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Non-adiabatic molecular phenomena, arising from the breakdown of the Born-Oppenheimer approximation, govern the fate of virtually all photo-physical and photochemical processes and limit the quantum efficiency of molecules and other…

Quantum Physics · Physics 2024-05-15 N. S. Bassler , M. Reitz , R. Holzinger , A. Vibók , G. J. Halász , B. Gurlek , C. Genes

Fast nonadiabatic control protocols known as shortcuts to adiabaticity have found a plethora of applications, but their use has been severely limited to speeding up the dynamics of isolated quantum systems. We introduce shortcuts for open…

Quantum Physics · Physics 2020-08-06 L. Dupays , I. L. Egusquiza , A. del Campo , A. Chenu

The exact dynamics of a system coupled to an environment can be described by an integro-differential stochastic equation of its reduced density. The influence of the environment is incorporated through a mean-field which is both stochastic…

Quantum Physics · Physics 2009-11-13 Denis Lacroix

We consider the dynamics of a massless scalar field with time-dependent sources in the adiabatic limit. This is an example of an adiabatic problem without spectral gap. The main goal of our paper is to illustrate the difference between the…

Mathematical Physics · Physics 2012-04-03 Johannes von Keler , Stefan Teufel

We theoretically investigate the impact of the excited state quantum phase transition on the adiabatic dynamics for the Lipkin-Meshkov-Glick model. Using a time dependent protocol, we continuously change a model parameter and then discuss…

Quantum Gases · Physics 2017-08-08 Wassilij Kopylov , Gernot Schaller , Tobias Brandes

In applied sciences, we often deal with deterministic simulation models that are too slow for simulation-intensive tasks such as calibration or real-time control. In this paper, an emulator for a generic dynamic model, given by a system of…

Methodology · Statistics 2012-07-06 Carlo Albert

We study the emergence of non-Gaussian quantum features in pulsed squeezed light generation with a mesoscopic number (i.e., dozens to hundreds) of pump photons. Due to the strong optical nonlinearities necessarily involved in this regime,…

Current dynamical control based on the bang-bang control mechanism involving various types of pulse sequences is essentially a perturbative theory. This paper presents a non-perturbative dynamical control approach based on the exact…

Quantum Physics · Physics 2013-09-03 Jun Jing , Lian-Ao Wu , J. Q. You , Ting Yu

The powerful molecular dynamics (MD) simulation is basically based on a picture that the atoms experience classical-like trajectories under the exertion of classical force field determined by the quantum mechanically solved electronic…

Chemical Physics · Physics 2013-12-16 Wei Feng , Luting Xu , Xin-Qi Li , Weihai Fang

A single-loop scenario is proposed to realize nonadiabatic geometric quantum computation. Conventionally, a so-called multi-loop approach is used to remove the dynamical phase accumulated in the operation process for geometric quantum…

Quantum Physics · Physics 2009-11-11 Xin-Ding Zhang , Shi-Liang Zhu , L. Hu , Z. D. Wang

We formulate a hyperspherical approach within standard configuration interaction calculations aiming at a description of large-scale dynamics of $N$-particle system. The channel wave function and the adiabatic channel energy are determined…

Nuclear Theory · Physics 2018-12-05 Y. Suzuki , K. Varga

We present a new formulation of the correlated electron-ion dynamics (CEID) scheme, which systematically improves Ehrenfest dynamics by including quantum fluctuations around the mean-field atomic trajectories. We show that the method can…

Materials Science · Physics 2007-12-13 L. Stella , M. Meister , A. J. Fisher , A. P. Horsfield

Nonlinear stochastic motion presents significant challenges for Bayesian particle tracking. To address this challenge, this paper proposes a framework to construct an invertible transformation that maps the nonlinear state-space model (SSM)…

Methodology · Statistics 2026-04-13 Yonatan L. Ashenafi

We have implemented quantum modeling mainly based on Bohmian Mechanics to study time series that contain strong coupling between their events. We firstly propose how compared to normal densities, our target time series seem to be associated…

Mathematical Finance · Quantitative Finance 2023-07-26 Reza Hosseini , Samin Tajik , Zahra Koohi Lai , Tayeb Jamali , Emmanuel Haven , G. Reza Jafari

Ab initio modeling of conical intersection dynamics is crucial for various photochemical, photophysical, and biological processes. However, adiabatic electronic states obtained from electronic structure computations involve random phases,…

Chemical Physics · Physics 2024-06-13 Xiaotong Zhu , Bing Gu

We present a novel route to constructing cost-efficient semi-empirical approximations for the non-additive kinetic energy in subsystem density functional theory. The developed methodology is based on the use of Slater determinants composed…

Chemical Physics · Physics 2025-01-13 Larissa Sophie Eitelhuber , Denis G. Artiukhin

Describing dynamic medical systems using machine learning is a challenging topic with a wide range of applications. In this work, the possibility of modeling the blood glucose level of diabetic patients purely on the basis of measured data…

Machine Learning · Computer Science 2023-03-10 David Jödicke , Daniel Parra , Gabriel Kronberger , Stephan Winkler

We introduce open-loop quantum control protocols for characterizing the spectral properties of non-Gaussian noise, applicable to both classical and quantum dephasing environments. The basic idea is to engineer a multi-dimensional frequency…

Quantum Physics · Physics 2016-04-20 Leigh M. Norris , Gerardo A. Paz-Silva , Lorenza Viola

We present a new approach to carry out non-adiabatic molecular dynamics to study the carrier mobility in an organic monolayer. This approach allows the calculation of a 4802 atom system for 825 fs in about three hours using 51,744 computer…

Materials Science · Physics 2012-03-13 Junfeng Ren , Nenad Vukmirovic , Lin-Wang Wang

We derive the theory of open quantum system dynamics intervened by a series of nonselective measurements. We analyze the cases of time independent and time dependent Hamiltonian dynamics in between the measurements and find the approximate…

Quantum Physics · Physics 2018-01-17 Sergey N. Filippov