Related papers: Suppressing photochemical reactions with quantized…
We present a self-consistent theory, as well as an illustrative application to a realistic system, of phase control of photoabsorption in an optically dense medium. We demonstrate that, when propagation effects are taken into consideration,…
The interpretation of nanoplasmonic effects on molecular properties, such as metal-enhanced absorption or fluorescence, typically assumes a fully coherent picture (in the quantum-mechanical sense) of the phenomena. Yet, there may be…
Owing to the possibility of controlling its specific mechanical behaviors up taken by irradiated by light at particular wavelengths, the photoisomerization hydrogels have a broad range of potential applications. A theory connecting the…
We have studied the photo-induced isomerization from 1,3-cyclohexadiene to 1,3,5-hexatriene in the presence of an intense ultrafast laser pulse. We find that the laser field maximally suppresses isomerization if it is both polarized…
Photochemical heating is analyzed with emphasis on the heating generated by chemical reactions initiated by the products of photodissociation and photoionization. The immediate products are slowed down by collisions with the ambient gas and…
Inter-Symbol Interference (ISI) is the main challenge of bio-inspired diffusion-based molecular communication. In real biological systems, the degradation of the remaining molecules from a previous transmission is used to mitigate ISI.…
Analogous to Coulomb blockade for electrons, photon blockade is a key quantum optical effect in which the presence of one photon prevents the transmission of subsequent ones through a nonlinear medium. Beyond its fundamental interest,…
Massless particles, including photons, are not governed by particle conservation law during their typical interaction with matter even at low energies, and thus have no chemical potential. However, in driven systems, near equilibrium…
The structural dynamics of macromolecules is important for most microbiological processes, from protein folding to the origins of neurodegenerative disorders. Noninvasive measurements of these dynamics are highly challenging. Recently,…
Reabsorption, the multiple scattering of spontaneously emitted photons in optically thick gases, is a major limitation to efficient optical pumping and laser cooling in ultracold gases. We report mitigation of reabsorption using spatial and…
Photoinduced biological processes occur via one photon absorption in natural light, which is weak, CW and incoherent, but are often studied in the laboratory using pulsed coherent light. Here we compare the response of a molecule to these…
Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…
Photopolymerization processes are exploited in light exposure-based 3D printing technologies, where either a focused laser beam or a patterned light sheet allows layers of a UV curable, liquid pre-polymer to be solidified. Here we focus on…
Organic photoswitchable molecules have struggled in solid state form to fulfill their remarkable potential, in terms of photoswitching performance and long-term stability when compared to their inorganic counterparts. We report the concept…
Isomerization in molecular systems almost invariably occurs through 3-dimensional motion due to the nature of chemical bonding. Pseudorotation is an unusual type of isomerization that occurs in some high symmetry systems that gives the…
We report a method to control the conformation of a weak polyampholyte (the protein $\beta$-casein) in Langmuir monolayers by light, even though the protein is not photosensitive. Our approach is to couple the monolayer state to a…
We propose to control the retinal photoisomerization yield through the back-action dynamics imparted by a nonselective optical measurement of the molecular electronic state. This incoherent effect is easier to implement than comparable…
Photon-photon interactions mediated by the neutral hydrogen background can transform plane polarization into circular polarization, through completely forward processes, [gamma+gamma+atom-> gamma+ gamma+atom], in which only the photon…
Manipulating the flow of energy in nanoscale and molecular photonic devices is of both fundamental interest and central importance for applications in light harvesting optoelectronics. Under erratic solar irradiance conditions, unregulated…
Light-matter interactions that lead to nonthermal changes in size of the sample constitute a photostrictive effect in many compounds. The photostriction phenomenon was observed in four main groups of materials, ferroelectrics, polar, and…