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A variational approach, based on a discrete representation of the chain, is used to calculate free energy and conformational properties in polyelectrolytes. The true bond and Coulomb potentials are approximated by a trial isotropic harmonic…

chem-ph · Physics 2016-08-15 B. Jönsson , C. Peterson , B. Söderberg

Researchers in physical science aim to uncover universal features in strongly interacting many-body systems, often hidden in complicated observables like entanglement entropy (EE). The non-local nature of EE makes it challenging to compute…

Strongly Correlated Electrons · Physics 2025-04-22 Yuan Da Liao

We recently developed a scheme to use low-cost calculations to find a single twist angle where the couple cluster doubles energy of a single calculation matches the twist-averaged coupled cluster doubles energy in a finite unit cell. We…

Chemical Physics · Physics 2021-02-03 Tina N. Mihm , William Z. Van Benschoten , James J. Shepherd

Monte-Carlo simulations are routinely used for estimating the scaling exponents of complex systems. However, due to finite-size effects, determining the exponent values is often difficult and not reliable. Here we present a novel technique…

Computational Physics · Physics 2008-04-14 Jaan Kalda

We propose a staggered mesh method for correlation energy calculations of periodic systems under the random phase approximation (RPA), which generalizes the recently developed staggered mesh method for periodic second order…

Computational Physics · Physics 2023-04-10 Xin Xing , Lin Lin

Based on the recently developed resummation-based quantum Monte Carlo method for the SU($N$) spin and loop-gas models, we develop a new algorithm, dubbed ResumEE, to compute the entanglement entropy (EE) with greatly enhanced efficiency.…

Strongly Correlated Electrons · Physics 2024-09-20 Menghan Song , Ting-Tung Wang , Zi Yang Meng

Despite the unitary evolution of closed quantum systems, long-time expectation of local observables are well described by thermal ensembles, providing the foundation of quantum statistical mechanics. A promising route to understanding this…

Quantum Physics · Physics 2026-02-03 Yuke Zhang , Pengfei Zhang

Convergence of path integral simulations requires a substantial number of beads when quantum effects are significant. Traditional Trotter scaling approaches estimate the continuum limit through extrapolation, however they are restricted to…

Statistical Mechanics · Physics 2024-05-28 Sabry G Moustafa

Small system sizes are a well known source of error in DFT calculations, yet computational constraints frequently dictate the use of small supercells, often as small as 96 atoms in oxides and compound semiconductors. In ionic compounds,…

Materials Science · Physics 2017-09-19 P. A. Burr , M. W. D. Cooper

Precise control of quantum systems is of fundamental importance for quantum device engineering, such as is needed in the fields of quantum information processing, high-resolution spectroscopy and quantum metrology. When scaling up the…

We review the use of continuum quantum Monte Carlo (QMC) methods for the calculation of energy gaps from first principles, and present a broad set of excited-state calculations carried out with the variational and fixed-node diffusion QMC…

Materials Science · Physics 2018-08-22 Ryan J. Hunt , Marcin Szyniszewski , Genki I. Prayogo , Ryo Maezono , Neil D. Drummond

We introduce an exact Monte Carlo approach to the statistics of discrete quantum systems which does not rely on the standard fragmentation of the imaginary time, or any small parameter. The method deals with discrete objects, kinks,…

Condensed Matter · Physics 2009-10-28 N. V. Prokof'ev , B. V. Svistunov , I. S. Tupitsyn

A variational approach is used to calculate free energy and conformational properties in polyelectrolytes. The true bond and Coulomb potentials are approximated by a trial isotropic harmonic energy containing monomer-monomer force constants…

High Energy Physics - Lattice · Physics 2009-09-25 B. Jönsson , C. Peterson , B. Söderberg

An error control technique aimed to assess the quality of smoothed finite element approximations is presented in this paper. Finite element techniques based on strain smoothing appeared in 2007 were shown to provide significant advantages…

The efficient evaluation of high-dimensional integrals is of importance in both theoretical and practical fields of science, such as data science, statistical physics, and machine learning. However, exact computation methods suffer from the…

Statistics Theory · Mathematics 2017-12-15 Radislav Vaisman , Robert Salomone , Dirk P. Kroese

Extended solids are frequently simulated as finite systems with periodic boundary conditions, which due to the long-range nature of the Coulomb interaction may lead to slowly decaying finite- size errors. In the case of Quantum-Monte-Carlo…

Other Condensed Matter · Physics 2015-06-04 R. Gaudoin , I. G. Gurtubay , J. M. Pitarke

A numerically implementable Multi-scale Many-Body approach to strongly correlated electron systems is introduced. An extension to quantum cluster methods, it approximates correlations on any given length-scale commensurate with the strength…

Strongly Correlated Electrons · Physics 2012-01-04 C. Slezak , M. Jarrell , Th. Maier , J. Deisz

We present a recently developed projector quantum Monte Carlo method for calculations of electronic structure in systems with spin-orbit interactions. The method solves for many-body eigenstates in the presence of spin-orbit using the…

Chemical Physics · Physics 2017-08-09 Cody A. Melton , M. Chandler Bennett , Lubos Mitas

In the context of global/goal-oriented error estimation applied to computational mechanics, the need to obtain reliable and guaranteed bounds on the discretization error has motivated the use of residual error estimators. These estimators…

Numerical Analysis · Mathematics 2017-04-25 Florent Pled , Ludovic Chamoin , Pierre Ladevèze

We suggest an efficient method to resolve electronic cusps in electronic structure calculations by using an effective transcorrelated Hamiltonian. This effective Hamiltonian takes a simple form for plane wave bases, containing up to…

Computational Physics · Physics 2018-02-14 Hongjun Luo , Ali Alavi