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The thermal conductivity of several diamond-like materials is calculated from a kinetic-collective model. From this approach, a thermal conductivity expression is obtained that includes a transition from a kinetic (free) to a collective…

Mesoscale and Nanoscale Physics · Physics 2015-06-05 C. de Tomas , A. Cantarero , A. F. Lopeandia , F. X. Alvarez

We present a model which deepens into the role that normal scattering has on the thermal conductivity in semiconductor bulk, micro and nanoscale samples. Thermal conductivity as a function of the temperature undergoes a smooth transition…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 C. de Tomas , A. Cantarero , A. F. Lopeandia , F. X. Alvarez

Several hitherto unexplained features of thermal conductivity in group IV materials, such as the change in the slope as a function of sample size for pure vs. alloyed samples and the fast decay in thermal conductivity for low impurity…

Materials Science · Physics 2015-09-04 P. Torres , C. de Tomas , A. Lopeandia , X. Cartoixà , X. Alvarez

In recent years, nanostructuring of dielectric and semiconducting crystals has enhanced controllability of their thermal conductivity. To carry out computational material search for nanostructured materials with desirable thermal…

Mesoscale and Nanoscale Physics · Physics 2016-02-23 Takuma Shiga , Daisuke Aketo , Lei Feng , Junichiro Shiomi

Predicting the thermal conductivity of glasses from first principles has hitherto been a prohibitively complex problem. In fact, past works have highlighted challenges in achieving computational convergence with respect to length and/or…

Materials Science · Physics 2022-09-23 Michele Simoncelli , Francesco Mauri , Nicola Marzari

First-principles molecular dynamics simulation based on a plane wave/pseudopotential implementation of density functional theory is adopted to investigate atomic scale energy transport for semiconductors (silicon and germanium). By imposing…

Computational Physics · Physics 2016-02-02 Pengfei Ji , Yuwen Zhang

We propose empirical formulae of the electrical conductivity sigma and thermal conductivity for elemental metals such as Na, Cu or Fe at room temperature ranges. Assuming the relaxation time is given by the Planck constant divided by pai…

Materials Science · Physics 2011-09-01 T. Hirayama

In this work, we demonstrate the correspondence between first principle calculations and experimental measurements of size effects on thermal transport in SiGe alloys. Transient thermal grating (TTG) is used to measure the effective thermal…

The ab-initio theory of low-field electronic transport properties such as carrier mobility in semiconductors is well-established. However, an equivalent treatment of electronic fluctuations about a non-equilibrium steady state, which are…

Materials Science · Physics 2021-04-14 Alexander Y. Choi , Peishi Cheng , Benjamin Hatanpaa , Austin J. Minnich

In this paper, thermal conductivity of crystalline GaAs is calculated using first-principles lattice dynamics. The harmonic and cubic force constants are obtained by fitting them to the force-displacement data from density functional theory…

Materials Science · Physics 2013-01-11 Tengfei Luo , Jivtesh Garg , Junichiro Shiomi , Keivan Esfarjani , Gang Chen

Designing and searching for a high thermal conductivity material in both bulk and nanoscale is highly demanding for electronics cooling. In this work, we studied the thermal conductivity of 2H-Germanium Carbide(2H-GeC) using first…

Materials Science · Physics 2021-07-13 Rajmohan Muthaiah , Jivtesh Garg

In this study, an efficient first-principles approach for calculating the thermodynamic properties of mixed metal oxides at high temperatures is demonstrated. More precisely, this procedure combines density functional theory and harmonic…

Materials Science · Physics 2023-05-12 Joakim Brorsson , Ivana Staničić , Jonatan Gastaldi , Tobias Mattison , Anders Hellman

We study charge and heat transport from first-principles in the topological Weyl semimetal TaAs. Electron-phonon coupling matrix elements are calculated using density functional perturbation theory and used to derive the thermo-electric…

Materials Science · Physics 2025-05-22 Guillaume E. Allemand , Matteo Giantomassi , Matthieu J. Verstraete

We discuss the thermal conductivity of a chain of coupled rotators, showing that it is the first example of a 1d nonlinear lattice exhibiting normal transport properties in the absence of an on-site potential. Numerical estimates obtained…

chao-dyn · Physics 2009-10-31 C. Giardina' , R. Livi , A. Politi , M. Vassalli

Separating electron and phonon thermal conductivity components is imperative for understanding the principle thermal transport mechanisms in metals and highly desirable in many applications. In this work, we predict the mode-dependent…

Materials Science · Physics 2019-10-23 Zhen Tong , Shouhang Li , Xiulin Ruan , Hua Bao

We propose a novel approach to model amorphous materials using a first principles density functional method while simultaneously enforcing agreement with selected experimental data. We illustrate our method with applications to amorphous…

Materials Science · Physics 2009-11-10 Parthapratim Biswas , De Nyago Tafen , Raymond Atta-Fynn , D. A. Drabold

Magnesium Selenide (MgSe) is a wide bandgap semiconductor with applications in optoelectronics and energy conversion technologies. Understanding thermal conductivity (k) of MgSe is critical for optimum design of thermal transport in these…

Materials Science · Physics 2021-02-01 Rajmohan Muthaiah , Jivtesh Garg

Oxides have many potentially desirable characteristics for thermoelectric applications, including low cost and stability at high temperatures, but thus far there are few known high $zT$ $n$-type oxide thermoelectrics. In this work, we use…

Materials Science · Physics 2016-07-18 Kevin F. Garrity

Using harmonic and anharmonic force constants extracted from density-functional calculations within a supercell, we have developed a relatively simple but general method to compute thermodynamic and thermal properties of any crystal. First,…

Materials Science · Physics 2015-05-28 Keivan Esfarjani , Gang Chen , Harold T. Stokes

It is generally assumed in the thermoelectric community that the lattice thermal conductivity of a given material is independent of the electronic properties. This perspective is however questionable since the electron-phonon coupling could…

Materials Science · Physics 2018-01-03 D. D. Fan , H. J. Liu , L. Cheng , J. H. Liang , P. H. Jiang
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