Related papers: C60 as a probe for astrophysical environments
Fullerenes are a particularly stable class of carbon molecules in the shape of a hollow sphere or ellipsoid that might be formed in the outflows of carbon stars. Once injected into the interstellar medium (ISM), these stable species survive…
Molecular emission is observed in a wide variety of astrophysical environments, yet a substantial fraction of spectral features detected at mm wavelengths remains unidentified. Identifying these features is essential for constraining the…
Astronomical dust molecule of carbon-rich nebula-Lin49 and nebula-Tc1 could be identified to be polycyclic-pure-carbon C23 by the quantum-chemical calculation. Two driving forces were assumed. One is high speed proton attack on…
Due to recent advances in laboratory spectroscopy, the first optical detection of a very large molecule has been claimed in the diffuse interstellar medium (ISM): C60+ (ionized Buckminsterfullerene). Confirming the presence of this molecule…
We present seeing-limited narrow-band mid-IR GTC/CanariCam images of the spatially extended fullerene-containing planetary nebula (PN) IC 418. The narrow-band images cover the C60 fullerene band at 17.4 {\mu}m, the polycyclic aromatic…
The current debate about the nature of the carbonaceous material carrying the infrared (IR) emission spectra of planetary and proto-planetary nebulae, including the broad plateaus, calls for further studies on the interplay between…
Small metal-containing molecules have been detected and recognized as one of the hybrid species efficiently formed in space; especially in the circumstellar envelopes of evolved stars. It has been predicted also that more complex hybrid…
The C_{60} molecule exhibits a remarkable stability and inertness that leads to its survival in ancient carbonaceous rocks initially subject to the high temperatures requisite for its formation. Elementary particles having very high…
Laboratory spectra of hydrogenated amorphous carbon (HAC) particles prepared under a variety of conditions show spectral features at 7.05, 8.5, 17.4 and 18.9 {\mu}m (1418, 1176, 575 & 529 cm-1) that have been associated with emission from…
The largest known molecule in space, C60 , has been detected in its neutral and cationic form through its vibrational, UV-driven fluorescence emission spectrum and its electronic absorption spectrum, respectively. The detection of several…
We present a charge distribution-based emission model that calculates the infrared spectrum of fullerenes (C$_{60}$). Analysis of the modelled spectrum of C$_{60}$ in various charge states shows that the relative intensity of the features…
Understanding the molecular vibrations underlying each of the unknown infrared emission (UIE) bands (such as those found at 3.3, 3.4, 3.5, 6.2, 6.9, 7.7, 11.3, 15.8, 16.4, 18.9 mm) observed in or towards astronomical objects is a vital link…
Gas phase spectroscopic laboratory experiments for the buckminsterfullerene cation C60+ resulted in accurate rest wavelengths for five C60+ transitions that have been compared with diffuse interstellar bands (DIBs) in the near infra-red.…
We analyze the 11.2 {\mu}m unidentified infrared band (UIR) spectrum from NGC 7027 and identify a small fullerene (C24) as a plausible carrier. The blurring effects of lifetime and vibrational anharmonicity broadening obscure the narrower,…
We performed a detailed spectroscopic analysis of the fullerene C60-containing planetary nebula (PN) Lin49 in the Small Magellanic Cloud using XSHOOTER at the ESO VLT and the Spitzer/IRS instruments. We derived nebular abundances for nine…
We searched the Spitzer Space Telescope data archive for Galactic planetary nebulae (PNe), that show the characteristic 17.4 and um features due to C60, also known as buckminsterfullerene. Out of 338 objects with Spitzer/IRS data, we found…
We perform a detailed analysis of the fullerene C60-containing planetary nebula (PN) SaSt2-3 to investigate the physical properties of the central star (B0-1II) and nebula based on our own Subaru/HDS spectra and multiwavelength archival…
We report the first detection of C$_2$ $A^1\Pi_u$--$X^1\Sigma_g^+$ (0,0) and CN $A^2\Pi_u$--$X^2\Sigma^+$ (0,0) absorption bands in the interstellar medium. The detection was made using the near-infrared (0.91--1.35 $\mu$m) high-resolution…
We performed multiwavelength observations of the young planetary nebula (PN) M1-11 and obtained its elemental abundances, dust mass, and the evolutionary status of the central star. The AKARI/IRC, VLT/VISIR, and Spitzer/IRS spectra show…
We report a computational study of the stability and infrared (IR) vibrational spectra of neutral and singly ionised fullerene cages containing between 44 and 70 carbon atoms. The stability is characterised in terms of the standard enthalpy…