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The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…

Surface enhanced Raman spectra from molecules (bipyridyl ethylene) adsorbed on gold dumbells are observed to become increasingly asymmetric (Fano-like) at higher incident light intensity. The electronic temperature (inferred from the…

Mesoscale and Nanoscale Physics · Physics 2016-01-12 S. Dey , M. Banik , E. Hulkko , K. Rodriguez , V. A. Apkarian , M. Galperin , A. Nitzan

The electronic structure of two V-based ladder compounds, the quarter-filled NaV$_2$O$_5$ in the symmetric phase and the iso-structural half-filled CaV$_2$O$_5$ is investigated by ab initio calculations. Based on the bandstructure we…

Other Condensed Matter · Physics 2009-11-10 J. Spitaler , E. Ya. Sherman , H. G. Evertz , C. Ambrosch-Draxl

The dipole-dipole interactions between excitons are of paramount importance in the nanoscale structures. When two excitons are placed together they can exchange the energy can manifest in the resonant Raman cross sections. We provide…

Mesoscale and Nanoscale Physics · Physics 2024-04-09 Anna Wroblewska , Niclas S. Mueller , Mariusz Zdrojek , Stephanie Reich , Georgy Gordeev

The strong coupling between two subsystems consisting of quantum emitters and photonic modes, at which the level splitting of mixed quantum states occurs, has been a central subject of quantum physics and nanophotonics due to various…

Optics · Physics 2021-06-30 Renming Liu , Yi-Cong Yu , Xue-Hua Wang

The bosonisation technique is used to calculate the resonant Raman spectrum of a quantum wire with two electronic sub-bands occupied. Close to resonance, the cross section at frequencies in the region of the inter sub-band transitions shows…

Strongly Correlated Electrons · Physics 2009-11-07 E. Mariani , M. Sassetti , B. Kramer

Multi-particle correlations of exciton-polaritons and reservoir-excitons in the strong light-matter coupling regime dictate the quantum dynamics of optical microcavities. In this letter, we examine the many-body exciton-polariton dynamics…

A new numerical method is introduced for calculating the polarizability of an arbitrary dielectric object with position dependent complex permittivity. Three separate numerical approaches are provided to calculate the dipole moment of a…

Materials Science · Physics 2022-03-18 Daniel B. Murray , Caleb H. Netting , Robin D. Mercer , Lucien Saviot

Plasmon-enhanced Raman scattering can push single-molecule vibrational spectroscopy beyond a regime addressable by classical electrodynamics. We employ a quantum electrodynamics (QED) description of the coherent interaction of plasmons and…

We show how to simulate a model of many molecules with both strong coupling to many vibrational modes and collective coupling to a single photon mode. We do this by combining process tensor matrix product operator methods with a mean-field…

Quantum Gases · Physics 2022-10-24 Piper Fowler-Wright , Brendon W. Lovett , Jonathan Keeling

Semiconductor microcavity polaritons, formed via strong exciton-photon coupling, provide a quantum many-body system on a chip, featuring rich physics phenomena for better photonic technology. However, conventional polariton cavities are…

Mesoscale and Nanoscale Physics · Physics 2018-05-09 Long Zhang , Rahul Gogna , Will Burg , Emanuel Tutuc , Hui Deng

We demonstrate theoretically that photon-photon attraction can be engineered in the continuum of scattering states for pairs of photons propagating in a hollow-core photonic crystal fiber filled with cold atoms. The atoms are regularly…

Quantum Physics · Physics 2016-05-31 Marina Litinskaya , Edoardo Tignone , Guido Pupillo

Molecular complexes are held together via a variety of bonds, but they all share the common feature that their individual entities are in contact. In this work, we introduce and demonstrate the concept of a \textit{molecular optical bond},…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Jahangir Nobakht , André Pscherer , Jan Renger , Stephan Götzinger , Vahid Sandoghdar

The interaction between excited states of a molecule and excited states of metal nanostructure (e.g. plasmons) leads to hybrid states with modified optical properties. When plasmon resonance is swept through molecular transition frequency…

Chemical Physics · Physics 2022-05-04 Monosij Mondal , Maicol A. Ochoa , Maxim Sukharev , Abraham Nitzan

Molecular polaritons, hybrid light-matter states resulting from strong cavity coupling of optical transitions, may provide a new route to guide chemical reactions. However, demonstrations of cavity-modified reactivity in clean benchmark…

Chemical Physics · Physics 2024-08-20 Liying Chen , Ashley P. Fidler , Alexander M. McKillop , Marissa L. Weichman

The scattering of a flying photon by a two-level system ultrastrongly coupled to a one-dimensional photonic waveguide is studied numerically. The photonic medium is modeled as an array of coupled cavities and the whole system is analyzed…

For many materials, Raman spectra are intricately structured and provide valuable information about compositional stoichiometry and crystal quality. Here we use density-functional theory calculations, mass approximation, and the Raman…

Materials Science · Physics 2024-09-04 Nima Ghafari Cherati , I. Abdolhosseini Sarsari , Arsalan Hashemi , Tapio Ala-Nissila

We develop a microscopic description of an electron-doped two-dimensional semiconductor embedded in a microcavity. Specifically, we investigate the interactions between exciton-polaritons and electrons for the case where the interactions…

Mesoscale and Nanoscale Physics · Physics 2021-05-19 Guangyao Li , Olivier Bleu , Jesper Levinsen , Meera M. Parish

Strong light-matter coupling has shown great potential for modifying the electro-optical properties of semiconducting materials in recent years. In the strong coupling regime, excitons and cavity photons form new states named…

Applied Physics · Physics 2023-11-23 Yahui Tang , Alexandra Stuart , Timothy van der Laan , Girish Lakhwani

Generating a coherent optical frequency comb at an arbitrary wavelength is important for fields such as spectroscopy and optical communications. Dark solitons which are coherent states of optical frequency combs in normal dispersion…

Optics · Physics 2023-08-02 Gwangho Choi , Judith Su