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The chemical composition of Titan organic haze is poorly known. To address this issue, laboratory analogs named tholins are synthesized, and analyzed by methods requiring often an extraction process in a carrier solvent. These methods…
Numerous studies have been carried out to characterize the chemical composition of laboratory analogues of Titan aerosols (tholins), but their molecular composition as well as their structure are still poorly known. If pyrolysis gas…
The role of polycyclic aromatic hydrocarbons (PAH) and Nitrogen containing PAH (PANH) as intermediates of aerosol production in the atmosphere of Titan has been a subject of controversy for a long time. An analysis of the atmospheric…
The aerosols present in the atmosphere of the Saturn s moon Titan are of particular planetary science interest and several spacecraft missions already allowed to gather spectroscopic data. Titan haze s analogs, so-called tholins, were…
Titan, the biggest moon of Saturn, has a thick atmosphere which presents similarities with the one thought to be on Earth at its beginning. The study of Titan s photochemical haze is thus a precious tool in gaining knowledge of the…
The Cassini/Huygens mission provided new insights on the chemistry of the upper atmosphere of Titan. The presence of large molecules and ions (>100 s of amu) detected by Cassini at high altitude was not expected, and questions the original…
Titan's organic aerosols are formed in the ionosphere, a layer ionized by solar VUV photons and energetic particles from the magnetosphere of Saturn, forming a natural N2-CH4-H2 plasma. Previous works showed some chemical evolution…
We present results of an investigation into the formation of nitrogen-bearing molecules in the atmosphere of Titan. We extend a previous model (Li et al. 2015, 2016) to cover the region below the tropopause, so the new model treats the…
In this chapter we describe the remote sensing measurement of nitrogen-bearing species in Titan's atmosphere by the Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft. This instrument, which detects the thermal infrared…
The organic haze produced from complex CH4/N2 chemistry in the atmosphere of Titan plays an important role in processes that occur in the atmosphere and on its surface. The haze particles act as condensation nuclei and are therefore…
In the Solar System, extra-terrestrial organic molecules have been found on cometary primitive objects, on Titan and Enceladus icy moons and on Mars. Identification could be achieved for simple organic species by remote sensing based on…
In this article I summarize the current state of knowledge about the composition of Titan's atmosphere, and our current understanding of the suggested chemistry that leads to that observed composition. I begin with our present knowledge of…
Titan is unique in the solar system as it hosts a dense atmosphere mainly made of N$_2$ and CH$_4$. Cassini-Huygens revealed the presence of an intense atmospheric photochemistry initiated by the photo-dissociation and ionization of N$_2$…
The Cassini Plasma Spectrometer (CAPS) Electron Spectrometer (ELS) instrument onboard Cassini revealed an unexpected abundance of negative ions above 950 km in Titan's ionosphere. \textit{In situ} measurements indicated the presence of…
Thanks to the \textit{Cassini} spacecraft onboard instruments, it has been known that Titan's ionospheric chemistry is complex and the molecular growth is initiated through the photolysis of the most abundant species directly in the upper…
Sulfur-bearing molecules are central to interstellar chemistry, yet their observed abundances in the gas phase remain far below cosmic expectations in dense interstellar regions. Mixed N-S-O species such as thionylimide (HNSO) are…
The Cassini Mission has greatly improved our understanding of the dynamics and chemical processes occurring in Titan's atmosphere. It has also provided us with more insight into the formation of the aerosols in the upper atmospheric layers.…
Aims. We present a new list of thorium and argon emission lines in the visible obtained by analyzing high-resolution (R=110,000) spectra of a ThAr hollow cathode lamp. The aim of this new line list is to allow significant improvements in…
The discovery of amino acids in meteorites and the detection of glycine in samples returned from a comet to Earth suggest that the interstellar chemistry is capable of producing such complex organic molecules. Our goal is to investigate the…
The Cassini-Huygens mission detected large negative ions in Titan's ionosphere at pressures as low as $10^{-6}$ torr. These ions ultimately polymerize to form Titan's complex organic haze particles, which are observed throughout the…