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The elastic moduli, elastic anisotropy coefficients, sound velocities and Poisson's ratio of hcp solid helium have been calculated using density functional theory in generalized gradient approximation (up to $30$ TPa), and pair+triple…

Other Condensed Matter · Physics 2015-06-19 A. Grechnev , S. M. Tretyak , Yu. A. Freiman , Alexander F. Goncharov , Eugene Gregoryanz

Combining experiment and theory, we investigate how the naturally created heterojunction at a graphene and metallic contact is modulated via interaction with molecular hydrogen (H2). Due to electrostatic interaction, a Cr/Au electrode…

Pristine graphene is not suitable for hydrogen storage at ambient conditions since it binds the hydrogen molecules only by van der Waals interactions. However, the adsorption energy of the hydrogen molecules can be improved by doping or…

Materials Science · Physics 2022-10-24 Vikram Mahamiya , Alok Shukla , Nandini Garg , Brahmananda Chakraborty

We show that the electron-phonon coupling in graphene, in contrast with the non-relativistic two-dimensional electron gas, leads to shifts in the phonon frequencies that are non-trivial functions of the electronic density. These shifts can…

Strongly Correlated Electrons · Physics 2013-05-29 A. H. Castro Neto , Francisco Guinea

Architected 2D lattice materials are appealing for shape-shifting applications due to the tunable sign of Poisson's ratio. It is commonly believed that the positive and negative Poisson's ratios lead to anticlastic and synclastic curvatures…

Soft Condensed Matter · Physics 2022-11-04 Yu Yao , Yong Ni , Ling-hui He

Density functional calculations of electronic structure, total energy, structural distortions, and magnetism for hydrogenated single-layer, bilayer, and multi-layer graphene are performed. It is found that hydrogen-induced magnetism can…

Materials Science · Physics 2008-01-24 D. W. Boukhvalov , M. I. Katsnelson , A. I. Lichtenstein

Graphene is an attractive electrode material to contact nanostructures down to the molecular scale since it can be gated electrostatically. Gating can be used to control the doping and the energy level alignment in the nanojunction, thereby…

Mesoscale and Nanoscale Physics · Physics 2016-01-20 Nick R. Papior , Tue Gunst , Daniele Stradi , Mads Brandbyge

We propose a multi-layer graphene-based device in which storage and release of atomic hydrogen is obtained by exploiting and controlling the corrugation of the layers. The proposal is based on density-functional simulations of hydrogen…

Mesoscale and Nanoscale Physics · Physics 2011-01-07 Valentina Tozzini , Vittorio Pellegrini

We report significant changes of optical conductivity in single layer graphene induced by mild oxygen plasma exposure, and explore the interplay between carrier doping, disorder, and many-body interactions from their signatures in the…

The hydrogen dynamics on a graphene sheet is studied in the presence of carbon vacancies. We analyze the motion of atomic H by means of molecular dynamics (MD) simulations, using a tight-binding Hamiltonian fitted to density-functional…

Chemical Physics · Physics 2022-09-29 Carlos P. Herrero , Jose A. Verges , Rafael Ramirez

Using molecular dynamics simulations, we probe a suspended graphene layer by a diamond-like-carbon tip at various temperatures. The force acting on the tip in the sliding direction is measured to be negative at liquid-helium temperature.…

Mesoscale and Nanoscale Physics · Physics 2021-06-22 Zhao Wang

We study an inhomogeneous random connection model in the connectivity regime. The vertex set of the graph is a homogeneous Poisson point process $\mathcal{P}_s$ of intensity $s>0$ on the unit cube…

Probability · Mathematics 2021-06-23 Srikanth K. Iyer , Sanjoy Kr. Jhawar

We present results of lattice dynamics calculations of Poisson's ratio (PR) for solid hydrogen and rare gas solids (He, Ne, Ar, Kr and Xe) under pressure. Using two complementary approaches - the semi-empirical many-body calculations and…

Materials Science · Physics 2015-05-13 Yu. A. Freiman , Alexei Grechnev , S. M. Tretyak , Alexander F. Goncharov , Eugene Gregoryanz

In this work, we present an investigation regarding how and why molecular hydrogen changes the electronic properties of graphene field effect transistors. We demonstrate that interaction with H2 leads to local doping of graphene near of the…

Using the molecular dynamics method, dynamics of hydrogen bond (HB) networks emerging on the surface of a graphene sheet during its functionalization with hydroxyl groups OH are simulated. It is demonstrated that two OH groups form an…

Mesoscale and Nanoscale Physics · Physics 2020-12-30 Alexander V. Savin

The paper presents evidence of a rather strong correlation of odd electrons in the singlet state of graphene. Due to the correlation, the chemical modification of graphene can be considered following a certain algorithmic computational…

Materials Science · Physics 2012-01-10 E. F. Sheka , N. A. Popova

Negative Poisson's ratio as the anomalous characteristic generally exists in artificial architectures, such as re-entrant and honeycomb structures. The structures with negative Poisson's ratio have attracted intensive attention due to their…

Auxetic materials are characterized by a negative Poisson's ratio, $\mathrm{\nu}$. As the Poisson's ratio becomes negative and approaches the lower isotropic mechanical limit of $\mathrm{\nu = -1}$, materials show enhanced resistance to…

Soft Condensed Matter · Physics 2023-11-08 Daniel R. Reid , Nidhi Pashine , Alec S. Bowen , Sidney R. Nagel , Juan J. de Pablo

Metal contacts are fundamental building components for graphene based electronic devices and their properties are greatly influenced by interface quality during device fabrication, leading to resistance variation. Here we show that nickel…

Chemical Physics · Physics 2016-01-28 Zhenjun Zhang , Fan Yang , Pratik Agnihotri , Ji Ung Lee , Jim R. Lloyd

Consider a graph on randomly scattered points in an arbitrary space, with two points $x,y$ connected with probability $\phi(x,y)$. Suppose the number of points is large but the mean number of isolated points is $O(1)$. We give general…

Probability · Mathematics 2017-09-21 Mathew D. Penrose