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Raman and combined trasmission and reflectivity mid infrared measurements have been carried out on monoclinic VO$_2$ at room temperature over the 0-19 GPa and 0-14 GPa pressure ranges, respectively. The pressure dependence obtained for both…

Materials Science · Physics 2010-03-18 E. Arcangeletti , L. Baldassarre , D. Di Castro , S. Lupi , L. Malavasi , C. Marini , A. Perucchi , P. Postorino

The insulator-to-metal transition (IMT) in vanadium dioxide (VO2) has garnered extensive attention for its potential applications in ultrafast switches, neuronal network architectures, and storage technologies. However, a significant…

Materials Science · Physics 2025-01-07 Feng-Wu Guo , Wen-Hao Liu , Zhi Wang , Shu-Shen Li , Lin-Wang Wang , Jun-Wei Luo

In order to study the origin of metallization of VO$_2$ induced by electron injection, we deposit K atoms onto the surface of VO$_2$ films grown on TiO$_2$ (001) substrates, and we investigate the change in the electronic and crystal…

Strongly Correlated Electrons · Physics 2019-03-27 Daisuke Shiga , Makoto Minohara , Miho Kitamura , Ryu Yukawa , Koji Horiba , Hiroshi Kumigashira

We report the simultaneous measurement of the structural and electronic components of the metal-insulator transition of VO$_2$ using electron and photoelectron spectroscopies and microscopies. We show that these evolve over different…

Strongly Correlated Electrons · Physics 2014-11-18 J. Laverock , S. Kittiwatanakul , A. A. Zakharov , Y. R. Niu , B. Chen , S. A. Wolf , J. W. Lu , K. E. Smith

The high-pressure behavior of monoclinic VO$_2$ is revisited by a combination of Raman spectroscopy and X-ray diffraction on a single crystal under hydrostatic conditions at room temperature. A soft mode is observed up to P$_c$ = 13.9(1)…

Strongly Correlated Electrons · Physics 2025-01-14 P. Bouvier , L. Bussmann , D. Machon , I. Breslavetz , G. Garbarino , P. Strobel , V. Dmitriev

Metal-insulator transition underlies many remarkable and technologically important phenomena in VO2. Even though its monoclinic structure had before been the reserve of the insulating state, recent experiments have observed an unexpected…

Strongly Correlated Electrons · Physics 2019-04-30 Yongcheng Liang , Ping Qin , Zhiyong Liang , Xun Yuan , Yubo Zhang

In femtosecond pump-probe measurements, the appearance of coherent phonon oscillations at 4.5 THz and 6.0 THz indicating the rutile metal phase of VO_2 does not occur simultaneously with the first-order metal-insulator transition (MIT) near…

Strongly Correlated Electrons · Physics 2015-06-25 Hyun-Tak Kim , Yong-Wook Lee , Bong-Jun Kim , Byung-Gyu Chae , Sun Jin Yun , Kwang-Yong Kang , Kang-Jeon Han , Ki-Ju Yee , Yong-Sik Lim

An abrupt first-order metal-insulator transition (MIT) without structural phase transition is first observed by current-voltage measurements and micro-Raman scattering experiments, when a DC electric field is applied to a Mott insulator…

Strongly Correlated Electrons · Physics 2015-06-24 Yong-Sik Lim , Hyun-Tak Kim , B. G. Chae , D. H. Youn , K. O. Kim , K. Y. Kang , S. J. Lee , K. Kim

We report the evolution of charge density wave states under pressure for two NbS3 phases triclinic (phase I) and monoclinic (phase II) at room temperature. Raman and X-ray diffraction (XRD) techniques are applied. The x-ray studies on the…

Vanadium dioxide (VO2) undergoes a phase transition at a temperature of 340 K between an insulating monoclinic M1 phase and a conducting rutile phase. Accurate measurements of possible anisotropy of the electronic properties and phonon…

Strongly Correlated Electrons · Physics 2013-07-24 T. J. Huffman , Peng Xu , M. M. Qazilbash , E. J. Walter , H. Krakauer , Jiang Wei , D. H. Cobden , H. A. Bechtel , M. C. Martin , G. L. Carr , D. N. Basov

Vanadium dioxide (VO$_2$) is central in the study of ultrafast photoinduced insulator-to-metal phase transitions in strongly correlated materials, and a primary candidate for next-generation light-driven devices. However, the physical…

Strongly Correlated Electrons · Physics 2025-09-23 S. Mandal , P. Kumar , H. Y. Kim , Z. Pi , J. Xu , D. Chen , D. Kazenwadel , P. Baum , S. Meng , E. Goulielmakis

Vanadium sesquioxide, V2O3, is a prototypical metal-to-insulator system where, in temperature-dependent studies, the transition always coincides with a corundum-to-monoclinic structural transition. As a function of pressure, V2O3 follows…

A strongly correlated Mott first-order metal-insulator transition (MIT) (or Jump) not accompanied by the structural phase transition (SPT) was clearly revealed in VO_2, (New J. Phys. 6 (1004) 52, Appl. Phys. Lett. 86 (2005) 242101, Physica…

Strongly Correlated Electrons · Physics 2007-05-23 Hyun-Tak Kim , Byung-Gyu Chae , Bong-Jun Kim , Yong-Wook Lee , Sun-Jin Yun , Kwang-Yong Kang

Synchrotron X-ray total scattering studies of structural changes in rutile VO2 at the metal-insulator transition temperature of 340 K reveal that monoclinic and tetragonal phases of VO2 coexist in equilibrium, as expected for a first-order…

Materials Science · Physics 2010-08-10 Serena A. Corr , Daniel P. Shoemaker , Brent C. Melot , Ram Seshadri

The correlated electron system SmNiO3 exhibits a metal-insulator phase transition at 130 {\deg}C. Using an ionic liquid as an electric double layer (EDL) gate on three-terminal ultrathin SmNiO3 devices, we investigate gate control of the…

Materials Science · Physics 2013-05-10 Sieu D. Ha , Ulrich Vetter , Jian Shi , Shriram Ramanathan

We apply ultrafast spectroscopy to establish a time-domain hierarchy between structural and electronic effects in a strongly-correlated electron system. We discuss the case of the model system VO2, a prototypical non-magnetic compound that…

Strongly Correlated Electrons · Physics 2007-05-23 A. Cavalleri , Th. Dekorsy , H. H. Chong , J. C. Kieffer , R. W. Schoenlein

Vanadium dioxide (VO2) has drawn significant attention for its near room temperature insulator to metal transition and associated structural phase transition. The underlying Physics behind the temperature induced insulator to metal and…

Materials Science · Physics 2023-04-19 S. R. Sahu , S. S. Majid , A. Ahad , A. Tripathy , K. Dey , S. Pal , B. K. De , Wen-Pin Hsieh , R. Rawat , V. G. Sathe , D. K. Shukla

In this paper we used Raman spectroscopy to investigate the optical properties of vanadium dioxide (VO2) thin films during the thermally induced insulating to metallic phase transition. We observed a significant difference in transition…

Materials Science · Physics 2013-01-14 E. Radue , E. Crisman , L. Wang , S. Kittiwatanakul , J. Lu , S. A. Wolf , R. Wincheski , R. A. Lukaszew , I. Novikova

We present a theoretical investigation of the electronic structure of rutile (metallic) and M$_1$ and M$_2$ monoclinic (insulating) phases of VO$_2$ employing a fully self-consistent combination of density functional theory and embedded…

Strongly Correlated Electrons · Physics 2016-08-03 W. H. Brito , M. C. O. Aguiar , K. Haule , G. Kotliar

Vanadium dioxide (VO$_2$) undergoes a metal-insulator transition (MIT) at 340 K with the structural change between tetragonal and monoclinic crystals as the temperature is lowered. The conductivity $\sigma$ drops at MIT by four orders of…

Materials Science · Physics 2015-06-03 Shigeji Fujita , Azita Jovaini , Salvador Godoy , Akira Suzuki
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