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Electron motion on the (sub-)femtosecond time scale constitutes the fastest response in many natural phenomena such as light-induced phase transitions and chemical reactions. Whereas static electron densities in single molecules can be…

Charge dynamics in an ultra-cold setup involving a laser dressed atom and an ion is studied here. This transfer of charge is enabled through molecular Rydberg states that are accessed via a laser. The character of the charge exchange…

Atomic Physics · Physics 2019-07-17 Rick Mukherjee

Recent advances in attosecond physics provide access to the correlated motion of valence and core electrons on their intrinsic timescales. For valence excitations, processes related to the electron spin are usually driven by nuclear motion.…

Chemical Physics · Physics 2017-01-18 Huihui Wang , Sergey I. Bokarev , Saadullah G. Aziz , O. Kühn

We report attosecond-scale probing of the laser-induced dynamics in molecules. We apply the method of high-harmonic spectroscopy, where laser-driven recolliding electrons on various trajec- tories record the motion of their parent ion.…

Ultraintense pulses from X-ray free-electron lasers can drive, within femtoseconds, multiple processes in the inner shells of atoms and molecules in all phases of matter. The ensuing complex ionization pathways of outer-shell electrons from…

Long-lived beatings in two-dimensional electronic spectroscopy (2DES) remain difficult to interpret within standard excitonic open-system models, which typically assume factorized initialization and predict rapid coherence decay. We show…

Quantum Physics · Physics 2026-02-05 Sirui Chen , Dragomir Davidović

We investigate electron transport through a mixed-valence molecular complex in which an excess electron can tunnel between hetero-valent transition metal ions, each having a fixed localized spin. We show that in this class of molecules the…

Mesoscale and Nanoscale Physics · Physics 2009-03-11 F. Reckermann , M. Leijnse , M. R. Wegewijs

The ultrafast electronic and nuclear dynamics of H2 laser-induced double ionization is studied using a time-dependent wave packet approach that goes beyond the fixed nuclei approximation. The double ionization pathways are analyzed by…

Quantum Physics · Physics 2011-11-09 Sebastien Saugout , Christian Cornaggia , Annick Suzor-Weiner , Eric Charron

Photoionization of an atom $A$, in the presence of a neighboring atom $B$, can proceed via resonant excitation of $B$ with subsequent energy transfer to $A$ through two-center electron-electron correlation. We demonstrate that this…

Atomic Physics · Physics 2015-05-19 B. Najjari , A. B. Voitkiv , C. Müller

Excitons play an essential role in the optical response of two-dimensional materials. These are bound states showing up in the band gaps of many-body systems and are conceived as quasiparticles formed by an electron and a hole. By…

Many puzzling properties of high-$T_c$ superconducting (HTSC) copper oxides have deep roots in the nature of the antinodal quasiparticles, the elementary excitations with wavevector parallel to the Cu-O bonds. These electronic states are…

We investigate theoretically electron dynamics under a VUV attosecond pulse train which has a controlled phase delay with respect to an additional strong infrared laser field. Using the strong field approximation and the fact that the…

Atomic Physics · Physics 2015-05-13 P. Riviere , O. Uhden , U. Saalmann , J. M. Rost

We use an independent electron model with semi-classical approximation to electron dynamics to investigate differential cross sections for electron emission in fast collisions of protons with ammonia molecules. An effective potential model…

Atomic Physics · Physics 2023-09-29 Alba Jorge , Marko Horbatsch , Tom Kirchner

Attosecond streaking of photoelectrons emitted by extreme ultraviolet light has begun to reveal how electrons behave during their transport within simple crystalline solids. Many sample types within nanoplasmonics, thin-film physics, and…

We investigate transient transport of electrons through a single-quantum-dot controlled by a plunger gate. The dot is embedded in a finite wire that is weakly coupled to leads and strongly coupled to a single cavity photon mode. A…

Mesoscale and Nanoscale Physics · Physics 2013-11-15 Nzar Rauf Abdullah , Chi-Shung Tang , Andrei Manolescu , Vidar Gudmundsson

Atomically thin semiconductors have versatile future applications in the information and communication technologies for the ultimate miniaturization of electronic components. In particular, the ongoing research demands not only a…

Phenomena involving electron transfer are ubiquitous in nature, photosynthesis and enzymes or protein activity being prominent examples. Their deep understanding thus represents a mandatory scientific goal. Moreover, controlling the…

Chemical Physics · Physics 2017-12-01 Carlo Andrea Rozzi , Filippo Troiani , Ivano Tavernelli

A general scenario for electronic charge migration in finite samples illuminated by an intense laser pulse is given. Microscopic calculations for neon clusters under strong short pulses as produced by X-ray free-electron laser sources…

Atomic and Molecular Clusters · Physics 2009-04-30 Christian Gnodtke , Ulf Saalmann , Jan M. Rost

The electron transfer kinetics of mixed-valence systems is studied via solving the eigen-structure of the two-state non-adiabatic diffusion operator for a wide range of electronic coupling constants and energy bias constants. The calculated…

Chemical Physics · Physics 2007-05-23 Y. Jung , R. J. Silbey , J. Cao

A coherent vibrational wavepacket is launched and manipulated in the symmetric stretch (a$_1$) mode of CBr$_4$, by impulsive stimulated Raman scattering from non-resonant 400 nm laser pump pulses with various peak intensities on the order…