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In the present work we compare reliability of several most widely used reduced detailed chemical kinetic schemes for hydrogen-air and hydrogen-oxygen combustible mixtures. The validation of the schemes includes detailed analysis of 0D and…

Fluid Dynamics · Physics 2013-12-13 M. F. Ivanov , A. D. Kiverin , M. A. Liberman , A. E Smygalina

Several chemical networks have been developed to study warm (exo)planetary atmospheres. The kinetics of the reactions related to the methanol chemistry included in these schemes have been questioned. The goal of this paper is to update the…

Earth and Planetary Astrophysics · Physics 2020-02-12 Olivia Venot , Thibault Cavalié , Roda Bounaceur , Pascal Tremblin , Lothaire Brouillard , Romain Lhoussaine Ben Brahim

Context. Clouds are ubiquitous in exoplanets' atmospheres and play an important role in setting the opacity and chemical inventory of the atmosphere. Understanding clouds is a critical step in interpreting exoplanets' spectroscopic data.…

Earth and Planetary Astrophysics · Physics 2024-11-27 Helong Huang , Chris W. Ormel , Michiel Min

HCN is a key ingredient for synthesizing biomolecules such as nucleobases and amino acids. We calculate 42 reaction rate coefficients directly involved with or in competition with the production of HCN in the early Earth or Titan…

Earth and Planetary Astrophysics · Physics 2019-03-12 Ben K. D. Pearce , Paul W. Ayers , Ralph E. Pudritz

We have developed a 1D planetary atmosphere model that solves in a self-consistent manner the evolution of temperature and disequilibrium chemistry in the vertical direction. Thermochemical kinetics is based on a reaction network built from…

Earth and Planetary Astrophysics · Physics 2025-06-16 Marcelino Agundez

The absorption and emission of light by exoplanet atmospheres encode details of atmospheric composition, temperature, and dynamics. Fundamentally, simulating these processes requires detailed knowledge of the opacity of gases within an…

Instrumentation and Methods for Astrophysics · Physics 2024-08-07 Arjun B. Savel , Megan Bedell , Eliza M. -R. Kempton

In this era of exoplanet characterisation with JWST, the need for a fast implementation of classical forward models to understand the chemical and physical processes in exoplanet atmospheres is more important than ever. Notably, the…

Earth and Planetary Astrophysics · Physics 2023-06-28 Julius L. A. M. Hendrix , Amy J. Louca , Yamila Miguel

We present a comprehensive study of the abundance of carbon dioxide in exoplanetary atmospheres in hot, hydrogen-dominated atmospheres. We construct novel analytical models of systems in chemical equilibrium that include carbon monoxide,…

Earth and Planetary Astrophysics · Physics 2016-02-03 Kevin Heng , James R. Lyons

Resolving Orbital and Climate Keys of Earth and Extraterrestrial Environments with Dynamics (ROCKE-3D) is a 3-Dimensional General Circulation Model (GCM) developed at the NASA Goddard Institute for Space Studies for the modeling of…

The chemical environments of young planets are assumed to be largely influenced by impacts of bodies lingering on unstable trajectories after the dissolution of the protoplanetary disk. We explore the chemical consequences of impacts within…

Most observed exoplanets have high equilibrium temperatures. Understanding the chemistry of their atmospheres and interpreting their observations requires the use of chemical kinetic models including photochemistry. The thermal dependence…

Exoplanet atmospheric retrieval is a computational technique widely used to infer properties of planetary atmospheres from remote spectroscopic observations. Retrieval codes typically employ Bayesian sampling algorithms or machine learning…

Earth and Planetary Astrophysics · Physics 2023-03-24 Ryan J. MacDonald , Natasha E. Batalha

Recently discovered exoplanets on close-in orbits should have surface temperatures of 100's to 1000's of K. They are likely tidally locked and synchronously rotating around their parent stars and, if an atmosphere is absent, have surface…

Earth and Planetary Astrophysics · Physics 2015-05-28 Joost van Summeren , Clinton P. Conrad , Eric Gaidos

The atmospheric dynamics of tidally-locked hot Jupiters is characterized by strong equatorial winds. Understanding the interaction between global circulation and chemistry is crucial in atmospheric studies and interpreting observations.…

In this work we investigate the impact of calculating non-equilibrium chemical abundances consistently with the temperature structure for the atmospheres of highly-irradiated, close-in gas giant exoplanets. Chemical kinetics models have…

Earth and Planetary Astrophysics · Physics 2016-10-19 Benjamin Drummond , Pascal Tremblin , Isabelle Baraffe , David S. Amundsen , Nathan J. Mayne , Olivia Venot , Jayesh Goyal

We present the easy-to-use, publicly available, Python package petitRADTRANS, built for the spectral characterization of exoplanet atmospheres. The code is fast, accurate, and versatile; it can calculate both transmission and emission…

Earth and Planetary Astrophysics · Physics 2019-07-23 P. Mollière , J. P. Wardenier , R. van Boekel , Th. Henning , K. Molaverdikhani , I. A. G. Snellen

The identification of molecules in exoplanetary atmospheres is only possible thanks to the availability of high-resolution molecular spectroscopic data. However, due to its intensive and time-consuming generation process, at present, only…

Earth and Planetary Astrophysics · Physics 2023-07-12 Juan C. Zapata Trujillo , Maria M. Pettyjohn , Laura K. McKemmish

The Combustion Toolbox (CT) is a newly developed open-source thermochemical code designed to solve problems involving chemical equilibrium for both gas- and condensed-phase species. The kernel of the code is based on the theoretical…

Chemical Physics · Physics 2026-01-06 Alberto Cuadra , César Huete , Marcos Vera

Hydrogen cyanide (HCN) is a key feedstock molecule for the production of life's building blocks. The formation of HCN in an N$_2$-rich atmospheres requires first that the triple bond between N$\equiv$N be severed, and then that the atomic…

Earth and Planetary Astrophysics · Physics 2019-05-22 Paul B. Rimmer , Sarah Rugheimer

For the calculation of complex neutral/ionized gas phase chemical equilibria, we present a semi-analytical versatile and efficient computer program, called FastChem. The applied method is based on the solution of a system of coupled…

Earth and Planetary Astrophysics · Physics 2018-06-27 J. W. Stock , D. Kitzmann , A. B. C. Patzer , E. Sedlmayr