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We introduce a new optical tool - a "two-dimensional optical centrifuge", capable of aligning molecules in extreme rotational states. Unlike the conventional centrifuge, which confines the molecules in the plane of their rotation, its…

Chemical Physics · Physics 2016-05-18 A. A. Milner , A. Korobenko , V. Milner

Quantum interference between multiple pathways in molecular photodissociation often results in angular momentum polarization of atomic products and this can give deep insight into fundamental physical processes. For dissociation of diatomic…

Chemical Physics · Physics 2022-04-26 Chaya Weeraratna , Arthur G. Suits , Oleg S. Vasyutinskii

Molecules with deep vibrational potential wells provide optical intervals sensitive to variation in the proton-electron mass ratio ($\mu$). On one hand, polar molecules are of interest since optical state preparation techniques have been…

Atomic Physics · Physics 2018-12-05 Mark G. Kokish , Patrick R. Stollenwerk , Masatoshi Kajita , Brian C. Odom

We investigate a cavity quantum electrodynamic effect, where the alignment of two-dimensional freely rotating optical dipoles is driven by their collective coupling to the cavity field. By exploiting the formal equivalence of a set of…

Quantum Physics · Physics 2017-08-02 Erika Cortese , Pavlos Lagoudakis , Simone De Liberato

Selection of "magic" trapping conditions with ultracold atoms or molecules, where pairs of internal states experience identical trapping potentials, brings substantial benefits to precision measurements and quantum computing schemes.…

Quantum Physics · Physics 2011-01-04 Svetlana Kotochigova , David DeMille

A theoretical study of the rotational dynamics of a linear polar molecule in a two-color non-resonant cw laser field is presented. By systematically considering the interactions of this field with the electric dipole moment, polarizability…

Quantum Physics · Physics 2020-08-26 David Mellado-Alcedo , Niurka R. Quintero , Rosario González-Férez

Optical forces allow manipulation of small particles and control of nanophotonic structures with light beams. Here, we describe a counter-intuitive lateral optical force acting on particles placed above a substrate, under uniform plane wave…

A theoretical framework is presented for the computation of rovibrational polaritonic states of a molecule in a lossless infrared (IR) microcavity. In the proposed approach the quantum treatment of the rotational and vibrational motion of…

Chemical Physics · Physics 2023-10-30 Tamás Szidarovszky

A strong inhomogeneous static electric field is used to spatially disperse a rotationally cold supersonic beam of 2,6-difluoroiodobenzene molecules according to their rotational quantum state. The molecules in the lowest lying rotational…

We show that the vibrational state tailoring method developed for molecular systems can be applied for cold atoms in optical lattices. The original method is based on a three-level model interacting with two strong laser pulses in a…

Atomic Physics · Physics 2007-05-23 Kari Harkonen , Ollijuhani Karki , Kalle-Antti Suominen

Strong light-matter interactions facilitate not only emerging applications in quantum and non-linear optics but also modifications of materials properties. In particular the latter possibility has spurred the development of advanced…

Mesoscale and Nanoscale Physics · Physics 2021-08-17 Jakub Fojt , Tuomas P. Rossi , Tomasz J. Antosiewicz , Mikael Kuisma , Paul Erhart

We study ionization dynamics of aligned diatomic molecules N$_2$ in strong elliptical laser fields experimentally and theoretically. The alignment dependence of photoelectron momentum distributions (PMDs) of N$_2$ measured in experiments is…

We present a detailed theoretical and experimental study of the rotation of the plane of polarization of light traveling through a gas of fast-spinning molecules. This effect is similar to the polarization drag phenomenon predicted by Fermi…

The rapid development of experimental techniques to produce ultracold alkali molecules opens the ways to manipulate them and to control their dynamics using external electric fields. A prerequisite quantity for such studies is the knowledge…

Extensive studies in the past have focused on precise calculations of the nonlinear-optical susceptibility of thousands of molecules. In this work, we use the broader approach of considering how geometry and symmetry alone play a role. We…

Optics · Physics 2009-11-11 Mark G. Kuzyk , David S. Watkins

The creation and detection of atomic polarization is examined theoretically, through the study of basic optical-pumping mechanisms and absorption and fluorescence measurements, and the dependence of these processes on the size of ground-…

Atomic Physics · Physics 2013-05-29 M. Auzinsh , D. Budker , S. M. Rochester

We investigate the dynamics of a fluid of dipolar hard spheres in its liquid and glassy phase, with emphasis on the microscopic time or frequency regime. This system shows rather different glass transition scenarios related to its rich…

Disordered Systems and Neural Networks · Physics 2009-11-07 T. Theenhaus , R. Schilling , A. Latz , M. Letz

Recently, several laser schemes have been proposed to separate racemic mixtures of enantiomers by splitting a molecular beam into subbeams consisting of molecules of definite chirality [Y. Li, C. Bruder, and C. P. Sun, Phys. Rev. Lett. 99,…

Quantum Physics · Physics 2012-08-09 Andreas Jacob , Klaus Hornberger

A path integral ground state approach has been used to estimate the ground-state energy and structural properties of hydrogen fluoride molecules pinned to a one-dimensional lattice. In the simulations, the molecules are assumed to be rigid,…

Chemical Physics · Physics 2023-08-10 Tapas Sahoo , Gautam Gangopadhyay

We present a theoretical study of recent laser-alignment and mixed-field-orientation experiments of asymmetric top molecules. In these experiments, pendular states were created using linearly polarized strong ac electric fields from pulsed…