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The anomalous hysteresis is reported in photo current density-voltage (J-V) curves of perovskite solar cells. The origins responsible for hysteresis are primarily attributed to ferroelectricity, trapping/de-trapping, and ions migration.…

Materials Science · Physics 2015-08-25 Zeguo Tang , Takashi Minemoto

Increasing evidence suggests that the presence of mobile ions in perovskite solar cells can cause a current-voltage curve hysteresis. Steady state and transient current-voltage characteristics of a planar metal halide CH$_3$NH$_3$PbI$_3$…

Applied Physics · Physics 2018-04-24 N. E. Courtier , J. M. Foster , S. E. J. O'Kane , A. B. Walker , G. Richardson

Hysteretic effects are investigated in perovskite solar cells in the standard FTO/TiO$_2$/CH$_3$NH$_3$PbI$_{3-x}$Cl$_x$/spiro-OMeTAD/Au configuration. We report normal (NH) and inverted hysteresis (IH) in the J-V characteristics occurring…

We report a model describing the molecular orientation disorder in CH3NH3PbI3, solving a classical Hamiltonian parametrised with electronic structure calculations, with the nature of the motions informed by ab-initio molecular dynamics. We…

Mesoscale and Nanoscale Physics · Physics 2014-12-15 Jarvist M. Frost , Keith T. Butler , Aron Walsh

A dynamic electrical model is introduced to investigate the hysteretic effects in the I-V characteristics of perovskite based solar cells. By making a simple ansatz for the polarization relaxation, our model is able to reproduce…

Perovskite solar cells (PSCs) have emerged as a promising photovoltaic technology, already achieving efficiencies surpassing 25%. However, effects such as hysteresis are commonly observed due to the interplay of ionic and electronic…

Interplays between charge and electric field, which play a critical role in determining the charge transport, recombination, storage and hysteresis in the perovskite solar cell, have been systematically investigated by both electrical…

Materials Science · Physics 2017-10-31 Jiangjian Shi , Huiyin Zhang , Xin Xu , Dongmei Li , Yanhong Luo , Qingbo Meng

Hysteresis in the current-voltage characteristics of hybrid organic-inorganic perovskite-based solar cells is one of the fundamental aspects of these cells that we do not understand well. One possible cause, suggested for the hysteresis, is…

Selecting suitable charge transport layers and suppressing non-radiative recombination at interfaces to the absorber layer are vital to maximize the efficiency of halide perovskite solar cells. In this work, high-quality perovskite thin…

In this work, perovskite solar cells (PSCs) with different transport layers were fabricated to understand the hysteresis phenomenon under a series of scan rates. The experimental results show that the hysteresis phenomenon would be affected…

Materials Science · Physics 2022-05-24 Jun-Yu Huang , You-Wei Yang , Wei-Hsuan Hsu , En-Wen Chang , Mei-Hsin Chen , Yuh-Renn Wu

Negative capacitance at the low-frequency domain and inverted hysteresis are familiar features in perovskite solar cells, where the origin is still under discussion. Here we use Impedance Spectroscopy to analyse these responses in…

Ionic migration has been proposed as a possible cause of photovoltaic current-voltage hysteresis in hybrid perovskite solar cells. However, a major objection to this hypothesis is that hysteresis can be reduced by changing the interfacial…

If charge carriers accumulate in the charge transport layer of a solar cell, then the transient response of the electric field that originates from these accumulated charges results in hysteresis in the current-voltage ($J$-$V$)…

Materials Science · Physics 2016-07-22 Kazuhiko Seki

Dynamic hysteresis effects have been long known to occur in the J-V characteristics of perovskite solar cells (PSCs), with the ionic migration being identified as the primary factor. The hysteretic effects impacted early studies by the…

Perovskite solar cells are notorious for exhibiting transient behaviour not seen in conventional inorganic semiconductor devices. Significant inroads have been made into understanding this fact in terms of rapid ion migration, now a…

Organic-inorganic hybrid perovskite solar cells (PSC) have demonstrated impressive performance improvement. Among the various characteristics, the time-dependent current-voltage (J-V) hysteresis allows a direct exploration of various…

Materials Science · Physics 2024-12-23 Abhimanyu Singareddy , Pradeep R. Nair

An effective method, performed adding external electric field (EEF) on CH3NH3PbI3-xClx (OPIC) perovskite layer during the annealing process, is proposed to improve the performance of the solar cell. By harmonizing EEF direction with the…

Materials Science · Physics 2015-07-10 Xiu Gong , Heng Ma , Yu-Rong Jiang , Meng Li , Zhao-Kui Wang , Tetsuo Soga

We investigate in how far the hysteresis-free behavior of perovskite solar cells can be reproduced using particular pre-conditioning and measurement conditions. As there are currently more and more reports of perovskite solar cells without…

Current-voltage measurements are a standard testing protocol to determine the efficiency of any solar cell. However, perovskite solar cells display significant kinetic phenomena that modify the performance at several time scales, due to…

Applied Physics · Physics 2024-07-03 Enrique H. Balaguera , Juan Bisquert

Halide perovskite semiconductors respond to electric fields in a way that varies across time and length scales. We discuss the microscopic processes that give rise to the macroscopic polarization of these materials, ranging from the optical…

Materials Science · Physics 2018-12-04 Jacob N. Wilson , Jarvist M. Frost , Suzanne K. Wallace , Aron Walsh
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