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Functional polymers, such as poly(ethylene glycol) (PEG) terminated with a single phosphonic acid, hereafter PEGik-Ph are often applied to coat metal oxide surfaces during post synthesis steps, but are not sufficient to stabilize sub-10 nm…

We investigate "Posner molecules", calcium phosphate clusters with chemical formula Ca$_9$(PO$_4$)$_6$. Originally identified in hydroxyapatite, Posner molecules have also been observed as free-floating molecules $in$ $vitro$. The formation…

Chemical Physics · Physics 2019-04-04 Michael W. Swift , Chris G. Van de Walle , Matthew P. A. Fisher

Active colloids, also known as artificial microswimmers, are self-propelled micro and nanoparticles that convert uniform sources of fuel (e.g. chemical) or uniform external driving fields (e.g. magnetic or electric) into directed motion by…

Soft Condensed Matter · Physics 2017-01-30 Songbo Ni , Emanuele Marini , Ivo Buttinoni , Heiko Wolf , Lucio Isa

We report the chemical synthesis of Fe-core/Au-shell nanoparticles by a reverse micelle method, and the investigation of their growth mechanisms and oxidation-resistant characteristics. The core-shell structure and the presence of the Fe &…

Red abalone nacre is an intensely studied biomineral, and yet its formation mechanism remains poorly understood. Here we report quantitative measurements probing the degree of order of the aragonite tablets in nacre, and show that order…

Materials Science · Physics 2007-10-26 Rebecca A. Metzler , Dong Zhou , Mike Abrecht , Susan N. Coppersmith , P. U. P. A. Gilbert

Bimetallic nanoparticles (often known as nanoalloys) with core-shell arrangement are of special interest in several applications, such as in optics, catalysis, magnetism and biomedicine. Despite wide interest in applications, the physical…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Davide Bochicchio , Riccardo Ferrando

3D porous scaffolds based on agarose and nanocrystalline apatite, two structural components that act as a temporary mineralized extracellular matrix, were prepared by the GELPOR3D method. This shaping technology allows the introduction of…

Tissues and Organs · Quantitative Biology 2021-03-18 Juan L. Paris , Nuria Lafuente-Gomez , M. Victoria Cabanas , Jesus Roman , Juan Pena , Maria Vallet-Regi

Arguably the most ubiquitous construction material in modern civilization, concrete is enabling the development of megacities around the globe together with increasing living standards in developing nations. However, it can be argued that…

Materials Science · Physics 2019-03-27 Kengran Yang , Claire E. White

Straight-chain (normal-propyl cyanide, n - C3H7CN) and branched-chain (iso-propyl cyanide, i - C3H7CN) alkyl cyanides are recently identified in the massive star-forming regions (Sgr B2(N) and Orion). These branched-chain molecules indicate…

Astrophysics of Galaxies · Physics 2022-08-09 Satyam Srivastav , Milan Sil , Prasanta Gorai , Amit Pathak , Bhalamurugan Sivaraman , Ankan Das

Nacre, commonly known as mother-of-pearl, is a remarkable biomineral that in red abalone consists of layers of 400-nm thick aragonite crystalline tablets confined by organic matrix sheets, with the $(001)$ crystal axes of the aragonite…

Soft Condensed Matter · Physics 2009-11-13 S. N. Coppersmith , P. U. P. A. Gilbert , R. A. Metzler

We report the co-assembly and adsorption properties of coacervate complexes made from polyelectrolyte-neutral block copolymers and oppositely charged nanocolloids. The nanocolloids put under scrutiny were ionic surfactant micelles and…

Fe3C/few-layered graphene core/shell nanoparticles embedded in a carbon matrix are synthesized by a novel two-step surfactant sol-gel strategy, where the processes of hydrolysis, polycondensation and drying take place in a one-pot. The…

The peculiar linear temperature-dependent swelling of core-shell microgels has been conjectured to be linked to the core-shell architecture combining materials of different transition temperatures. Here the structure of pNIPMAM-core and…

A pearl's distinguished beauty and toughness are attributable to the periodic stacking of aragonite tablets known as nacre. Nacre has naturally occurring mesoscale periodicity that remarkably arises in the absence of discrete translational…

We describe a novel application of atomic force microscopy (AFM) to directly visualize cytoskeletal fibers in human foreskin epithelial cells. The nonionic detergent Triton X-100 in a low concentration was used to remove the membrane,…

Biological Physics · Physics 2007-05-23 T. Berdyyeva , C. D. Woodworth , I. Sokolov

Silicon nanocrystals with diameters between 1 and 3 nm and surfaces passivated by chlorine or a mixture of chlorine and hydrogen were modeled using density functional theory, and their properties compared with those of fully hydrogenated…

Mesoscale and Nanoscale Physics · Physics 2013-11-06 A. Carvalho , S. Öberg , M. J. Rayson , P. R. Briddon

Based on combination of experimental measurements and first-principles calculations we report a novel carbon-based catalytic material and describe significant acceleration of the hydrogenation of magnesium at room temperature in presence of…

Materials Science · Physics 2012-11-13 A. Ye. Yermakov , D. W. Boukhvalov , M. A. Uimin , E. S. Lokteva , A. V. Erokhin , N. N. Schegoleva

Transmission electron microscopy has undergone a revolution in recent years with the possibility to perform routine cryo-imaging of biological materials and (bio)chemical systems, as well as the possibility to image liquids via dedicated…

Crystallization of proteins, specifically proteins of medical relevance, is performed for various reasons such as to understand the protein structure and to design therapies. Obtaining kinetic constants in rate laws for nucleation and…

Under ambient conditions, we directly observed NaCl crystals experimentally in the rGO membranes soaked in the salt solution with concentration below and far below the saturated concentration. Moreover, in most probability, the NaCl…