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We report a numerical study of equilibrium phase-diagrams and interfacial properties of bulk and confined colloid-polymer mixtures using grand canonical Monte Carlo simulations. Colloidal particles are treated as hard spheres, while the…

Soft Condensed Matter · Physics 2009-11-13 Andrea Fortini , Peter G. Bolhuis , Marjolein Dijkstra

We introduce a general physical formulation that allows one to obtain uniquely the effectiveinteractions by contracting the bare forces, even in highly concentrated systems. We tested it bystudying depletion forces in two-dimensional binary…

While colloids are promising building blocks for the self-assembly of materials with novel microstructures, their numerous tunable parameters inhibit brute force searching for appropriate parameter combinations that yield self-assembly of a…

Soft Condensed Matter · Physics 2020-03-13 Beth A Lindquist

We determine the solvent mediated contribution to the effective potentials for model colloidal or nano- particles dispersed in a binary solvent that exhibits fluid-fluid phase separation. Using a simple density functional theory we…

Soft Condensed Matter · Physics 2011-06-24 Paul Hopkins , Andrew J. Archer , Robert Evans

We map dilute or semi-dilute solutions of non-intersecting polymer chains onto a fluid of ``soft'' particles interacting via a concentration dependent effective pair potential, by inverting the pair distribution function of the centers of…

Soft Condensed Matter · Physics 2009-10-31 A. A. Louis , P. G. Bolhuis , J. P. Hansen , E. J. Meijer

We present a theory of effective electrostatic interactions in polydisperse suspensions of charged macroions, generalizing to mixtures a theory previously developed for monodisperse suspensions. Combining linear response theory with a…

Soft Condensed Matter · Physics 2013-08-20 Jun Kyung Chung , Alan R. Denton

Using numerical simulations, we study how a solution of small active disks, acting as depletants, induces effective interactions on large passive colloids. Specifically, we analyze how the range, strength, and sign of these interactions are…

Soft Condensed Matter · Physics 2014-11-20 J. Harder , S. A. Mallory , C. Tung , C. Valeriani , A. Cacciuto

Colloids dispersed in nematic liquid crystals form topological composites in which colloid-associated defects mediate interactions while adhering to fundamental topological constraints. Better realising the promise of such materials…

Soft Condensed Matter · Physics 2024-04-16 Louise C. Head , Yair A. G. Fosado , Davide Marenduzzo , Tyler N. Shendruk

Electrostatic interactions between macroions largely govern the equilibrium thermodynamic and dynamical properties of charge-stabilized colloidal suspensions and polyelectrolyte solutions. Predicting the properties of such complex,…

Soft Condensed Matter · Physics 2012-12-11 Alan R. Denton

Interparticle interactions in charge-stabilized colloidal suspensions, of arbitrary salt concentration, are described at the level of effective interactions in an equivalent one-component system. Integrating out from the partition function…

Soft Condensed Matter · Physics 2009-10-31 A. R. Denton

An effective pair potential for systems of uniformly charged lamellar colloids in the presence of an electrolytic solution of microscopic co- and counterions is derived. The charge distribution on the discs is expressed as a collection of…

Soft Condensed Matter · Physics 2009-10-31 D. G. Rowan , J. -P. Hansen , E. Trizac

Spherically-symmetric atom-centered descriptors of atomic environments have been widely used for constructing potential or free energy surfaces of atomistic and colloidal systems and to characterize local structures using machine learning…

Soft Condensed Matter · Physics 2022-07-27 Gerardo Campos-Villalobos , Giuliana Giunta , Susana Marín-Aguilar , Marjolein Dijkstra

An analytical description of polymer melts and their mixtures as liquids of interacting soft colloidal particles is obtained from liquid-state theory. The derived center-of-mass pair correlation functions with no adjustable parameters…

Soft Condensed Matter · Physics 2009-11-10 G. Yatsenko , E. J. Sambriski , M. A. Nemirovskaya , M. Guenza

Active colloidal particles provide versatile model systems for exploring non-equilibrium physics in motile matter. To date, most experimental realizations have focused on spherical particles, largely due to fabrication constraints. However,…

Soft Condensed Matter · Physics 2026-04-10 Mengshi Wei , Daniela J. Kraft

We propose a method to tune interactions between absorptionless colloidal particle pairs. This is achieved via optimization of the spectral energy density of a homogeneous random optical field. Several standard and more exotic interaction…

Soft Condensed Matter · Physics 2025-10-09 Augustin Muster , Diego Romero Abujetas , Frank Scheffold , Luis S. Froufe-Pérez

The physical behaviour of anisotropic charged colloids is determined by their material dielectric anisotropy, affecting colloidal self-assembly, biological function and even out-of-equilibrium behaviour. However, little is known about…

Soft Condensed Matter · Physics 2021-01-29 Jeffrey C. Everts , Bohdan Senyuk , Haridas Mundoor , Miha Ravnik , Ivan I. Smalyukh

We calculate the two, three, four, and five-body (state independent) effective potentials between the centers of mass (CM) of self avoiding walk polymers by Monte-Carlo simulations. For full overlap, these coarse-grained n-body interactions…

Soft Condensed Matter · Physics 2009-11-07 P. G. Bolhuis , A. A. Louis , J. P. Hansen

The interaction between two particles with shape or interaction anisotropy can be modeled using a pairwise potential energy function that depends on their relative position and orientation; however, this function is often challenging to…

Soft Condensed Matter · Physics 2025-03-03 Mohammadreza Fakhraei , Chris A. Kieslich , Michael P. Howard

Colloidal systems observed in video microscopy are often analysed using the displacements correlation matrix of particle positions. In non-thermal systems, the inverse of this matrix can be interpreted as a pair-interaction potential…

Soft Condensed Matter · Physics 2016-02-03 Michael Schindler , A. C. Maggs

We demonstrate that Widom's particle insertion technique provides a convenient and efficient method to determine the effective pair interaction between complex, composite soft-matter particles in the zero-density limit. By means of three…

Soft Condensed Matter · Physics 2010-11-15 Bianca M. Mladek , Daan Frenkel