Jae-Wook Kim , Choong-Jae Won , Kristjan Haule , David Vanderbilt , Sang-Wook Cheong , Girsh Blumberg

The electronic and energetic properties of the elementary building block, i.e. a five-membered atom ring (pentagon), of the Ge(110) surface was studied by scanning tunneling microscopy and spectroscopy at room temperature. The Ge(110)…

Materials Science · Physics 2017-06-06 Pantelis Bampoulis , Adil Acun , Lijie Zhang , Harold J. W. Zandvliet

We have investigated the ground state structures of neutral and charged XH$_{4}$(X=C, Si, Ge, Sn and Pb) molecules using the first-principles electronic structure methods. The structure of positively charged molecules for X = Si, Ge, Sn and…

Materials Science · Physics 2007-05-23 D. Balamurgan , Manoj. K. Harbola , R. Prasad

The precise crystal symmetry and hence the emergence of the electric polarization still remains an open question in the multiferroic materials $R$Mn$_2$O$_5$ ($R$ = rare-earth, Bi, Y). While previous diffraction studies have indicated that…

Strongly Correlated Electrons · Physics 2022-06-22 N. Narayanan , P. J. Graham , P. Rovillain , J. O'Brien , J. Bertinshaw , S. Yick , J. Hester , A. Maljuk , D. Souptel , B. Büchner , D. Argyriou , C. Ulrich

We examine the structural properties of free standing II-VI and III-V semiconductors at the monolayer limit within first principle density functional theory calculations. A non-polar buckled structure was found to be favoured over a polar…

Mesoscale and Nanoscale Physics · Physics 2018-01-17 Poonam Kumari , Saikat Debnath , Priya Mahadevan

Rock-salt chalcogenide SnTe represents the simplest realization of a topological insulator where a crystal symmetry allows for the appearence of topologically protected metallic states with an even number of Dirac cones on high-symmetry…

Materials Science · Physics 2013-10-09 Paolo Barone , Domenico Di Sante , Silvia Picozzi

Equilibrium atomic configuration and electronic structure of the (001) surface of IV-VI semiconductors PbTe, PbSe, SnTe and SnSe, is studied using the density functional theory (DFT) methods. At surfaces of all those compounds, the…

Materials Science · Physics 2023-09-07 A. Łusakowski , P. Bogusławski , T. Story

Over the last few years, group IV hexagonal-diamond type crystals have acquired great attention in semiconductor physics thanks to the appearance of novel and very effective growth methods. However, many questions remain unaddressed on…

Materials Science · Physics 2020-07-09 Michele Amato , Thanayut Kaewmaraya , Alberto Zobelli

A complicating factor in unraveling the theory of high-temperature (high-Tc) superconductivity is the presence of a "pseudogap" in the density of states, whose origin has been debated since its discovery [1]. Some believe the pseudogap is a…

The alkaline-earth orthovanadate Sr$_3$V$_2$O$_8$ with the palmierite structure is reported to host a dielectric anomaly as well as a structural phase transition above the room temperature. With V$^{5+}$ ions and tetrahedral oxygen…

Materials Science · Physics 2023-11-28 Amartyajyoti Saha , Turan Birol

The low-energy structures of mixed Ar--Xe and Kr--Xe Lennard-Jones clusters are investigated using a newly developed parallel Monte Carlo minimization algorithm with specific exchange moves between particles or trajectories. Tests on the…

Atomic and Molecular Clusters · Physics 2009-11-10 F. Calvo , E. Yurtsever