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We have successfully synthesized a new layered iron oxychalcogenide BaFe2OSe2 single crystal. This compound is built up of Ba and Fe-Se(O) layers alternatively stacked along the c-axis. The Fe-Se(O) layers contain double chains of…

Superconductivity · Physics 2015-06-05 Hechang Lei , Hyejin Ryu , John Warren , A. I. Frenkel , V. Ivanovski , B. Cekic , C. Petrovic

A new layered iron-oxychalcogenide Na2Fe2OSe2 has been synthesized and structurally characterized by powder X-ray diffraction. The structure is formed by alternate stacking of the newly discovered [Fe2OSe2] blocks and double layers of Na.…

Strongly Correlated Electrons · Physics 2013-05-29 J. B. He , D. M. Wang , H. L. Shi , H. X. Yang , J. Q. Li , G. F. Chen

The recent discovery of superconductivity with relatively high transition temperature Tc in the layered iron-based quaternary oxypnictides La[ O1-xFx] FeAs was a real surprise. The excitement generated can be seen by the number of…

PbO-type Fe chalcogenide has been drawing much attention as the Fe-based superconductor with the most simple crystal structure. Whereas FeSe is an intrinsic superconductor, FeTe, while having a structure analogous to FeSe, exhibits…

Superconductivity · Physics 2011-05-27 Yoshikazu Mizuguchi , Yoshihiko Takano

We report the synthesis and physical properties studies of quais-1D iron chalcogenide $\rm BaFe_2Se_4$ which shares the $\rm FeSe_4$ tetrahedra building motif commonly seen in the iron chalcogenide superconductors. A high-quality…

Strongly Correlated Electrons · Physics 2020-11-11 Xiaoyuan Liu , Keith M. Taddei , Sheng Li , Wenhao Liu , Nikhil Dhale , Rashad Kadado , Diana Berman , Clarina Dela Cruz , Bing Lv

Single crystal synchrotron X-ray diffraction as a function of temperature and pressure has revealed a complex biphase mixture in superconducting FeSe. Based on our experimental results we construct a phase diagram where structural behavior…

Superconductivity · Physics 2017-08-02 V. Svitlyk , M. Raba , V. Dmitriev , P. Rodiere , P. Toulemonde , D. Chernyshov , M. Mezouar

Here we report the electronic structure of FeS, a recently identified iron-based superconductor. Our high-resolution angle-resolved photoemission spectroscopy studies show two hole-like ($\alpha$ and $\beta$) and two electron-like ($\eta$…

The crystal structure of the superconductor FeSe0.44Te0.56 was redetermined by high-resolution X-ray single crystal diffraction at 173 K (anti-PbO-type, P4/nmm, a=3.7996(2), c=5.9895(6) A, R1=0.022, wR2=0.041, 173 F^2). Significantly…

Superconductivity · Physics 2010-02-24 Marcus Tegel , Catrin Loehnert , Dirk Johrendt

Oxygen solubility in solid iron is extremely low, even at high pressures and temperatures. Thus far, no Fe-O compounds between Fe and FeO endmembers have been reported experimentally. We observed chemical reactions of Fe with FeO or…

Using angle-resolved photoemission spectroscopy (ARPES), we revealed the surface electronic structure and superconducting gap of (Li$_{0.8}$Fe$_{0.2}$)OHFeSe, an intercalated FeSe-derived superconductor without antiferromagnetic phase or…

We report on the synthesis of large single crystals of a new FeSe-layer superconductor Cs0.8(FeSe0.98)2. X-ray powder diffraction, neutron powder-diffraction and magnetization measurements have been used to compare the crystal structure and…

(Li0.8Fe0.2)OHFeSe is a newly-discovered intercalated iron-selenide superconductor with a Tc above 40 K, which is much higher than the Tc of bulk FeSe (8 K). Here we report a systematic study of (Li0.8Fe0.2)OHFeSe by low temperature…

Superconductivity · Physics 2016-10-12 Y. J. Yan , W. H. Zhang , M. Q. Ren , X. Liu , X. F. Lu , N. Z. Wang , X. H. Niu , Q. Fan , J. Miao , R. Tao , B. P. Xie , X. H. Chen , T. Zhang , D. L. Feng

Superconducting iron chalcogenide FeSe has the simplest crystal structure among all the Fe-based superconductors. Unlike other iron pnictides, FeSe exhibits no long range magnetic order accompanying the tetragonal-to-orthorhombic structural…

We study the crystalline and electronic properties of the $\textrm{Fe}_{1-x}\textrm{Co}_x\textrm{Se}$ system ($x=0$, 0.25, 0.5, 0.75, and 1.0) using X-ray diffraction, X-ray spectroscopy and density functional theory. We show that the…

Superconductivity · Physics 2014-07-22 I. Perez , J. A. McLeod , R. J. Green , R. Escamilla , V. Ortiz , A. Moewes

Exploration of new superconductors has always been one of the research directions in condensed matter physics. We report here a new layered heterostructure of [(Fe,Al)(OH)2][FeSe]1.2, which is synthesized by the hydrothermal ion-exchange…

We report on the first investigation of the quasiparticle local density of states and superconducting gap in the iron chalcogenide superconductor Fe$_{1+\delta}$Se$_{1-x}$Te$_{x}$ ($T_{\mathrm{c}} \sim 14$ K). The surface of a cleaved…

The metal-metal bond in metal-rich chalcogenide is known to exhibit various structures and dominate interesting physical properties. Ta2Se can be obtained by both arc-melting and solid-state pellet methods. Ta2Se crystallizes a layered…

Superconductivity · Physics 2020-06-23 Xin Gui , Karolina Gornicka , Tomasz Klimczuk , Weiwei Xie

The Fe-based superconducting KxFe2-ySe2 (0.6 {\leg} x {\leg} 1, 0.2{\leg} y {\leg} 0.4) compounds, unlike the well-known RFe2As2 (R = Ba, Sr, Ca) superconductors, contain complex structural features and notable physical properties, such as…

Superconductivity · Physics 2011-04-29 J. Q. Li , Y. J. Song , H. X. Yang , Z. Wang , H. L. Shi , G. F. Chen , Z. W. Wang , Z. Chen , H. F. Tian

A new iron-based superconductor (Ca,Pr)FeAs2 was discovered. Plate-like crystals of the new phase were obtained and crystal structure was investigated by single-crystal X-ray diffraction analysis. The structure was identified as the…

The sawtooth lattice shares some structural similarities with the kagome lattice and may attract renewed research interest. Here, we report a comprehensive study on the physical properties of Fe$_2$SiSe$_4$, an unexplored member in the…

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