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The dynamic effects observed in the J-V measurements represent one important hallmark in the behavior of the perovskite solar cells. Proper measurement protocols (MPs) should be employed for the experimental data reproducibility, in…

Mesoscale and Nanoscale Physics · Physics 2018-09-05 G. A. Nemnes , Cristina Besleaga , A. G. Tomulescu , Alexandra Palici , L. Pintilie , A. Manolescu , Ioana Pintilie

We investigate in how far the hysteresis-free behavior of perovskite solar cells can be reproduced using particular pre-conditioning and measurement conditions. As there are currently more and more reports of perovskite solar cells without…

Hysteretic effects are investigated in perovskite solar cells in the standard FTO/TiO$_2$/CH$_3$NH$_3$PbI$_{3-x}$Cl$_x$/spiro-OMeTAD/Au configuration. We report normal (NH) and inverted hysteresis (IH) in the J-V characteristics occurring…

The anomalous hysteresis is reported in photo current density-voltage (J-V) curves of perovskite solar cells. The origins responsible for hysteresis are primarily attributed to ferroelectricity, trapping/de-trapping, and ions migration.…

Materials Science · Physics 2015-08-25 Zeguo Tang , Takashi Minemoto

Previously, we proposed that the polarization and capacitive charge in \ce{CH3NH3PbI3} screens the external electric field that hinders charge transport. We argue here that this screening effect is in significant part responsible for the…

Mesoscale and Nanoscale Physics · Physics 2016-09-28 Yecheng Zhou , Fuzhi Huang , Yi-Bing Cheng , Angus Gray-Weale

Increasing evidence suggests that the presence of mobile ions in perovskite solar cells can cause a current-voltage curve hysteresis. Steady state and transient current-voltage characteristics of a planar metal halide CH$_3$NH$_3$PbI$_3$…

Applied Physics · Physics 2018-04-24 N. E. Courtier , J. M. Foster , S. E. J. O'Kane , A. B. Walker , G. Richardson

Current-voltage measurements are a standard testing protocol to determine the efficiency of any solar cell. However, perovskite solar cells display significant kinetic phenomena that modify the performance at several time scales, due to…

Applied Physics · Physics 2024-07-03 Enrique H. Balaguera , Juan Bisquert

Organic-inorganic hybrid perovskite solar cells (PSC) have demonstrated impressive performance improvement. Among the various characteristics, the time-dependent current-voltage (J-V) hysteresis allows a direct exploration of various…

Materials Science · Physics 2024-12-23 Abhimanyu Singareddy , Pradeep R. Nair

Hysteresis in the current-voltage characteristics of hybrid organic-inorganic perovskite-based solar cells is one of the fundamental aspects of these cells that we do not understand well. One possible cause, suggested for the hysteresis, is…

Dynamic hysteresis effects have been long known to occur in the J-V characteristics of perovskite solar cells (PSCs), with the ionic migration being identified as the primary factor. The hysteretic effects impacted early studies by the…

Halide perovskite semiconductors respond to electric fields in a way that varies across time and length scales. We discuss the microscopic processes that give rise to the macroscopic polarization of these materials, ranging from the optical…

Materials Science · Physics 2018-12-04 Jacob N. Wilson , Jarvist M. Frost , Suzanne K. Wallace , Aron Walsh

Perovskites are promising next-generation absorber materials for low-cost and high-efficiency solar cells. Although perovskite cells are configured similar to the classical solar cells, their operation is unique and requires development of…

Mesoscale and Nanoscale Physics · Physics 2018-02-01 Xingshu Sun , Reza Asadpour , Wanyi Nie , Aditya D. Mohite , Muhammad A. Alam

Ionic migration has been proposed as a possible cause of photovoltaic current-voltage hysteresis in hybrid perovskite solar cells. However, a major objection to this hypothesis is that hysteresis can be reduced by changing the interfacial…

In this work, perovskite solar cells (PSCs) with different transport layers were fabricated to understand the hysteresis phenomenon under a series of scan rates. The experimental results show that the hysteresis phenomenon would be affected…

Materials Science · Physics 2022-05-24 Jun-Yu Huang , You-Wei Yang , Wei-Hsuan Hsu , En-Wen Chang , Mei-Hsin Chen , Yuh-Renn Wu

In this perspective, we explore the insights into the device physics of perovskite solar cells gained from modeling and simulation of these devices. We discuss a range of factors that influence the modeling of perovskite solar cells,…

Applied Physics · Physics 2020-08-04 Nir Tessler , Yana Vaynzof

To overcome the challenges associated with poor temporal stability of perovskite solar cells, methods are required that allow for fast iteration of fabrication and characterisation, such that optimal device performance and stability may be…

Despite the remarkable progress in emerging solar cell technologies such as hybrid organic-inorganic perovskites, there are still significant limitations related to the stability of the devices and their non-ideal electrical behavior under…

Perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology, already achieving efficiencies surpassing 25%. However, effects such as hysteresis are commonly observed due to the interplay of ionic and electronic…

Negative capacitance at the low-frequency domain and inverted hysteresis are familiar features in perovskite solar cells, where the origin is still under discussion. Here we use Impedance Spectroscopy to analyse these responses in…

Halide perovskite solar cells presented a unique opportunity to apply modern computational materials science techniques to an (initially) poorly understood new material. In this review, we recount the key understanding developed during the…

Mesoscale and Nanoscale Physics · Physics 2018-11-07 Jarvist Moore Frost
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