Related papers: Improved Correlation for Viscosity from Surface Te…
New correlations between viscosity and surface tension are proposed and checked for saturated normal fluids. The proposed correlations contain three or four adjustable coefficients for every fluid. They were obtained by fitting 200 data…
The response of Newtonian liquids to small perturbations is usually considered to be fully described by homogeneous transport coefficients like shear and dilatational viscosity. However, the presence of strong density gradients at the…
In 1966 Pelofsky proposed an empirical linear correlation between the natural logarithm of the surface tension and the reciprocal viscosity, which seems to work adequately for a wide range of fluids. In particular, it has been shown that it…
Electrostatic correlations between ions dissolved in water are known to impact their transport properties in numerous ways, from conductivity to ion selectivity. The effects of these correlations on the solvent itself remain, however, much…
Molecular modelling and simulation of the surface tension of fluids with force fields is discussed. 29 real fluids are studied, including nitrogen, oxygen, carbon dioxide, carbon monoxide, fluorine, chlorine, bromine, iodine, ethane,…
This paper summarizes the properties of strongly correlating liquids, i.e., liquids with strong correlations between virial and potential energy equilibrium fluctuations at constant volume. We proceed to focus on the experimental…
Recently a new approach to the determination of dynamic correlation lengths, {\xi}, for supercooled liquids, based on the properties of the slow (picosecond) vibrational dynamics, was carried out [L. Hong, V.N. Novikov, and A.P. Sokolov,…
In this paper we propose an analytic expression for surface tension of organic compounds. This new expression, originally derived from the statistical-mechanics is shown to represent the experimental surface tension data of 94 different…
Recently Escobedo and Mansoori (AIChE J. 42(5): 1425, 1996) proposed a new expression, originally derived from statistical mechanics, for the surface tension prediction of pure fluids. In this report, the same theory is extended to the case…
Dynamic surface tension measurements play a critical role in interfacial activities for liquids with varying viscosities. Understanding the rate at which the interface attains the equilibrium, for surface tension measurements, after the…
We use a recently proposed method [Berthier L.; Biroli G.; Bouchaud J.P.; Cipelletti L.; El Masri D.; L'Hote D.; Ladieu F.; Pierno M. Science 2005, 310, 1797.] to obtain an approximation to the 4-point dynamic correlation function from…
The master asymptotic behavior of the usual parachor correlations, expressing surface tension $\sigma$ as a power law of the density difference $\rho_{L}-\rho_{V}$ between coexisting liquid and vapor, is analyzed for a series of pure…
The origin of the dramatic changes in the behavior of liquids as they approach their vitreous state - increases of many orders of magnitude in transport properties and dynamic time scales - is a major unsolved problem in condensed matter.…
The recent empirical correlation for the surface tension is further investigated for universality. C5-C8 liquid hydrocarbons, for which accurate surface tension data over the complete liquid range are available, are used. Functional reduced…
We consider the atomistic origin and the main mechanisms determining the energy of a liquid interface after relaxation. A simple theory is constructed for the monatomic densely packed liquids that allows calculation of the surface tension…
Within the framework of relativistic fluctuating hydrodynamics we compute the contribution of thermal fluctuations to the effective infrared shear viscosity of a conformal fluid, focusing on quadratic (in fluctuations), second order (in…
This work investigates the link between residual entropy and viscosity based on wide-ranging, highly accurate experimental and simulation data. This link was originally postulated by Rosenfeld in 1977, and it is shown that this scaling…
Surface tension is a macroscopic manifestation of the cohesion of matter, and its value $\sigma_\infty$ is readily measured for a flat liquid-vapor interface. For interfaces with a small radius of curvature $R$, the surface tension might…
A linear correlation is presented between the reduced surface tension \sigma^* and reduced temperature T^*_{extScal} by applying the extended scaling law. The correlation is applied quite accurately to 17 atomic, diatomic, and molecular…
We present molecular dynamics simulations studying the influence of pressure on the correlation between the constant-volume thermal equilibrium fluctuations of virial W and potential energy U, focusing on liquids that are not strongly…