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Use of density-functional theory in a $\Delta$self-consistent field framework result in both the ground- and two lowest electronicly excited states of the NaCl and LiCl. The accuracy of this method is confirmed using a multi-configuration…

Chemical Physics · Physics 2007-05-23 A. Hellman , M. Slabanja

A recent work [arXiv:2401.04685] has merged $N$-centered ensembles of neutral and charged electronic ground states with ensembles of neutral ground and excited states, thus providing a general and in-principle exact (so-called extended…

Strongly Correlated Electrons · Physics 2024-05-14 Filip Cernatic , Emmanuel Fromager

To describe excited states, the electron density alone being insufficient, we use the noninteracting reference density matrix $\gamma_{s}({\bf x},{\bf x}')$ based on the recently established foundation for the $\Delta SCF$ theory, in which…

Chemical Physics · Physics 2024-08-20 Weitao Yang , Yichen Fan

Self-energy-functional theory is a formal framework which allows to derive non-perturbative and thermodynamically consistent approximations for lattice models of strongly correlated electrons from a general dynamical variational principle.…

Strongly Correlated Electrons · Physics 2011-12-08 Michael Potthoff

We present conditional probability (CP) density functional theory (DFT) as a formally exact theory. In essence, CP-DFT determines the ground-state energy of a system by finding the CP density from a series of independent Kohn-Sham (KS) DFT…

Chemical Physics · Physics 2022-06-28 Ryan Pederson , Jielun Chen , Steven R. White , Kieron Burke

We present lattice calculations for the ground state energy of dilute neutron matter at next-to-leading order in chiral effective field theory. This study follows a series of recent papers on low-energy nuclear physics using chiral…

Nuclear Theory · Physics 2015-05-13 Evgeny Epelbaum , Hermann Krebs , Dean Lee , Ulf-G. Meißner

Current-density-functional theory is used to calculate ionization energies of current-carrying atomic states. A perturbative approximation to full current-density-functional theory is implemented for the first time, and found to be…

Materials Science · Physics 2009-11-10 E. Orestes , T. Marcasso , K. Capelle

In a previous work, the meaning of the Planck constant $h = \left( e^2 / 2 \alpha \right) \sqrt{\mu_0 / \epsilon_0}$, accomplished by solving Maxwell's electrodynamics laws with specific electric $1 / \tau_C = 1 / R_q C_q$ and magnetic $1/…

General Physics · Physics 2023-03-02 Paulo Roberto Bueno

Orbital-free Density Functional Theory (OF-DFT) has been used when studying atoms, molecules and solids. In nuclear physics, there has been basically no application of OF-DFT so far, as the Density Functional Theory (DFT) has been widely…

Nuclear Theory · Physics 2023-08-03 Gianluca Colo' , Kouichi Hagino

We prove that the electron density function of a real physical system can be uniquely determined by its values on any finite subsystem. This establishes the existence of a rigorous density-functional theory for any open electronic system.…

Quantum Physics · Physics 2007-05-23 Xiao Zheng , Fan Wang , GuanHua Chen

Motivated by recent suggestions --to split the electron-electron interaction into a short-range part, to be treated within the density functional theory, and a long-range part, to be handled by other techniques-- we compute, with a…

Materials Science · Physics 2009-11-10 Lorenzo Zecca , Paola Gori-Giorgi , Saverio Moroni , Giovanni B. Bachelet

The Exact Factorization framework is extended and utilized to introduce the electronic-states of correlated electron-photon systems. The formal definitions of an exact scalar potential and an exact vector potential that account for the…

Quantum Physics · Physics 2018-09-26 Ali Abedi , Elham Khosravi , Ilya Tokatly

In the accompanying Comment [Phys. Rev. A {\bf 67}, 056501 (2003)], I. Lindgren and S. Salomonson claim to prove for the Kohn-Sham kinetic energy functional of ground state electron density that a Fr\"echet functional derivative exists,…

Atomic Physics · Physics 2007-05-23 R. K. Nesbet

We calculate the ground state energies of a system of two dipolar fermions trapped in a harmonic oscillator potential. The dipoles are assumed to be aligned parallel to each other. We perform the calculations of ground state energy as a…

Atomic and Molecular Clusters · Physics 2014-10-09 Amit K. Das , Arup Banerjee

We study the effect of a constant uniform magnetic field on an electrically charged massive particle (an electron) bound by a potential well, which is described by means of a single attractive $\lambda\delta({\bf r})$ potential. A…

Quantum Physics · Physics 2009-11-13 V. R. Khalilov , F. Kh. Chibirova

Perhaps the simplest first-principles approach to electronic structure is to fit the charge distribution of each orbital pair and use those fits wherever they appear in the entire electron-electron (EE) interaction energy. The charge…

Chemical Physics · Physics 2015-11-10 Brett I Dunlap , Mark C Palenik

The purpose of this paper is to derive sharp asymptotics of the ground state energy for the heavy atoms and molecules in the relativistic settings, with the self-generated magnetic field, and, in particular, to derive relativistic Scott…

Spectral Theory · Mathematics 2017-08-28 Victor Ivrii

The correlation between electrons in different quantum wires is expected to affect the electronic properties of quantum electron-electron biwire systems. Here, we use the variational Monte Carlo method to study the ground-state properties…

Quantum Gases · Physics 2021-08-04 Rajesh O. Sharma , N. D. Drummond , Vinod Ashokan , K. N. Pathak , Klaus Morawetz

We calculate the ground-state energy, pair correlation function, static structure factor, and momentum density of the one-dimensional electron fluid at high density using variational quantum Monte Carlo simulation. For an infinitely thin…

Strongly Correlated Electrons · Physics 2018-10-03 Vinod Ashokan , N. D. Drummond , K. N. Pathak

The Exact Factorization (EF) theory aims at the separation of the nuclear and electronic degrees of freedom in the many-body (MB) quantum mechanical problem. Being formally equivalent to the solution of the MB Schr\"{o}dinger equation, EF…

Quantum Physics · Physics 2026-05-01 Vladimir U. Nazarov , E. K. U. Gross
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