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Light chargeable metal-ion batteries using semiconductor heterostructures are gaining enormous interest. A few such heterostructures such as MoS2/MoOy and TiS2/TiO2 have been shown to function as photocathodes in photochargeable Li-ion…

Materials Science · Physics 2023-07-07 Raheel Hammad , Amar Kumar , Tharangattu N. Narayanan , Soumya Ghosh

The development of advanced materials with high specific energy is crucial for enabling sustainable energy storage solutions, particularly in applications such as lithium-air batteries. Lithium peroxide (Li$_{2}$O$_{2}$) is a key discharge…

Next-generation lithium-ion batteries with silicon anodes have positive characteristics due to higher energy densities compared to state-of-the-art graphite anodes. However, the large volume expansion of silicon anodes can cause high…

Numerical Analysis · Mathematics 2024-04-03 R. Schoof , G. F. Castelli , W. Dörfler

In Li-ion batteries the electrochemical potential drives the redox reactions occurring at the interface between electrolyte and storage material, typically active particles for porous electrodes, allowing Li ions intercalation/extraction…

Applied Physics · Physics 2022-03-15 M. Magri , B. Boz , L. Cabras , A. Salvadori

Photothermal (photonic) sintering crystallizes as-deposited amorphous LiCoO2 (LCO) cathodes for solid-state thin-film batteries using millisecond, surface-localized heating. However, process design often relies on 1D models with…

Materials Science · Physics 2026-04-28 Yang Hu , Benoit Sklénard , Wouter Vels , Yaroslav E. Romanyuk , Vladyslav Turlo

We demonstrate that photoacoustic microscopy (PAM) can be a potential novel imaging tool to investigate the Li metal dendrite growth, a critical issue leading to short circuit and even explosion of Li metal batteries. Our results suggest…

Applied Physics · Physics 2019-10-02 Huihui Liu , Yibo Zhao , Jiasheng Zhou , Ping Li , Shou-Hang Bo , Sung-Liang Chen

Lithium metal batteries are seen as a critical piece towards electrifying aviation. During charging, plating of lithium metal, a critical failure mechanism, has been studied and mitigation strategies have been proposed. For electric…

Chemical Physics · Physics 2021-03-09 Victor Venturi , Venkatasubramanian Viswanathan

Understanding solid liquid interfaces at high spatial and chemical resolution is crucial for advancing electrochemical energy storage technologies, yet this remains a persistent challenge due to the lack of characterisation techniques that…

All-solid-state batteries are currently developed at high pace and show a strong potential for market introduction within the next years. Though their performance has improved considerably over the last years, investigation of their…

Lithium iron phosphate (LiFePO$_4$) is the prototypical two-phase battery material, whose complex patterns of lithium ion intercalation provide a testing ground for theories of electrochemical thermodynamics. Using a depth-averaged (a-b…

Chemical Physics · Physics 2018-08-21 Daniel A. Cogswell , Martin Z. Bazant

The projected rapid growth of battery cell production over the next decade demands advanced diagnostic tools for quality control, ageing prediction, and recycling. Most existing techniques lack the spatial and temporal resolution required…

In recent years, rapid progress has been made in solid-state lithium batteries. Among various technologies, coating the surface of electrodes or electrolytes has proven to be an effective method to enhance interfacial stability and improve…

Chemical Physics · Physics 2025-04-17 Zicun Li , Xinguo Ren , Jinbin Li , Ruijuan Xiao , Hong Li

Despite being the major cause of battery safety issues and detrimental performance, a comprehensive growth mechanism for metallic lithium deposited at electrode surfaces in lithium metal batteries remains elusive. While lithium surface…

Materials Science · Physics 2023-04-05 Christophe Didier , Elliot P. Gilbert , Jitendra Mata , Vanessa Peterson

Lithium (Li) plating on graphite is a significant degradation mechanism in Li-ion batteries. While numerous experimental techniques have been used to study Li plating in laboratory cells, investigations of commercial high-energy cells often…

An isothermal porous-electrode model of a discharging lead-acid battery is presented, which includes an extension of concentrated-solution theory that accounts for excluded-volume effects, local pressure variation, and a detailed…

Chemical Physics · Physics 2020-06-05 Valentin Sulzer , S. Jon Chapman , Colin P. Please , David A. Howey , Charles W. Monroe

Ni-rich cathode materials achieve both high voltages and capacities in Li-ion batteries but are prone to structural instabilities and oxygen loss via the formation of singlet oxygen. Using ab initio molecular dynamics simulations, we…

Lithium intercalated anatase used in Li-ion batteries has some special features: coexistence of Li-rich and Li-poor phases as well as two possible positions for Li ions in the oxygen tetrahedron. A theoretical description of the compound…

Materials Science · Physics 2009-07-06 O. V. Velychko , I. V. Stasyuk

Recently, a disruptive idea was reported about the discovery of a new type of battery named Liquid Displacement Battery (LDB) comprising liquid metal electrodes and molten salt electrolyte. This cell featured a novel concept of a porous…

Chemical Physics · Physics 2021-11-16 Kashif Mushtaq , Ji Zhao , Norbert Weber , Adelio Mendes , Donald R. Sadoway

In this work a 1D finite volume based model using coupled meshes is introduced to capture potential and species distribution throughout the discharge process in a lithium bismuth liquid metal battery while neglecting hydrodynamic effects,…

Chemical Physics · Physics 2023-05-30 Carolina Duczek , Norbert Weber , Omar E. Godinez-Brizuela , Tom Weier

The chemical behaviour of single metal atoms largely depends on the local coordination environment, including interactions with the substrate and with the surrounding gas or liquid. However, the key instrumentation for studying such systems…