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We unveil the nature of the structural disorder in bottom-up zigzag graphene nanoribbons along with its effect on the magnetism and electronic transport on the basis of scanning probe microscopies and first-principles calculations. We find…

Bilayer graphene nanoribbon with zigzag edge is investigated with the tight binding model. Two stacking structures, alpha and beta, are considered. The band splitting is seen in the alpha structure, while the splitting in the wave number…

Mesoscale and Nanoscale Physics · Physics 2012-03-13 Kikuo Harigaya , Hiroshi Imamura

We explore the edge properties of rectangular graphene nanoribbons featuring two zigzag edges and two armchair edges. Although the self-consistent Hartree-Fock fields break chiral symmetry, our work demonstrates that graphene nanoribbons…

Mesoscale and Nanoscale Physics · Physics 2024-03-25 Hyun Cheol Lee , S. -R. Eric Yang

In contrast to the well recognized transverse-electric-field-induced half-metallicity in zigzag graphene nanoribbons, here we demonstrate by first-principles calculations that zigzag graphene nanoribbons sandwiched between hexagonal boron…

Mesoscale and Nanoscale Physics · Physics 2013-04-15 Jin Yu , Wanlin Guo

Zigzag graphene nanoribbons can have magnetic ground states with ferromagnetic, antiferromagnetic, or canted configurations, depending on carrier density. We show that an electric field directed across the ribbon alters the magnetic state,…

Mesoscale and Nanoscale Physics · Physics 2010-12-21 J. Jung , A. H. Macdonald

Two magnetic impurities on the edge of a zigzag graphene nanoribbon strongly interact with each other via indirect coupling, which can be mediated by conducting carriers. By means of Quantum Monte Carlo (QMC) simulations, we find that the…

Strongly Correlated Electrons · Physics 2015-03-09 F. M. Hu , Liangzhi Kou , Thomas Frauenheim

Spin-hosting graphene nanostructures are promising metal-free systems for elementary quantum spintronic devices. Conventionally, spins are protected from quenching by electronic bandgaps, which also hinder electronic access to their quantum…

Half-metals have been envisioned as active components in spintronic devices by virtue of their completely spin-polarized electrical currents. Actual materials hosting half-metallic phases, however, remain scarce. Here, we predict that…

We study the edge magnetization of bilayer graphene ribbons with zigzag edges. The presence of flat edge-state bands at the Fermi energy of undoped bilayer, which gives rise to a strong peak in the density of states, makes bilayer ribbons…

Mesoscale and Nanoscale Physics · Physics 2008-07-22 Eduardo V. Castro , N. M. R. Peres , J. M. B. Lopes dos Santos

We investigate the ground-state properties of triangular graphene nanoflakes with zigzag edge configurations. The description of zero-dimensional nanostructures requires accurate many-body techniques since the widely used density-functional…

Strongly Correlated Electrons · Physics 2018-01-24 I. Hagymasi , O. Legeza

Using a model Hamiltonian approach including electron-electron interactions, we systematically investigate the electronic structure and magnetic properties of chiral graphene nanoribbons. We show that the presence of magnetic edge states is…

Mesoscale and Nanoscale Physics · Physics 2011-09-13 Oleg V. Yazyev , Rodrigo B. Capaz , Steven G. Louie

We theoretically study the electronic properties of BC2N nanoribbons with zigzag edges using a tight binding model. We show that the zigzag BC2N nanoribbons have the flat bands and edge states when atoms are arranged as B-C-N-C along the…

Materials Science · Physics 2013-03-18 Tomoaki Kaneko , Kikuo Harigaya

Defects change essentially not only electronic but also chemical properties of graphene being centers of its chemical activity. Their functionalization is a way to modify electronic and crystal structure of graphene which may be important…

Materials Science · Physics 2009-01-05 D. W. Boukhvalov , M. I. Katsnelson

The in-plane lattice constants of close-packed planes of fcc and hcp Ni and Co match that of graphite almost perfectly so that they share a common two dimensional reciprocal space. Their electronic structures are such that they overlap in…

Graphene is a nonmagnetic semimetal and cannot be directly used as electronic or spintronic devices. We demonstrate that graphene quantum dots (GQDs) can exhibit strong edge magnetism and tunable energy gaps due to the presence of localized…

Materials Science · Physics 2017-11-01 Wei Hu , Yi Huang , Lin Lin , Erjun Kan , Xingxing Li , Chao Yang , Jinlong Yang

Zigzag edges of graphene have long been predicted to exhibit magnetic electronic state near the Fermi level, which can cause spin-related phenomena and offer unique potentials for graphene-based spintronics. However, the magnetic conduction…

We show that patterned defects can be used to disrupt the sub-lattice symmetry of graphene so as to open up a band gap. This way of modifying graphene's electronic structure does not rely on external agencies, the addition of new elements…

Mesoscale and Nanoscale Physics · Physics 2010-09-09 David J. Appelhans , Zhibin Lin , Mark T. Lusk

We investigate the interactions between two identical magnetic impurities substituted into a graphene superlattice. Using a first-principles approach, we calculate the electronic and magnetic properties for transition-metal substituted…

We investigate spin transport in diffusive graphene nanoribbons with both clean and rough zigzag edges, and long-range potential fluctuations. The long-range fields along the ribbon edges cause the local doping to come close to the charge…

Mesoscale and Nanoscale Physics · Physics 2014-03-31 Jan Bundesmann , Ming-Hao Liu , Inanc Adagideli , Klaus Richter

In this article, we report band structure studies of zigzag graphene nanoribbons (ZGNRs) on introducing defects (sp_3 hybridized carbon atoms) in different concentrations at edges by varying the ratio of sp_3 to sp_2 hybridized carbon…

Mesoscale and Nanoscale Physics · Physics 2018-03-19 Payal Wadhwa , Shailesh Kumar , T. J. Dhilip Kumar , Alok Shukla , Rakesh Kumar