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We investigate the thermodynamics and percolation regimes of model binary mixtures of patchy colloidal particles. The particles of each species have three sites of two types, one of which promotes bonding of particles of the same species…

Soft Condensed Matter · Physics 2015-03-19 Daniel de las Heras , José Maria Tavares , Margarida M. Telo da Gama

Equilibrium gels of colloidal particles can be realized through the introduction of a second species, a linker that mediates the bonds between the colloids. A gel forming binary mixture whose linkers can self-assemble into linear chains…

Soft Condensed Matter · Physics 2022-11-09 M. Gouveia , C. S. Dias , J. M. Tavares

In this work we extend Wertheim's thermodynamic perturbation theory (TPT) to binary mixtures (species A and species B) of patchy colloids where each species has a single patch which can bond a maximum of twice (divalent). Colloids are…

Soft Condensed Matter · Physics 2014-08-16 B. D. Marshall , W. G. Chapman

We investigate the phase behaviour of 2D mixtures of bi-functional and three-functional patchy particles and 3D mixtures of bi-functional and tetra-functional patchy particles by means of Monte Carlo simulations and Wertheim theory. We…

We study the phase diagram of a binary mixture of patchy particles which has been designed to form a reversible gel. For this we perform Monte Carlo and molecular dynamics simulations to investigate the thermodynamics of such a system and…

Soft Condensed Matter · Physics 2014-12-17 Sándalo Roldán-Vargas , Frank Smallenburg , Walter Kob , Francesco Sciortino

Determining the onset of rigidity in gels is a fundamental challenge with significant practical implications across different applications. Limited-valence, or patchy-particle systems have proven to be a valuable model to study the…

Soft Condensed Matter · Physics 2025-04-04 J. C. Neves , J. M. Tavares , N. A. M. Araújo , C. S. Dias

We study a two-dimensional binary mixture of patchy colloids in sedimentation-diffusion-equilibrium using Monte Carlo simulation and Wertheim's theory. By tuning the buoyant masses of the colloids we can control the gravity-induced sequence…

Soft Condensed Matter · Physics 2016-03-03 Daniel de las Heras , Lucas L. Treffenstädt , Matthias Schmidt

We present a new model of patchy particles in which the interaction sites can be activated or deactivated by varying the temperature of the system. We study the thermodynamics of the system by means of Wertheim's first order perturbation…

Soft Condensed Matter · Physics 2016-05-25 Daniel de las Heras , Margarida M. Telo da Gama

The melting of a binary system of charged particles confined in a {\it quasi}-one-dimensional parabolic channel is studied through Monte Carlo simulations. At zero temperature the particles are ordered in parallel chains. The melting is…

Soft Condensed Matter · Physics 2015-05-19 W. P. Ferreira , G. A. Farias , F. M. Peeters

Colloidal patchy particles with divalent attractive interaction can self-assemble into linear polymer chains. Their equilibrium properties in 2D and 3D are well described by Wertheim's thermodynamic perturbation theory which predicts a…

Soft Condensed Matter · Physics 2022-09-21 H. J. Jonas , P. Schall , P. G. Bolhuis

We introduce a simple model, a binary mixture of patchy particles, which has been designed to form a gel upon heating. Due to the specific nature of the particle interactions, notably the number and geometry of the patches as well as their…

Soft Condensed Matter · Physics 2013-10-16 Sandalo Roldan-Vargas , Frank Smallenburg , Walter Kob , Francesco Sciortino

Binary mixture of oppositely charged of colloids can be used to stabilize water-in-oil or oil-in-water emulsions. A Monte Carlo simulation study to address the effect of charge ratio of colloids on the stability of Pickering emulsions is…

Soft Condensed Matter · Physics 2015-12-09 Sam David Christdoss Pushpam , Madivala G. Basavaraj , Ethayaraja Mani

We critically discuss the application of the Wertheim's theory to classes of complex associating fluids that can be today engineered in the laboratory as patchy colloids and to the prediction of their peculiar gas-liquid phase diagrams. Our…

Soft Condensed Matter · Physics 2016-01-06 Riccardo Fantoni , Giorgio Pastore

We combine particle-based simulations, mean-field rate equations, and Wertheim's theory to study the dynamics of patchy particles in and out of equilibrium, at different temperatures and densities. We consider an initial random distribution…

Soft Condensed Matter · Physics 2017-11-01 J. M. Tavares , C. S. Dias , N. A. M. Araújo , M. M. Telo da Gama

Patchy colloids with highly directional interactions are ideal building blocks to control the local arrangements resulting from their spontaneous self-organization. Here we propose their use, combined with substrates and nonequilibrium…

Soft Condensed Matter · Physics 2013-03-21 C. S. Dias , N. A. M. Araújo , M. M. Telo da Gama

Patchy particles are a class of colloids with functionalized surfaces. Through surface functionalization, the strength and directionality of the colloidal interactions are tunable allowing control over coordination of the particle.…

Soft Condensed Matter · Physics 2013-10-21 Cristóvão Dias , Nuno Araújo , Margarida Telo da Gama

We calculate the network fluid regime and phase diagrams of binary mixtures of patchy colloids, using Wertheim's first order perturbation theory and a generalization of Flory-Stockmayer's theory of polymerization. The colloids are modelled…

Soft Condensed Matter · Physics 2011-06-13 Daniel de las Heras , José M. Tavares , Margarida M. Telo da Gama

In this work we develop the first theory to model self assembling mixtures of single patch colloids and colloids with spherically symmetric attractions. In the development of the theory we restrict the interactions such that there are short…

Soft Condensed Matter · Physics 2013-09-18 B. D. Marshall , W. G. Chapman

Systems of four nonbinary particles, each having three or more internal states, exhibit maximally entangled states that are inaccessible to four qubits. This breaks the pattern of two- and three-particle systems, in which the existing graph…

Quantum Physics · Physics 2015-06-23 Mario Gaeta , Andrei Klimov , Jay Lawrence

In this study, we investigate the phenomenon of collective motion in binary mixtures of self-propelled particles. We consider two particle species, each of which consisting of pointlike objects that propel with a velocity of constant…

Soft Condensed Matter · Physics 2013-11-20 Andreas M. Menzel
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