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A modified detailed balance model is built to understand and quantify efficiency loss of perovskite solar cells. The modified model captures the light-absorption dependent short-circuit current, contact and transport-layer modified carrier…

The outstanding photovoltaic performances of lead halide perovskite (LHP) thin film solar cells are due in particular to the large diffusion length of photocarriers. The mechanism behind this property and its dependence on the various…

The photocurrent density-voltage (J(V)) curve is the fundamental characteristic to assess opto-electronic devices, in particular solar cells. However, it only yields information on the performance integrated over the entire active device…

Halide perovskites make efficient solar cells due to their exceptional optoelectronic properties, but suffer from several stability issues. The characterization of the degradation processes is challenging because of the limitations in the…

Materials Science · Physics 2022-05-25 Mike Pols , José Manuel Vicent-Luna , Ivo Filot , Adri C. T. van Duin , Shuxia Tao

Metal halide perovskite solar cells have gained widespread attention due to their high efficiency and high defect tolerance. The absorbing perovskite layer is as a mixed electron-ion conductor that supports high rates of ion and charge…

The physics of organic bulk heterojunction solar cells is studied within a six state model, which is used to analyze the factors that affect current-voltage characteristics, power-voltage properties and efficiency, and their dependence on…

Materials Science · Physics 2015-06-18 Mario Einax , Marcel Dierl , Philip R. Schiff , Abraham Nitzan

Fundamental working mechanisms of perovskite solar cells remain an elusive topic of research. Impedance Spectroscopy (IS) application to perovskite-based devices generates uncommon features and misleading outputs, mainly due to the lack of…

Applied Physics · Physics 2019-08-19 So-Min Yoo , Seog Joon Yoon , Juan A. Anta , Hyo Joong Lee , Pablo P. Boix , Iván Mora-Seró

Lead-halide perovskites attracted attention as materials for high-efficiency solar cells and light emitting applications. Among their attributes are solution processability, high absorbance in the visible spectral range and defect…

Materials Science · Physics 2018-11-14 Hee Taek Yi , Pavel Irkhin , Prakriti P. Joshi , Yuri N. Gartstein , Xiaoyang Zhu , Vitaly Podzorov

Perovskite solar cells have reached power conversion efficiencies that rival those of established silicon photovoltaics. Nanotextures in perovskite solar cells scatter the incident light, thereby improving optical absorption. In addition,…

In order to understand the physical hysteresis loops clearly, we constructed a novel model, which is combined with the electric field, the temperature, and the stress as one synthetically parameter. This model revealed the shape of…

Materials Science · Physics 2017-07-31 Zhi Ma , Yanan Ma , Fu Zheng , Hua Gao , Hongfei Liu , Huanming Chen

Halide perovskites have emerged as one of the most interesting materials for optoelectronic applications due to their favorable properties, such as defect-tolerance and long charge carrier lifetimes, which are attributed to their dynamic…

Materials Science · Physics 2023-11-20 Julia Wiktor , Erik Fransson , Dominik Kubicki , Paul Erhart

One of the most significant features of lead-halide perovskites are their ability to have comparably slow recombination despite the fact that these materials are mostly processed from solution at room temperature. The slow recombination…

Applied Physics · Physics 2019-07-26 Thomas Kirchartz

An effective method, performed adding external electric field (EEF) on CH3NH3PbI3-xClx (OPIC) perovskite layer during the annealing process, is proposed to improve the performance of the solar cell. By harmonizing EEF direction with the…

Materials Science · Physics 2015-07-10 Xiu Gong , Heng Ma , Yu-Rong Jiang , Meng Li , Zhao-Kui Wang , Tetsuo Soga

The stability of high-symmetry $P4mm$ polar phase in eleven ferroelectric perovskite superlattices with the polar discontinuity is studied from first principles. In most superlattices, this phase exhibits either the ferroelectric or the…

Materials Science · Physics 2021-09-03 Alexander I. Lebedev

Halide perovskites are semiconductors that exhibit sharp optical absorption edges and small Urbach energies allowing for efficient collection of sunlight in thin-film photovoltaic devices. However, halide perovskites also exhibit large…

Materials Science · Physics 2019-07-25 Christian Gehrmann , David A. Egger

Epitaxial thin films of relaxor PbMg1/3Nb2/3O3 and PbSc0.5Nb0.5O3, and ferroelectric PbZr0.65Ti0.35O3, Pb0.955La0.045Zr0.65Ti0.35O3, and Ba0.4Sr0.6TiO3 were prepared, and their dielectric properties were studied in a broad range of the…

Materials Science · Physics 2009-11-11 M. Tyunina , J. Levoska , I. Jaakola

We study both theoretically and experimentally switching dynamics in surface stabilized ferroelectric liquid crystal cells with asymmetric boundary conditions. In these cells the bounding surfaces are treated differently to produce…

Soft Condensed Matter · Physics 2009-11-11 Alexei D. Kiselev , Vladimir G. Chigrinov , Eugene P. Pozhidaev

Solution combustion synthesized hole transport layer of co-doped spinel nickel cobaltite were fabricated using doctor-blading technique for planar inverted perovskite solar cells. Perovskite solar cells incorporating Co-doped spinel nickel…

Inorganic ferroelectric perovskite oxides are more stable than hybrid perovskites. However, their solar energy harvest efficiency is not so good. Here, by constructing a series of BiFeO3 based devices (solar cells), we investigated three…

Materials Science · Physics 2020-03-27 Chao He , Guocai Liu , Huiyan Zhao , Kun Zhao , Zuju Ma , Xingtao An

Impedance spectroscopy (IS) is a relatively straightforward experimental technique that is commonly used to obtain information about the physical and chemical characteristics of photovoltaic devices. However, the non-standard physical…