Related papers: New Closed Virial Equation of State for Hard-Spher…
Although many equations of state of hard-disk fluids have been proposed, none is capable of reproducing the currently calculated or estimated values of the first eighteen virial coefficients at the same time as giving very good accuracy…
Using the first seven known virial coefficients and forcing it to possess two branch-point singularities, a new equation of state for the hard-sphere fluid is proposed. This equation of state predicts accurate values of the higher virial…
Based on the survey of the literatures on the new improvements on the equation of state (EOS) for the hard sphere fluids, we here compare lots of different EOSs and present a very accurate equation of state for this kind of fluids. The new…
The asymptotic expansion method is extended by using currently available accurate values for the first ten virial coefficients for hard sphere fluids. It is then used to yield an equation of state for hard sphere fluids, which accurately…
Recent values for virial coefficients up to B12, when expressed in powers of density relative to maximum close packing,lead to a closed equation-of-state for the equilibrium fluid. The series obtained converges for all densities;it becomes…
Virial coefficients for the two-dimensional hard-disk fluid, when expressed in powers of density relative to maximum close packing, lead to an accurate closed equation-of-state for the equilibrium fluid, analogous to that recently found for…
We propose a new semi empirical expression of the virial coefficients for a hard sphere fluid which is valid in the disordered phase over the whole density range. The results are in good agreement with the numerical data and better than…
A closed virial equation-of-state for the low density fluid phase of hard disks is obtained from the known virial coefficients. The equation exhibits 6-figure accuracy for the thermodynamic (MD) pressure up to the reduced number density ~…
A new analytical approach to derive an approximate equation of state and the virial coefficients for simple fluids is presented. Starting from the usual expression of the partition function, we first perform a Fourier transformation, and…
Despite the fact that more that more than 30 analytical expressions for the equation of state of hard-disk fluids have been proposed in the literature, none of them is capable of reproducing the currently accepted numeric or estimated…
New proposals for the equation of state of four- and five-dimensional hard-hypersphere mixtures in terms of the equation of state of the corresponding monocomponent hard-hypersphere fluid are introduced. Such proposals (which are…
Following the work of Leutheusser [Physica A 127, 667 (1984)], the solution to the Percus-Yevick equation for a seven-dimensional hard-sphere fluid is explicitly found. This allows the derivation of the equation of state for the fluid…
We evidence via a computation in the reciprocal space the asymptotic behaviour of the high order virial coefficients for a hard sphere system. These coefficients, if their order is high enough, are those of a geometric series. We thus are…
The question of whether the known virial coefficients are enough to determine the packing fraction $\eta_\infty$ at which the fluid equation of state of a hard-sphere fluid diverges is addressed. It is found that the information derived…
An equation of state for a multicomponent mixture of non-additive hard spheres in $d$ dimensions is proposed. It yields a rather simple density dependence and constitutes a natural extension of the equation of state for additive hard…
We present new molecular dynamics results for the pressure of the pure hard disk fluid up to the hexatic transition (about reduced density 0.9). The data combined with the known virial coefficients (up to $B_{10}$) are used to build an…
Here we present new results obtained for the equation of state with induced surface and curvature tensions. The explicit formulas for the first five virial coefficients of system pressure and for the induced surface and curvature tension…
The composition-independent virial coefficients of a $d$-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the mixture [Santos, A., Yuste, S. B., and L\'opez de Haro,…
We use the Percus-Yevick approach in the chemical-potential route to evaluate the equation of state of hard hyperspheres in five dimensions. The evaluation requires the derivation of an analytical expression for the contact value of the…
A new method of estimating high-order virial coefficients for fluids composed of equal three-dimensional rigid spheres is proposed. The predicted $B_{11}$ and $B_{12}$ values are in good agreement with reliable estimates previously…